We
demonstrated
the
selective
catalytic
NO
reduction
with
H
2
(H
-SCR)
over
Pt
nanoparticles
supported
on
a
monolayer
zirconium
phosphate
(ZrP)
nanosheet
derived
from
α-Zr(HPO
4
)
·H
O.
Catalysts,
Journal Year:
2025,
Volume and Issue:
15(3), P. 269 - 269
Published: March 12, 2025
Selective
catalytic
reduction
of
NOx
with
H2
(H2-SCR)
is
crucial
for
eliminating
emissions
from
hydrogen
internal
combustion
engines
(H2-ICE).
Although
1
wt.%
Pt/SSZ-13
(Pt/SZ)
a
promising
H2-SCR
catalyst,
it
faces
challenges
such
as
narrow
operating
window
and
low
N2
selectivity.
Herein,
the
effects
WO3
on
improving
performance
Pt/SZ
was
investigated.
Results
showed
that
incorporating
5
significantly
widened
temperature
80%
conversion
enhanced
selectivity
at
90–180
°C.
Several
characterizations
revealed
electrons
transfer
W
to
Pt,
so
more
active
Pt0
species
were
formed
Pt-5
W/SZ
(Pt-5W/SZ).
In
situ
diffuse
reflectance
infrared
Fourier
transform
spectroscopy
(DRIFTS)
analysis
indicated
monodentate
nitrates,
nitrites,
NH4+
generated
Pt-5W/SZ,
which
are
key
intermediates
formation.
Consequently,
windows
(over
80%)
70%)
by
65
°C
66
°C,
respectively.
This
work
provides
insights
into
developing
catalysts
broader
higher
Catalysts,
Journal Year:
2024,
Volume and Issue:
14(1), P. 75 - 75
Published: Jan. 17, 2024
With
increasing
environmental
awareness,
the
issue
of
atmospheric
pollution
has
gained
significant
attention.
Specifically,
three
types
pollutants,
namely,
nitrogen
oxides,
volatile
organic
compounds,
and
carbon
monoxide,
have
become
focus
widespread
concern.
In
addressing
these
mesoporous
zeolites
emerged
as
promising
materials
due
to
their
large
specific
surface
area,
which
enables
effective
dispersion
active
sites,
pore
volume,
facilitates
efficient
diffusion.
This
article
provides
a
comprehensive
overview
preparation
methods
applications
in
removing
monoxide.
It
also
highlights
challenges
limitations
faced
by
application
pollutant
removal
emphasizes
potential
catalysts.