A perspective on mechanism of high-current–density electrocatalytic CO2 reduction DOI

Yumo Chen,

Shuqi Hu, Xin Kang

et al.

MRS Energy & Sustainability, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 6, 2025

Language: Английский

Recent advances in the mechanism and catalyst design in the research of aprotic, photo-assisted, and solid-state Li–CO2 batteries DOI
Haixia Chen,

Xijuan Li,

Hairong Xue

et al.

Inorganic Chemistry Frontiers, Journal Year: 2024, Volume and Issue: 11(18), P. 5833 - 5857

Published: Jan. 1, 2024

This review focuses on the reaction mechanisms and cathodic catalysts for various types of LCBs, including aprotic, photo-assisted, all-solid-state offering insights suggestions to advance their research development.

Language: Английский

Citations

4
Catalyst Design and Engineering for CO2‐to‐Formic Acid Electrosynthesis for a Low‐Carbon Economy DOI

Karthik Peramaiah,

Moyu Yi,

Indranil Dutta

et al.

Advanced Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Oct. 12, 2024

Abstract Formic acid (FA) has emerged as a promising candidate for hydrogen energy storage due to its favorable properties such low toxicity, flammability, and high volumetric capacity under ambient conditions. Recent analyses have suggested that FA produced by electrochemical carbon dioxide (CO 2 ) reduction reaction (eCO RR) using low‐carbon electricity exhibits lower fugitive (H emissions global warming potential (GWP) during the H carrier production, transportation processes compared those of other alternatives like methanol, methylcyclohexane, ammonia. eCO RR can enable industrially relevant current densities without need pressures, temperatures, or auxiliary sources. However, widespread implementation is hindered requirement highly stable selective catalysts. Herein, aim explore evaluate catalyst engineering in designing nanostructured catalysts facilitate economically viable production FA.

Language: Английский

Citations

4
Boosting Formate Production in Electrocatalytic CO2 Reduction on Bimetallic Catalysts Enriched with In–Zn Interfaces DOI
Ruirui Zhao, Huihua Luo,

Ting Ouyang

et al.

ACS Nano, Journal Year: 2024, Volume and Issue: 18(52), P. 35749 - 35757

Published: Dec. 18, 2024

We present an effective strategy for developing the dispersing strong-binding metal In on surface of weak-binding Zn, which modulates binding energy reaction intermediates and further facilitates efficient conversion CO2 to formate. The In-Zn interface (In-Zn2) benefits from formation active sites through favorable orbital interactions, leading a Faradaic efficiency 82.7% formate partial current density 12.39 mA cm-2, along with stable performance over 15 h at -1.0 V versus reversible hydrogen electrode. Both in situ Fourier transform infrared spectroscopy functional theory calculations show that bimetallic catalyst can deliver superior *OCHO intermediate, thereby fundamentally accelerating addition, exposed promotes capture activation molecules dynamics within significantly reduce barrier associated generation HCOO-, thus augmenting selectivity catalytic activity generation.

Language: Английский

Citations

4
Electrodeposition of Bismuth Dendrites on Oxide-Derived Copper Foam Enhancing Electrochemical CO2 Reduction to Formate DOI Open Access

Jialin Xu,

Li Lv, Chunlai Wang

et al.

Catalysts, Journal Year: 2025, Volume and Issue: 15(1), P. 52 - 52

Published: Jan. 8, 2025

The electrochemical CO2 reduction reaction (CO2RR) to formate offers a promising pathway mitigate the energy crisis and realize carbon neutrality. Bismuth (Bi), as metal catalyst for CO2RR, is considered have great potential in producing formate, yet hindered low current density selectivity. Herein, we constructed an oxide-derived copper foam substrate (OD-Cu) improve electrocatalytic properties of Bi dendrites loaded on its surface. electrodeposited OD-Cu (Bi/OD-Cu) grows pinecone-like dendrites, exhibiting high faradaic efficiency (FEformate) 97.2% partial ~24 mA·cm−2 at −0.97 V vs. RHE (reversible hydrogen electrode) H-cell. Notably, Bi/OD-Cu electrode demonstrates FEformate 95.8% total close 90 −1.17 neutral flow cell. experimental studies reveal that remarkable CO2RR performance results from electron transfer Cu Bi, which optimizes adsorption CO2•− boosts kinetics. This study emphasizes crucial role engineering strategies enhancing catalytic activity shows possibility porous advancing industrialization production.

