Aryne Alder-Ene Reaction Enables Arylation of Conformationally Locked Styrenes DOI
Tamal Ballav, S. C. Barman, Venkataraman Ganesh

et al.

Organic Letters, Journal Year: 2025, Volume and Issue: unknown

Published: April 15, 2025

We report a transition metal-free aryne Alder-ene (AAE) reaction of conformationally locked styrenes like methylene indane (5,6-fusion) and tetralin (6,6-fusion) to provide aryl-decorated indenes dihydronaphthalenes. DFT studies compared the states between 5,6- 6,6-fused systems. The synthetic utility products was demonstrated.

Language: Английский

Aryne Alder-Ene Reaction Enables Arylation of Conformationally Locked Styrenes DOI
Tamal Ballav, S. C. Barman, Venkataraman Ganesh

et al.

Organic Letters, Journal Year: 2025, Volume and Issue: unknown

Published: April 15, 2025

We report a transition metal-free aryne Alder-ene (AAE) reaction of conformationally locked styrenes like methylene indane (5,6-fusion) and tetralin (6,6-fusion) to provide aryl-decorated indenes dihydronaphthalenes. DFT studies compared the states between 5,6- 6,6-fused systems. The synthetic utility products was demonstrated.

Language: Английский

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