Journal of Materials Chemistry A,
Journal Year:
2024,
Volume and Issue:
12(24), P. 14508 - 14516
Published: Jan. 1, 2024
The
introduction
of
CoP
could
efficiently
facilitate
the
electron
transfer
from
CN
towards
O
2
and
enrich
production
·O
−
,
which
was
indispensable
in
photocatalytic
H
S
oxidation.
Rationally
regulating
the
photogenerated
carrier
transfer
behavior
and
band
structure
of
TiO2
through
metal
doping
is
an
effective
strategy
for
enhancing
photocatalytic
activity
in
removal
malodorous
gas
hydrogen
sulfide
(H2S).
In
this
study,
modified
with
Group
IIIA
ions
(Al3+,
Ga3+,
In3+)
was
utilized
as
efficient
desulfurizer
under
ultraviolet
irradiation.
Among
these
samples,
4%
In-TiO2
exhibited
best
H2S
efficiency
100%
a
duration
120
min,
nearly
3
times
higher
than
that
commercial
P25
TiO2.
The
UV–vis
DRS
PL
spectra
demonstrated
incorporation
Group-IIIA
into
resulted
formation
shallow
acceptor
level
above
valence
energy
structure,
which
induced
slight
redshift
at
edge
visible
light
absorption
reduced
electron–hole
recombination
rate.
situ
DRIFTS
DFT
calculations
revealed
adsorption
activation
occurred
simultaneously
on
In-TiO2,
facilitated
by
its
strong
oxygen
vacancy
capability.
ln3+
promoted
photothermal-catalytic
oxidation
reaction
surfaces
thereby
significantly
desulfurization
H2S.
This
study
not
only
offers
deeper
understanding
regulated
ions,
but
also
provides
promising
green
Energy & Fuels,
Journal Year:
2024,
Volume and Issue:
38(17), P. 15972 - 15997
Published: Aug. 7, 2024
Acid
gas,
which
contains
toxic
hydrogen
sulfide,
is
produced
by
several
sources,
including
refineries
and
processing
plants
for
natural
gas.
Catalytic
decomposition
reforming
of
H2S
offer
viable
ways
to
produce
from
a
waste
resource,
with
the
added
benefit
reducing
pollution.
However,
conventional
thermolysis
traditional
Claus
process,
highly
endothermic
exhibits
low
conversion
at
reaction
temperatures.
While
photocatalytic
pathway
would
less
energy-intensive
pathway,
its
overall
efficiency
regarding
light/heat
absorption
utilization
needs
be
further
enhanced.
Hydrogen
sulfide
can
converted
via
photothermocatalysis
into
elemental
sulfur
hydrogen,
two
value-added
products.
This
process
addresses
drawbacks
pure
photo
thermal
procedures
could
approach
treating
streams.
study
extensively
examines
potential
interaction
between
photo-
thermocatalytic
systems,
concentrating
on
hydrogen.
The
aim
provide
valuable
insights
pathways
future
optimization.
For
first
time,
as
per
literature
survey,
photothermocatalytic
that
extended
both
reformation
toward
production
proposed,
considering
current
challenges
prospects.
Journal of Materials Chemistry A,
Journal Year:
2024,
Volume and Issue:
12(24), P. 14508 - 14516
Published: Jan. 1, 2024
The
introduction
of
CoP
could
efficiently
facilitate
the
electron
transfer
from
CN
towards
O
2
and
enrich
production
·O
−
,
which
was
indispensable
in
photocatalytic
H
S
oxidation.