ChemElectroChem,
Journal Year:
2024,
Volume and Issue:
12(3)
Published: Dec. 27, 2024
Abstract
In
an
era
where
renewable
energy
resources
are
pivotal
yet
plagued
by
variability,
vanadium‐cerium
(V‐Ce)
redox
flow
batteries
(RFBs)
present
a
sophisticated
solution
to
storage
and
grid
stability.
This
study
focuses
into
the
electrochemical
integration
of
cerium
with
vanadium
enhance
traditional
batteries′
density
cost‐effectiveness.
Through
innovative
design
that
allows
scalability
addresses
challenges
lower
inherent
in
RFBs,
V‐Ce
RFBs
demonstrate
potential
for
more
compact
efficient
systems.
this
work,
we
provide
open‐source
mono
cell
research.
Herein,
research
spotlights
characterization
Ce‐based
electrolytes,
employing
mixed
acid
electrolytes
improve
solubility.
For
improving
performance
including
diffusion
coefficients
electron
transfer
rates,
L–Leucine
L–Lysine
have
been
used
as
organic
additives.
Obtained
results
revealed
these
additives
not
only
influence
stability
efficiency
but
also
significantly
affect
charge‐discharge
properties
which,
L‐leucine
showing
superior
over
L‐lysine.
These
findings
propose
new
way
optimizing
large‐scale
regarding
efficiency,
safety,
environmental
impact.
Lithium-metal
batteries
(LMBs)
incorporating
nickel-rich
cathodes
have
the
potential
to
achieve
superior
energy
densities.
However,
challenges
associated
with
electrolyte-electrode
interphases
(EEIs)
impeded
successful
transition
of
these
advanced
systems
into
practical
applications.
In
this
study,
azidotrimethylsilane
(ATMS)
is
introduced
as
a
multifunctional
additive
for
traditional
carbonate-based
electrolytes.
The
azido
group
in
ATMS
plays
dual
role
electrochemical
reactions,
multiple
nitrogen
(N)
atoms
engaging
both
nucleophilic
and
electrophilic
interactions.
These
N
tend
undergo
preferential
oxidation
reactions
at
cathode,
forming
stable
cathode
electrolyte
interphase,
while
also
undergoing
reduction
anode
inhibit
lithium
dendrite
growth.
Si-N
bond
structure
has
unique
reactivity,
effectively
neutralizing
HF
produced
from
LiPF6
decomposition,
thus
preventing
recurrent
formation
EEIs
battery.
As
result,
long-cycle
performance
Li||NCM811
significantly
improved,
capacity
retention
increasing
34.7%
baseline
82.6%
after
600
cycles.
Similarly,
enhances
cycling
Li||Li
symmetric
cells,
extending
their
lifespan
over
800
h,
improves
Coulombic
efficiency
Li||Cu
cells
81.6
91.6%.
synergistic
effect
on
anodes
further
high-voltage
LMBs.
Advanced Energy Materials,
Journal Year:
2025,
Volume and Issue:
unknown
Published: May 9, 2025
Abstract
Aqueous
Zinc‐sulfur
(Zn‐S)
rechargeable
batteries
are
emerging
as
promising
next‐generation
energy
storage
devices
due
to
safety,
capacity,
cost
and
efficiency.
However,
Zn
corrosion,
polarization,
low
conductivity
volume
expansion
of
sulfur
cathode
the
bottlenecks
for
battery
stability
capacity.
Herein,
we
report
a
dual
strategy
involving
sulfanilamide
(SA)
additive
stabilize
Zn,
paired
with
hollow
Ni
x
Fe
y
O
4
confine
sulfur,
mitigating
enhancing
along
iodine
redox
mediator
improve
2+
kinetics.
The
designed
demonstrated
an
excellent
specific
capacity
1260
mAh
g
−1
at
0.1
C
81%
retention
after
1000
cycles
1
C.
SA
mitigates
hydrogen
evolution
reaction
(HER)
by
3.5
times
2.8‐fold
reduction
in
corrosion
rate
anode,
which
is,
supported
Raman,
H
NMR
spectroscopy
furthercomplimented
computational
studies.
symmetric
Zn||Zn
cell
was
stable
more
than
770
h,
demonstrating
ultra‐high
anode.
Formation
ZnS
monitered
electrochemical
in‐situ
Raman
spectroscopy.
Zn‐S
homemade
pouch
powered
panel
30
red
LED
93
h
furthered
fan,
exceptional
sustainability.
Journal of Materials Chemistry A,
Journal Year:
2024,
Volume and Issue:
12(37), P. 25211 - 25221
Published: Jan. 1, 2024
2-Propyn-1-ol
methanesulfonate
(PMS)
preferentially
undergoes
reduction
decomposition
on
sodium
metal
anodes
and
actively
induces
FEC
solvation
behavior,
thereby
forming
a
stable
SEI
film
enriched
with
sulfide
compounds
NaF.
