Halogen Engineering Strategy-Induced Color-Tunable Room Temperature Phosphorescence in Metal–Organic Halides DOI
Yaping Du, Qian Wang,

Meng-yuan Zhu

et al.

Inorganic Chemistry, Journal Year: 2024, Volume and Issue: 63(37), P. 17127 - 17133

Published: Sept. 3, 2024

Color-tunable room temperature phosphorescence (RTP) materials possess potential applications in multicolor imaging, multichannel anticounterfeiting, and information encryption. Herein, we synthesized two zero-dimensional cadmium-organic halides, (H-aepy)

Language: Английский

Lone Pairs-Mediated Multiple Through-Space Interactions for Efficient Room-Temperature Phosphorescence DOI
Fulong Ma, Bo Wu, Siwei Zhang

et al.

Journal of the American Chemical Society, Journal Year: 2025, Volume and Issue: unknown

Published: March 18, 2025

The simultaneous generation and stabilization of triplet excitons are the key to realizing efficient organic room temperature phosphorescence (RTP), which is challenging owing obscure mechanism structure-property relationships. Herein, a strategy lone-pair-mediated multiple through-space interactions (TSIs) proposed availably induce RTP. By incorporating heteroatoms facilitate n-n n-π interactions, lone pairs delocalized throughout structure, resulting in dense splitting excited-state energy levels. Thus, more matched levels with small gap between singlet states (ΔEST) emerge, intersystem crossing (ISC) transition channels that assist generation. strong TSIs also effectively rigidify molecular structures thus stabilize for radiation. Furthermore, manipulation TSI intensity allows efficiency enhancement, persistent time prolongation, tolerance high temperatures This work not only explores fundamental principle RTP from new view but provides universal ISC promotion triple stabilization.

Language: Английский

Citations

0
Advancements and Applications of Herbal Cocrystals DOI
Rajni Goyal, Pankaj Popli, Kashish Wilson

et al.

Published: March 29, 2025

Language: Английский

Citations

0
High-Temperature Phosphorescence of Carbon Dots by a Synergistic Locking Strategy DOI
Yuan Li,

Longchuang Li,

Ruiwen Shao

et al.

ACS Applied Materials & Interfaces, Journal Year: 2025, Volume and Issue: unknown

Published: April 7, 2025

Phosphorescent materials have potential applications in anticounterfeiting and optoelectronics, but their luminescence is generally quenched at elevated temperatures. Herein, a synergistic locking strategy has been developed to achieve high-temperature phosphorescence (HTP) of carbon dot (CD) composites. Impressively, the CD composites retain over 90% 75% intensity temperatures up 110 170 °C, respectively. Even higher than persists for 5 s, demonstrating remarkable stabilization triplet excitons. Experimental theoretical results revealed that this outstanding thermal resistance stems from effect interlayer covalent bridges multiple hydrogen bonding interface. Furthermore, by adjusting degree graphitization, multicolor HTP ranging blue red achieved This work not only provides facile versatile way construct CD-based also expands heat-resistant display environments.

Language: Английский

Citations

0
Organic Charge Transfer Complex Towards Functional Optical Materials DOI
Kalyan Jyoti Kalita,

Rakhi Arikkottira M,

Ratheesh K. Vijayaraghavan

et al.

CrystEngComm, Journal Year: 2024, Volume and Issue: 26(35), P. 4751 - 4765

Published: Jan. 1, 2024

The article highlights the recent developments on some interesting optical traits of organic charge transfer complexes. Properties like room temperature phosphorescence, thermally activated delayed fluorescence, circularly polarised luminescence, etc. , are summarized.

Language: Английский

Citations

3
Halogen Engineering Strategy-Induced Color-Tunable Room Temperature Phosphorescence in Metal–Organic Halides DOI
Yaping Du, Qian Wang,

Meng-yuan Zhu

et al.

Inorganic Chemistry, Journal Year: 2024, Volume and Issue: 63(37), P. 17127 - 17133

Published: Sept. 3, 2024

Color-tunable room temperature phosphorescence (RTP) materials possess potential applications in multicolor imaging, multichannel anticounterfeiting, and information encryption. Herein, we synthesized two zero-dimensional cadmium-organic halides, (H-aepy)

Language: Английский

Citations

2