Hypervalent iodine-mediated intramolecular alkene halocyclisation DOI Creative Commons
Charu Bansal,

Oliver Ruggles,

Albert C. Rowett

et al.

Beilstein Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: 20, P. 3113 - 3133

Published: Nov. 28, 2024

The chemistry of hypervalent iodine (HVI) reagents has gathered increased attention towards the synthesis a wide range chemical structures. HVI are characterized by their diverse reactivity as oxidants and electrophilic reagents. In addition, they inexpensive, non-toxic considered to be environmentally friendly. An important application is halogenated cyclic compounds, in particular, intramolecular HVI-mediated halocyclisation alkenes using carbon, oxygen, nitrogen or sulfur nucleophiles. Herein, we describe examples reported literature, which organised different halogens involved internal

Language: Английский

Divergent role of PIDA and PIFA in the AlX3 (X = Cl, Br) halogenation of 2-naphthol: a mechanistic study DOI Creative Commons
Kevin A. Juárez‐Ornelas, Manuel Solís-Hernández, Pedro Navarro‐Santos

et al.

Beilstein Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: 20, P. 1580 - 1589

Published: July 15, 2024

The reaction mechanism for the chlorination and bromination of 2-naphthol with PIDA or PIFA AlX

Language: Английский

Citations

3
Hypervalent iodine-mediated intramolecular alkene halocyclisation DOI Creative Commons
Charu Bansal,

Oliver Ruggles,

Albert C. Rowett

et al.

Beilstein Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: 20, P. 3113 - 3133

Published: Nov. 28, 2024

The chemistry of hypervalent iodine (HVI) reagents has gathered increased attention towards the synthesis a wide range chemical structures. HVI are characterized by their diverse reactivity as oxidants and electrophilic reagents. In addition, they inexpensive, non-toxic considered to be environmentally friendly. An important application is halogenated cyclic compounds, in particular, intramolecular HVI-mediated halocyclisation alkenes using carbon, oxygen, nitrogen or sulfur nucleophiles. Herein, we describe examples reported literature, which organised different halogens involved internal

Language: Английский

Citations

0