Al Promotion of In2O3 for CO2 Hydrogenation to Methanol DOI Creative Commons
Liang Liu,

Brahim Mezari,

Nikolay Kosinov

et al.

ACS Catalysis, Journal Year: 2023, Volume and Issue: 13(24), P. 15730 - 15745

Published: Nov. 22, 2023

In2O3 is a promising catalyst for the hydrogenation of CO2 to methanol, relevant renewable energy storage in chemicals. Herein, we investigated promoting role Al on using flame spray pyrolysis prepare series In2O3–Al2O3 samples single step (0–20 mol % Al). promoted methanol yield, with an optimum being observed at content 5 %. Extensive characterization showed that can dope into lattice (maximum ∼ 1.2 %), leading formation more oxygen vacancies involved adsorption and formation. The rest present as small Al2O3 domains surface, blocking active sites contributing higher CO selectivity. At (≥10 Al), particle size decreases due stabilizing effect Al2O3. Nevertheless, these smaller particles are prone sintering during since they appear be easily reduced. These findings show subtle effects structural promoter such reducibility texture catalyst.

Language: Английский

Role of oxygen vacancy in metal oxides for photocatalytic CO2 reduction DOI
Wenbin Jiang,

Hongyi Loh,

Beverly Qian Ling Low

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2022, Volume and Issue: 321, P. 122079 - 122079

Published: Oct. 17, 2022

Language: Английский

Citations

226
Atomic Pd-promoted ZnZrO solid solution catalyst for CO2 hydrogenation to methanol DOI
Kyungho Lee,

Uzma Anjum,

Thaylan Pinheiro Araújo

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2021, Volume and Issue: 304, P. 120994 - 120994

Published: Dec. 9, 2021

Language: Английский

Citations

114
Flame-made ternary Pd-In2O3-ZrO2 catalyst with enhanced oxygen vacancy generation for CO2 hydrogenation to methanol DOI Creative Commons
Thaylan Pinheiro Araújo, Cecilia Mondelli, Mikhail Agrachev

et al.

Nature Communications, Journal Year: 2022, Volume and Issue: 13(1)

Published: Sept. 24, 2022

Palladium promotion and deposition on monoclinic zirconia are effective strategies to boost the performance of bulk In2O3 in CO2-to-methanol could unlock superior reactivity if well integrated into a single catalytic system. However, harnessing synergic effects individual components is crucial very challenging as it requires precise control over their assembly. Herein, we present ternary Pd-In2O3-ZrO2 catalysts prepared by flame spray pyrolysis (FSP) with remarkable methanol productivity improved metal utilization, surpassing binary counterparts. Unlike established impregnation co-precipitation methods, FSP produces materials combining low-nuclearity palladium species associated monolayers highly dispersed ZrO2 carrier, whose surface partially transforms from tetragonal monoclinic-like structure upon reaction. A pioneering protocol developed quantify oxygen vacancies using situ electron paramagnetic resonance spectroscopy reveals enhanced generation because this unique catalyst architecture, thereby rationalizing its high sustained productivity.

Language: Английский

Citations

107
Catalytic Hydrogenation of CO2 to Methanol: A Review DOI Open Access
Menghao Ren, Yanmin Zhang, Xuan Wang

et al.

Catalysts, Journal Year: 2022, Volume and Issue: 12(4), P. 403 - 403

Published: April 6, 2022

High-efficiency utilization of CO2 facilitates the reduction concentration in global atmosphere and hence alleviation greenhouse effect. The catalytic hydrogenation to produce value-added chemicals exhibits attractive prospects by potentially building energy recycling loops. Particularly, methanol is one practically important objective products, synthesize has been extensively studied. In this review, we focus on some basic concepts activation, recent research advances methanol, development high-performance catalysts, microscopic insight into reaction mechanisms. Finally, thinking present possible future trend presented.

Language: Английский

Citations

91
Highly active Pt/In2O3-ZrO2 catalyst for CO2 hydrogenation to methanol with enhanced CO tolerance: The effects of ZrO2 DOI Open Access
Kaihang Sun, Chenyang Shen, Rui Zou

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2022, Volume and Issue: 320, P. 122018 - 122018

Published: Sept. 24, 2022

Language: Английский

Citations

82
CO2 Hydrogenation to Methanol on Indium Oxide-Supported Rhenium Catalysts: The Effects of Size DOI
Chenyang Shen, Kaihang Sun, Rui Zou

et al.

