Effect of Electrolyte on Carbon Dioxide Reduction of Silver Electrocatalyst

Journal of Physics Conference Series, Journal Year: 2025, Volume and Issue: 2962(1), P. 012007 - 012007

Published: Feb. 1, 2025

Abstract Large amounts of CO 2 have disrupted the natural carbon cycle. reduction reaction (CO RR) is an effective strategy to reduce high concentration . Currently, design cathode catalyst widespread promote RR. However, effect electrolyte on catalytic fuzzy. Hence, silver nanoparticles (Ag NPs) synthesized conveniently by a one-pot method was used study effects different electrolytes activity and selectivity in 0.1 M NaHCO 3 , KHCO KCl as were applied into Efficient RR performances are exposed three electrolytes. The results show that optimal choice with maximum over 80%, which better than many reports. Meanwhile, enhances but poisons active site weaken selectivity. This research affords direction for acquainting oneself exploit new energy.

Language: Английский

---

The Role of Tunnel‐Structured Hollandite Material Family for Advancing Energy Storage Applications

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: April 30, 2025

Abstract Rising demand for clean energy is driving the need advanced materials sustainable storage. Among rising candidates storing via their open framework, hollandite material family, represented by Mn‐/Ti‐/Fe‐based metal dioxides, particularly promising due to unique sub‐nanoscale tunnel structure that enables reversible ion diffusion. However, challenges like structural instability and ambiguous charge storage mechanisms largely reduce commercial potential. Thus, this article timely reviews recent advancements of in terms features, mechanisms, properties, performances. The focus on crystalline where diffusion/storage takes place, emphasize stability resulted performance both organic aqueous electrolyte systems; particularly, review covers intercalation/de‐intercalation when working as electrodes lithium‐ion sodium‐ion batteries, well behaviors supercapacitors zinc batteries. In addition, strategies doping, composite fabrication, nanostructure optimization are also included effectiveness enhancing electrochemical performance. This concluded discussing role andthe expectation tunnel‐structured future battery technologies, emphasizing urgent framework toward more efficient stable servicing.

Language: Английский

---

Atomic Size Misfit for Electrocatalytic Small Molecule Activation

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: May 26, 2025

Abstract The efficient activation of small molecules such as H 2 O, CO , and N for sustainable fuel chemical production is a critical challenge in catalysis, owing to the strong covalent bonds (O─H, C═O, N≡N) that resist easy cleavage. Catalysts are pivotal overcoming these energy barriers, enhancing reaction rates selectivity. strategy atomic size misfit, which introduces structural defects like vacancies, grain boundaries, dislocations, has gained attention promising approach optimize catalytic activity. This modulates interactions, alters electronic structures, enhances reactivity active sites, facilitating molecules. Moreover, this holds significant potential reducing environmental impact by enabling more processes. However, current research on misfit remains fragmented, lacking unified framework. A comprehensive review essential consolidate its mechanisms, applications, integration with other tuning methods alloying doping. aims provide valuable insights into design next‐generation catalysts, guiding future developments conversion technologies offering pathways practical, scalable applications molecule activation.

Language: Английский

---

Electrochemical Cell Designs for Efficient Carbon Dioxide Reduction and Water Electrolysis: Status and Perspectives

Advanced Materials, Journal Year: 2025, Volume and Issue: unknown

Published: May 30, 2025

Abstract Integrating renewable electricity and concentrated CO 2 from direct air capture, electrochemical reduction reactions (eCO RR) offer a promising pathway for converting into fuel chemicals, enabling the closure of carbon loop in sustainable manner. The clean H produced via hydrogen evolution reaction (HER) during water electrolysis can replace traditional fossil fuels without additional emissions. Achieving large‐scale high‐efficiency eCO RR HER requires development rational electrolyzer designs, which are crucial industrial implementation. This review examines recent innovations system designs RR, HER, latest advances situ cell operando characterization reactions. It focuses on improvements flow patterns, membrane electrode assemblies, electrolyte engineering to maximize catalytic activities at level. Besides, discusses optimizing counter‐anodic improve energy efficiency electrolysis, offering insights design systems with efficient utilization. Furthermore, it explores integration other (e.g., cells), highlighting their potential role decarbonization future processes. Finally, summary, challenge, outlook industrial‐scale concluded.

Language: Английский

---

Enhancing carbon enrichment by metal–organic cage to improve the electrocatalytic carbon dioxide reduction performance of silver-based catalyst

Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 683, P. 468 - 476

Published: Dec. 6, 2024

Language: Английский

---

Boosted Na+-MnO2 supercapacitor performance via strong metal support interaction

Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 682, P. 865 - 874

Published: Dec. 6, 2024

Language: Английский

---