Inorganica Chimica Acta, Journal Year: 2025, Volume and Issue: unknown, P. 122745 - 122745
Published: May 1, 2025
Language: Английский
Inorganica Chimica Acta, Journal Year: 2025, Volume and Issue: unknown, P. 122745 - 122745
Published: May 1, 2025
Language: Английский
Journal of Molecular Structure, Journal Year: 2025, Volume and Issue: unknown, P. 142292 - 142292
Published: April 1, 2025
Citations
0Process Safety and Environmental Protection, Journal Year: 2025, Volume and Issue: unknown, P. 107094 - 107094
Published: April 1, 2025
Language: Английский
Citations
0Water Research, Journal Year: 2025, Volume and Issue: 282, P. 123658 - 123658
Published: April 15, 2025
Language: Английский
Citations
0Chinese Journal of Structural Chemistry, Journal Year: 2025, Volume and Issue: unknown, P. 100603 - 100603
Published: April 1, 2025
Language: Английский
Citations
0Inorganic Chemistry, Journal Year: 2025, Volume and Issue: unknown
Published: May 3, 2025
It is of great research value to develop an efficient and stable catalyst that can achieve the oxidation alkenes obtain epoxides, which serve as a multifunctional intermediate with important commercial value. Based on this, three-dimensional (3D) supramolecular framework H[CuI(H3bdcbpy)2(Mo12O38)(H2O)] (1, H4bdcbpy·2Cl = N,N'-bis(3,5-dicarboxybenzyl-4,4'-bipyridine·dichloride) was obtained from carboxylate-functionalized 1D coordination polymers, were derived unusual in situ [Mo12O38]4- cluster Cu-electron-deficient carboxylate complex units. The catalytic performance 1 epoxidation using TBHP examined, revealing its remarkable efficiency conversion cis-cyclooctene, high rate 99% outstanding selectivity 100%. Complex exhibited higher activity than unmodified H4bdcbpy·2Cl, CuCl2·2H2O, Na2MoO4·2H2O, well most previously reported polyoxometalate (POM)-based metal-organic complexes (POMOCs). Moreover, reaction kinetics mechanism explored free radical trapping experiments control experiments. stability also investigated.
Language: Английский
Citations
0Journal of Molecular Structure, Journal Year: 2025, Volume and Issue: unknown, P. 142624 - 142624
Published: May 1, 2025
Language: Английский
Citations
0Inorganica Chimica Acta, Journal Year: 2025, Volume and Issue: unknown, P. 122745 - 122745
Published: May 1, 2025
Language: Английский
Citations
0