Characterization and Optimization of Biodiesel Production from Corn Oil Using Heterogeneous X_Moo3/Mcm-41 Catalysts DOI

Jéssica Caroline Freitas Cavalcante,

André M. N. Silva,

PAULA MIKAELLY BATISTA CALDAS

et al.

Published: Jan. 1, 2024

Different types of heterogeneous catalysts have been developed globally and tested for biodiesel production via transesterification reaction. In this study, varying contents MoO3 were incorporated into the mesoporous molecular sieve MCM-41 using pore saturation method to form (x_ MoO3/MCM-41). Characterization results confirmed formation structure phase filling by molybdenum, along with different surface areas, volume, diameters. The silanol groups impart acidity sieve, a molybdenum content above optimum reduced availability acidic sites on catalyst surface, micro channels, resulting in lower acidity. Catalytic performance was evaluated 22 factorial design three center points optimize reaction parameters including x_MoO3 temperature. maximum yield 87.87%, achieved 3% load containing 15 wt.% MoO3, at an oil-to-alcohol molar ratio 1:20 150°C 3 hours. Temperature had most significant influence yield.

Language: Английский

Advancements in biodiesel production from castor oil: A comprehensive review DOI
Ana V. Veličković, Dragana Rajković, Jelena M. Avramović

et al.

Energy Conversion and Management, Journal Year: 2025, Volume and Issue: 330, P. 119622 - 119622

Published: Feb. 22, 2025

Language: Английский

Citations

1
Biodiesel production from waste cooking oil through transesterification catalyzed by the strontium-zinc bifunctional oxides DOI
Sitong Liu, Zhipeng Li, Kuihua Han

et al.

Chemical Engineering and Processing - Process Intensification, Journal Year: 2024, Volume and Issue: 200, P. 109777 - 109777

Published: April 4, 2024

Language: Английский

Citations

6
Kinetics, thermodynamics, and optimization studies using response surface methodology in quinoxalines synthesis with efficient heterogeneous catalysts: environmental sustainability metrics assessment DOI
Khadija Sadraoui,

Touayba Ahl El Haj,

Khalid El Mejdoubi

et al.

Research on Chemical Intermediates, Journal Year: 2024, Volume and Issue: 50(12), P. 5799 - 5821

Published: Oct. 7, 2024

Language: Английский

Citations

6
Reaction Mechanism of Rapid CO Electroreduction to Propylene and Cyclopropane (C3+) over Triple Atom Catalysts DOI
Mohsen Tamtaji, Soonho Kwon, Charles B. Musgrave

et al.

ACS Applied Materials & Interfaces, Journal Year: 2024, Volume and Issue: 16(38), P. 50567 - 50575

Published: June 26, 2024

The carbon monoxide reduction reaction (CORR) toward C2+ and C3+ products such as propylene cyclopropane can not only reduce anthropogenic emissions of CO CO2 but also produce value-added organic chemicals for polymer pharmaceutical industries. Here, we introduce the concept triple atom catalysts (TACs) that have three intrinsically strained active metal centers reducing to products. We applied grand canonical potential kinetics (GCP-K) screen 12 transition metals (M) supported by nitrogen-doped graphene denoted M3N7, where M stands Mn, Fe, Co, Ni, Cu, Ru, Rh, Pd, Ag, Ir, Pt, Au. sought with favorable binding, hydrogen C–C dimerization energetics, identifying Fe3N7 Ir3N7 best candidates. then studied entire mechanism from C3H6 C2H4 a function via, respectively, 12-electron 8-electron transfer pathways on Ir3N7. Density functional theory (DFT) predicts an overpotential 0.17 VRHE 0.42 at 298.15 K pH = 7. Also, DFT 0.15 ethylene. This work provides fundamental insights into design advanced synthesis room temperature.

Language: Английский

Citations

4
Experimental and Computational Investigations of Biodiesel Production from Castor Oil Using Li-Doped Salmon Fish Bone-Supported Lanthanum oxide Catalyst in a Micro-Reactor DOI

Samira Piran,

Mohammad Kazemeini, Erfan Mohebolkhames

et al.

Renewable Energy, Journal Year: 2024, Volume and Issue: unknown, P. 121455 - 121455

Published: Sept. 1, 2024

Language: Английский

Citations

1
Characterization and optimization of biodiesel production from corn oil using heterogeneous MoO3/MCM-41 catalysts DOI

Jéssica Caroline Freitas Cavalcante,

André Miranda da Silva,

Paula Mikaelly Batista Caldas

et al.

Catalysis Today, Journal Year: 2024, Volume and Issue: unknown, P. 115119 - 115119

Published: Oct. 1, 2024

Language: Английский

Citations

1
Experimental and Computational Investigations of Biodiesel Production from Castor Oil: Intensifying Transesterification with a Lithium-Doped Salmon Fish Bone-Supported Lanthanum Oxide Composite Catalyst in a Micro-Reactor DOI

Samira Piran,

Mohammad Kazemeini, Erfan Mohebolkhames

et al.

Published: Jan. 1, 2024

Ensuring efficient and sustainable biodiesel production is essential for addressing environmental concerns meeting global energy demands. This study aims to optimize the transesterification of castor oil through development a distinctive Li-doped salmon fish bone-supported La2O3 composite catalyst within micro-reactor setup. The optimal (3%Li/SFB-La) was thoroughly evaluated its physicochemical features employing range characterization techniques, including XRD, XPS, BET, FESEM, TEM, TGA/DSC, FT-IR. According DFT calculations, function Li dopants, which have lower electronegativity (0.98) compared La (1.1), enhance charge transfer capability sites, thereby increasing their reactivity with triglycerides. In interim, we determined optimized reaction conditions: 6:1 methanol/oil molar ratio 5 wt. % loading at 338 K. Under these parameters, an impressive 99.38% conversion achieved 1.5 hours. Furthermore, 3%Li/SFB-La exhibited remarkable stability, retaining high activity throughout 7 cycles without any significant loss efficacy. Moreover, kinetics were investigated, revealing rate constant 1.17 h−1 activation 14.46 kJ mol−1.

Language: Английский

Citations

0
Characterization and Optimization of Biodiesel Production from Corn Oil Using Heterogeneous X_Moo3/Mcm-41 Catalysts DOI

Jéssica Caroline Freitas Cavalcante,

André M. N. Silva,

PAULA MIKAELLY BATISTA CALDAS

et al.

Published: Jan. 1, 2024

Different types of heterogeneous catalysts have been developed globally and tested for biodiesel production via transesterification reaction. In this study, varying contents MoO3 were incorporated into the mesoporous molecular sieve MCM-41 using pore saturation method to form (x_ MoO3/MCM-41). Characterization results confirmed formation structure phase filling by molybdenum, along with different surface areas, volume, diameters. The silanol groups impart acidity sieve, a molybdenum content above optimum reduced availability acidic sites on catalyst surface, micro channels, resulting in lower acidity. Catalytic performance was evaluated 22 factorial design three center points optimize reaction parameters including x_MoO3 temperature. maximum yield 87.87%, achieved 3% load containing 15 wt.% MoO3, at an oil-to-alcohol molar ratio 1:20 150°C 3 hours. Temperature had most significant influence yield.

Language: Английский

Citations

0