Journal of Molecular Structure, Journal Year: 2024, Volume and Issue: unknown, P. 140270 - 140270
Published: Oct. 1, 2024
Language: Английский
Journal of Molecular Structure, Journal Year: 2024, Volume and Issue: unknown, P. 140270 - 140270
Published: Oct. 1, 2024
Language: Английский
Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy, Journal Year: 2024, Volume and Issue: 318, P. 124386 - 124386
Published: May 3, 2024
Language: Английский
Citations
3Journal of Molecular Structure, Journal Year: 2024, Volume and Issue: 1317, P. 139108 - 139108
Published: June 24, 2024
Language: Английский
Citations
3Journal of Molecular Structure, Journal Year: 2024, Volume and Issue: 1318, P. 139287 - 139287
Published: July 14, 2024
Language: Английский
Citations
3Applied Organometallic Chemistry, Journal Year: 2025, Volume and Issue: 39(3)
Published: Feb. 5, 2025
ABSTRACT A cube‐like heptanuclear cobalt(II) cluster single crystals, namely, [Co 7 (L) 2 ( μ 3 ‐OCH ) ‐OH) 4 ](ClO , was successfully grown up by reacting of a bis(salamo)‐type ligand H L containing two N O coordination cavities with Co(NO ·6H using natural volatilization method. Single‐crystal analysis displayed that the is cluster. In this paper, UV–Vis absorption and fluorescence spectra its have been investigated. Through Hirshfeld surface analyses, intermolecular interactions on molecular surfaces are visually presented, contributions each interaction to quantified two‐dimensional fingerprints. DFT calculation MEP analyses used investigate electronic structures sites
Language: Английский
Citations
0Journal of Molecular Structure, Journal Year: 2025, Volume and Issue: unknown, P. 141846 - 141846
Published: Feb. 1, 2025
Language: Английский
Citations
0Journal of Molecular Structure, Journal Year: 2024, Volume and Issue: 1311, P. 138481 - 138481
Published: April 30, 2024
Language: Английский
Citations
3Chemical Papers, Journal Year: 2024, Volume and Issue: 78(12), P. 7001 - 7013
Published: July 2, 2024
Language: Английский
Citations
2Journal of Molecular Structure, Journal Year: 2024, Volume and Issue: 1320, P. 139692 - 139692
Published: Aug. 22, 2024
Language: Английский
Citations
2Journal of Molecular Structure, Journal Year: 2024, Volume and Issue: 1321, P. 140191 - 140191
Published: Sept. 26, 2024
Language: Английский
Citations
2Applied Organometallic Chemistry, Journal Year: 2024, Volume and Issue: 39(1)
Published: Sept. 27, 2024
ABSTRACT A mono‐salamo‐type ligand H 2 L was prepared to utilize 3‐methoxysalicylaldehyde and a semi‐salamo‐type compound, its novel trinuclear Ni(II) cluster with two significantly various configurations in the solid state obtained by reaction of ions. The structure validated x‐ray technique, ions exhibited hexa‐coordinated twisted octahedrons. Its structural formula is [Ni 3 (L) ( μ ‐Cl) (EtOH) ]. Chloride have also successfully double bridged participate coordination, play critical impact configuration's stability charge balance. Two solvent ethanol molecules are participated coordination. coordination ratio metal ion verified be 2:3 UV–Vis absorption titration spectroscopy. HOMO LUMO energies frontline molecular orbitals complex were analyzed DFT calculations, energy gap value 4.29 eV, that 0.72 eV. combined decreased produced more active complex. Furthermore, Hirshfeld surface analysis visualizes weak interactions crystalline molecules, these abundant an especially effect supramolecular self‐assembling. fluorescent researches proclaimed fluorescence intensity compared ligand, suggesting this greater promise for sensing.
Language: Английский
Citations
2