A Polyvinyl Alcohol-Based Ion-Solvating Membrane with Non-Precious Metal Catalysts for Advanced Water Electrolysis DOI

Guoxiong Deng,

Yiwen Liao,

Yakai Lin

et al.

Published: Jan. 1, 2024

Language: Английский

Microwave-assisted synthesis of carbonized polymer dots/CdS quantum dots/Bi2WO6 Z-scheme heterojunctions: Enhancing photocatalytic environmental remediation via dual-quantum dot heterostructures DOI

Bing Shen,

Yukun Chen, Li Zhao

et al.

Journal of Colloid and Interface Science, Journal Year: 2025, Volume and Issue: 684, P. 226 - 243

Published: Jan. 6, 2025

Language: Английский

Citations

3
High-efficiency Photocatalytic Hydrogen and Oxygen Evolution Properties by Z-scheme Electron Transfer in BiVO4/C3N5 Heterostructure DOI
Wuyou Wang, Biqing Li, Jia Shi

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2024, Volume and Issue: 362, P. 124766 - 124766

Published: Oct. 30, 2024

Language: Английский

Citations

11
Stacking Fault‐Enriched MoNi4/MoO2 Enables High‐Performance Hydrogen Evolution DOI Creative Commons
Yuan Wang, Hamidreza Arandiyan, Sajjad S. Mofarah

et al.

Advanced Materials, Journal Year: 2024, Volume and Issue: 36(33)

Published: June 13, 2024

Producing green hydrogen in a cost-competitive manner via water electrolysis will make the long-held dream of economy reality. Although platinum (Pt)-based catalysts show good performance toward evolution reaction (HER), high cost and scarce abundance challenge their economic viability sustainability. Here, non-Pt, high-performance electrocatalyst for HER achieved by engineering fractions stacking fault (SF) defects MoNi

Language: Английский

Citations

9
Unconventional hcp/fcc Nickel Heteronanocrystal with Asymmetric Convex Sites Boosts Hydrogen Oxidation DOI
Hairui Pan,

Zhuo‐Qi Shi,

Xiaozhi Liu

et al.

Angewandte Chemie International Edition, Journal Year: 2024, Volume and Issue: unknown

Published: July 2, 2024

Developing non-platinum group metal catalysts for the sluggish hydrogen oxidation reaction (HOR) is critical alkaline fuel cells. To date, Ni-based materials are most promising candidates but still suffer from insufficient performance. Herein, we report an unconventional hcp/fcc Ni (u-hcp/fcc Ni) heteronanocrystal with multiple epitaxial heterointerfaces and coherent twin boundaries, generating rugged surfaces plenty of asymmetric convex sites. Systematic analyses discover that such sites enable adsorption *H in unusual bridge positions weakened binding energy, circumventing over-strong on traditional hollow positions, simultaneously stabilizing interfacial

Language: Английский

Citations

7
Boosting Hydrogen Transport in Mixed Matrix Membranes Through Continuous Spillover Via Pd‐Functionalized MOF Gel Networks DOI Open Access
Keming Zhang, Xiaohe Tian, Zhe Xu

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 3, 2024

Abstract Membrane‐based gas separation offers notable energy efficiency benefits for hydrogen purification, yet it is often hindered by the inherent trade‐off between permeability and selectivity. To address this challenge, a novel mixed matrix membrane (MMM) design presented to boost H 2 performance via continuous spillover mechanisms first time. The MMM incorporates palladium‐functionalized ZIF‐67 gel (Pd@ZIF‐67 gel) network into polymer of intrinsic microporosity (PIM‐1) matrix. serves as uniform dispersion medium palladium nanoparticles (Pd NPs), thereby generating multitude active sites. These exposed sites, in conjunction with microporous structure ZIF‐67, facilitate dissociation establish pathway throughout membrane. This synergistic leads substantial improvements both transport At an optimal loading 28 wt% Pd@ZIF‐67 gel, MMMs exhibit 3620 Barrer remarkable 417% enhancement /CH 4 selectivity (24.9), surpassing 2008 upper bound. approach paves way development advanced materials tailored applications.

Language: Английский

Citations

4
High‐Performance NiCu Hydroxide Self‐Supported Electrode as a Bifunctional Catalyst for AOR and OER DOI Creative Commons
Yanchao Liu, Yin Cai,

Zhongmei Yang

et al.

Battery energy, Journal Year: 2025, Volume and Issue: unknown

Published: March 11, 2025

ABSTRACT Ammonia has gained considerable attention as a promising energy carrier due to its high hydrogen content, carbon‐free emissions, and ease of storage transportation compared gas. The electrochemical ammonia oxidation reaction (AOR) is pivotal process for harnessing sustainable source, enabling production through decomposition or electricity generation via direct fuel cells. NiCu, transition metal alloy, shown great potential an efficient cost‐effective catalyst AOR. In this study, high‐valence Ni Cu hydroxyl hydroxides were synthesized on nickel foam form NiCuOOH in the structure folded nanosheets, serving anodic electrocatalyst Comprehensive characterization identified metals primary active components. By optimizing Ni/Cu ratio, achieved remarkable performance stability, reaching maximum current density 169 mA cm − 2 at 1.62 V versus RHE, with 0.16 at% delivering activity, being stable 48 h 100 −2 . Additionally, exhibited excellent catalytic activity oxygen evolution (OER), attaining 152 1.72 RHE. This study presents cost‐effective, high‐performance, easily bifunctional self‐supporting catalyst, offering significant both AOR OER applications.

Language: Английский

Citations

0
In-situ transformation and synergistic electrocatalysis of asymmetric threefold hollow sites in rosebud-like ternary metal diselenide DOI
Shihao Wang, Lin Liao, Jinsong Wu

et al.

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 161585 - 161585

Published: March 1, 2025

Language: Английский

Citations

0
Optimizing H2 production via NH3 decomposition: alkali metal-doped Fe-based catalysts with FexN active phases DOI

Xiteng Yan,

X. T. Chen,

Runping Ye

et al.

Journal of environmental chemical engineering, Journal Year: 2025, Volume and Issue: unknown, P. 116115 - 116115

Published: March 1, 2025

Language: Английский

Citations

0
Revealing the role of 1T- & 2H- molybdenum Disulfide/Nickel sulfide heterojunction for efficient overall water splitting DOI Creative Commons

Zeming Li,

Zhiping Deng, Dong Yan

et al.

Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 678, P. 666 - 675

Published: Aug. 29, 2024

In the ongoing quest for cost-effective and durable electrocatalysts hydrogen production-a critical element of sustainable energy transformation-the 1T phase Molybdenum Disulfide (MoS

Language: Английский

Citations

3
Lattice strain Improves activity and stability of asymmetric Ag11Pd19Ir8 nanodendrites by pre-deposition and galvanic replacement reaction DOI
Junpeng Wang, Zhen Li, Chongyang Wang

et al.

Applied Surface Science, Journal Year: 2025, Volume and Issue: unknown, P. 162454 - 162454

Published: Jan. 1, 2025

Language: Английский

Citations

0