Language: Английский

Citations

0
Hydroxide-Oxide-Sulfur-Stabilized Bismuth Nanorod Conversion: Selective Induction of the Electrochemical Reduction of CO2 to Formate DOI

Naveenkumar Palanimuthu,

Ramasamy Santhosh Kumar,

Saleem Sidra

et al.

ACS Applied Nano Materials, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 14, 2025

The electrochemical CO2 reduction reaction (e-CO2RR) converts value-added chemicals into formate. Bismuth-based resources exhibit promising potential in the of to formate due their low toxicity and ability enhance *OCHO intermediate pathway. However, there are numerous hurdles optimizing activity applicability. Here, we describe assembly structurally stable bismuth hydroxide, oxide, sulfide nanorods supported by a reduced graphene oxide (rGO) nanosheet through simple hydrothermal method. obtained optimized rGO-Bi2S3 improved e-CO2RR conversions H-cell systems compared hydroxide electrocatalysts. maintain high within wide window (−0.76 −1.26 V vs RHE) obtain overall Faradaic efficiency ±84% at −1.16 RHE, current density ±41.50 mA cm–2, stability for longer than 12 h, with greater ±86% an system. Theoretical calculations reveal that strong interaction between rGO Bi2S3 stabilizes adsorption e-CO2RR. resulting structural transformation based on sulfur, provides encouraging avenue future energy conversion.

Language: Английский

Citations

0
Boron-Doped Oxidized Carbon Black Hybridizing Bismuth Oxide for Electrocatalytic CO2 to Formate at a Large Current Density DOI
Yujie Cao, Xiaoling Liu,

Mingdong Sun

et al.

Industrial & Engineering Chemistry Research, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 12, 2025

Language: Английский

Citations

0
Electrodeposition of Bi Nanocomposite with Mil-101 Derived Carbon as Gas Diffusion Layer for Co2 Electroreduction with Enhanced Formate Generation DOI

Xuetong Liu,

Chi Zhang,

Nuoyan Li

et al.

Published: Jan. 1, 2025

Language: Английский

Citations

0
Fabrication of Bi/S-Bi2O2CO3 plasmon heterojunction with sulfur-activated enhancement for photocatalysis DOI

Chao-Wei Luo,

Mengchen Liao, Jie Xiong

et al.

Colloids and Surfaces A Physicochemical and Engineering Aspects, Journal Year: 2025, Volume and Issue: 713, P. 136464 - 136464

Published: March 1, 2025

Language: Английский

Citations

0
Achieving Current Density of 815 mA/cm² for Electrochemical CO₂ Reduction to Formate by Enhancing ⁎OCHO Intermediate Adsorption through Intercalated Bi Single Atoms in BiOBr DOI
Huawang Zhao, Yuxin Xie, Bihong Lv

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2025, Volume and Issue: unknown, P. 125234 - 125234

Published: March 1, 2025

Language: Английский

Citations

0
In situ construction of a crystalline/amorphous interface in SnO2/Bi nanobelts for efficient CO2 electroreduction DOI
Hanjun Li, Guangtong Hai, Zhenyu Wang

et al.

Journal of Materials Chemistry A, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

Crystalline/amorphous SnO 2 /Bi nanobelts (C/A-SnO NBs) were prepared via an in situ electrochemical dynamic reconstruction strategy for efficient CO electroreduction.

Language: Английский

Citations

0