Chemical Science,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Jan. 1, 2024
For
sodium-ion
batteries,
solving
the
issue
of
short
cycle
life
is
key
to
their
large-scale
adoption
in
industry,
and
electrolyte
plays
an
important
role
on
this.
Herein,
this
work
aims
design
a
practical
sodium
ion
battery
with
industrial
application
value
introduces
anhydride
compounds
as
additives
for
first
time.
Meanwhile,
by
adjusting
solvent
composition
using
combination
ether
ester
solvents,
optimal
formulation
1
M
NaPF
Advanced Functional Materials,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Nov. 26, 2024
Abstract
Achieving
wide‐temperature
operation
is
a
crucial
objective
for
the
practical
deployment
of
sodium‐ion
batteries
(SIBs).
However,
development
suitable
electrolytes
hindered
by
significant
challenges,
including
compromised
ionic
dynamics
at
low
temperatures
and
interphase
instability
high
temperatures.
Herein,
this
study
proposes
novel
enhancement
mechanism
utilizing
sulfur‐rich
strategy,
grounded
in
rational
solvent
selection.
This
approach
enriches
electrolyte
with
sulfur‐containing
species
that
exhibit
Na
+
affinity
efficient
migration
both
cathode
anode
sides.
Consequently,
strategy
significantly
enhances
interfacial
charge
transfer
integrity,
confirmed
theoretical
calculations
electrochemical
measurements.
The
designed
demonstrates
robust
performance
half‐cells
based
on
3
V
2
(PO
4
)
(NVP)
across
wide
temperature
range
from
−25
to
60
°C.
Furthermore,
full‐cell,
featuring
an
NVP
paired
hard
carbon
anode,
exhibits
exceptional
stability.
Specifically,
full
cell
achieves
reversible
capacities
56.1
mAh
g
−1
after
100
cycles
°C
74.9
°C,
impressive
capacity
retentions
87.7%
88.2%,
respectively.
Importantly,
introduces
advanced
optimization
enables
SIBs
temperatures,
providing
solutions
future
developments
field.
ACS Applied Materials & Interfaces,
Journal Year:
2024,
Volume and Issue:
17(2), P. 3467 - 3477
Published: Dec. 31, 2024
This
work
develops
1,1′-oxalyldiimidazole
(ODI)
as
a
functional
electrolyte
additive.
film-forming
additive
improves
the
wide
range
of
temperature
and
rate
performances
LiNi0.8Co0.1Mn0.1O2/graphite
(NCM811)
batteries.
After
1200
cycles
at
room
(25
°C),
discharge
capacity
retention
is
51.95%
for
battery
with
blank
electrolyte,
it
93.18%
that
an
ODI-containing
electrolyte.
With
0.1%
ODI,
increases
from
0
to
75.89%
after
500
45
°C
48.51
95.54%
300
−10
°C.
In
addition,
performance
also
enhanced
by
introduction
ODI.
spectroscopic
characterization,
improvement
electrochemical
ODI
supported.
It
demonstrated
tends
preferentially
decompose
on
electrodes
then
participates
in
construction
stable
interfacial
film
low
impedance,
resulting
performance.
Not
only
does
this
develop
imidazole-based
but
inspires
innovative
approaches
creating
additives
can
enhance
ChemElectroChem,
Journal Year:
2024,
Volume and Issue:
12(3)
Published: Dec. 27, 2024
Abstract
In
an
era
where
renewable
energy
resources
are
pivotal
yet
plagued
by
variability,
vanadium‐cerium
(V‐Ce)
redox
flow
batteries
(RFBs)
present
a
sophisticated
solution
to
storage
and
grid
stability.
This
study
focuses
into
the
electrochemical
integration
of
cerium
with
vanadium
enhance
traditional
batteries′
density
cost‐effectiveness.
Through
innovative
design
that
allows
scalability
addresses
challenges
lower
inherent
in
RFBs,
V‐Ce
RFBs
demonstrate
potential
for
more
compact
efficient
systems.
this
work,
we
provide
open‐source
mono
cell
research.
Herein,
research
spotlights
characterization
Ce‐based
electrolytes,
employing
mixed
acid
electrolytes
improve
solubility.
For
improving
performance
including
diffusion
coefficients
electron
transfer
rates,
L–Leucine
L–Lysine
have
been
used
as
organic
additives.
Obtained
results
revealed
these
additives
not
only
influence
stability
efficiency
but
also
significantly
affect
charge‐discharge
properties
which,
L‐leucine
showing
superior
over
L‐lysine.
These
findings
propose
new
way
optimizing
large‐scale
regarding
efficiency,
safety,
environmental
impact.