ACS Catalysis, Journal Year: 2022, Volume and Issue: 12(20), P. 12658 - 12669

Published: Oct. 4, 2022

In this work, CO2 hydrogenation over In2O3-supported rhenium (Re) catalysts was found to be highly size-dependent. When the Re loading less than 1 wt %, strong interaction between and In2O3 caused atomically dispersed species with a positive charge, resulting in high activity for methanol enhanced stability at elevated temperatures. The space–time yield of % Re/In2O3 catalyst reached 0.54 gMeOH gcat–1 h–1 selectivity 72.1% 5 MPa 573 K. With increasing loading, supported become more favored methanation. Under same experimental conditions, methane is close 100.0% 10 catalyst. Catalyst characterizations density functional theoretical (DFT) calculations further confirm that size has significant effect on hydrogen activation reaction. Due Re–In2O3 interaction, surface lattice not only stabilizes oxygen vacancies but also results Hδ+ formation upon adsorption. This significantly promotes synthesis from hydrogenation. Meanwhile, nanoclusters induces Hδ- formation, which eventually leads production. present study demonstrates promising methanol.

Language: Английский

Citations

79
Atomic Structural Origin of the High Methanol Selectivity over In2O3–Metal Interfaces: Metal–Support Interactions and the Formation of a InOx Overlayer in Ru/In2O3 Catalysts during CO2 Hydrogenation DOI
Ning Rui, Xuelong Wang, Kaixi Deng

et al.

ACS Catalysis, Journal Year: 2023, Volume and Issue: 13(5), P. 3187 - 3200

Published: Feb. 17, 2023

CO2 hydrogenation to methanol is of great environmental and economic interest due its potential reduce carbon emissions produce valuable chemicals in one single reaction. Compared with the unmodified traditional Cu/ZnO/Al2O3 catalyst, an indium oxide (In2O3)-based catalyst can double selectivity from 30–50 60–100%. It worth noting that over catalysts involving various active metals dispersed on (M/In2O3, M = Pd, Ni, Au, etc.), although yield boosted, remains similar plain In2O3 despite distinct chemical properties added metals. To investigate phenomena behind this behavior, here we used RuO2/In2O3 as a test catalyst. The results ambient pressure photoelectron spectroscopy, situ X-ray absorption fine structure, time-resolved diffraction indicate structure highly dynamic presence reactive environment. Specifically, under conditions, Ru clusters facilitate reduction generate In2O3–x aggregates, which encapsulate systems migration driven by thermodynamics. In way, Ru0 sites for CH4 production are blocked while creating RuOx–In2O3–x interfacial tunable metal–oxide interactions selective production. inverse oxide/metal configuration, has not seen bulk phase useful binding conversion CO2. This work reveals nature In2O3-based catalysts, providing insights rational design materials synthesis methanol.

Language: Английский

Citations

75
Catalytic CO2 conversion to C1 value-added products: Review on latest catalytic and process developments DOI Creative Commons
Noor Yusuf, Fares Almomani, Hazim Qiblawey

et al.

Fuel, Journal Year: 2023, Volume and Issue: 345, P. 128178 - 128178

Published: April 3, 2023

With the increase in CO2 emissions last decades, capture and storage utilization technologies have been interesting topics literature industry. direct for oil gas recovery is a mature route focus of many technological academic studies its potential as source carbon producing value-added chemical products synthetic fuels. are grouped based on production route, such electrochemical, catalytic, photocatalytic, photosynthetic, biological, depolymerization. This review discusses latest innovations catalyst developments to C1 Amongst various products, conversion dimethyl carbonates, methanol, formic acid, syngas, methane using different homogenous heterogeneous catalytic systems was discussed. The most recent advancements process exploitations were highlighted each evaluate maturity proposed technically economically. revealed that thermally-driven synthesis promising industrial deployment. Furthermore, Green hydrogen cost energy key obstacles large-scale deployments utilization. However, supported by renewable production, discussed routes would be more applicable near future.

Language: Английский

Citations

68
Recent advancements and perspectives of the CO2 hydrogenation reaction DOI Creative Commons

Wenhang Wang,

Chunyang Zeng,

Noritatsu Tsubaki

et al.

Green Carbon, Journal Year: 2023, Volume and Issue: 1(2), P. 133 - 145

Published: Oct. 23, 2023

Owing to excessive carbon dioxide (CO2) emissions, which cause severe environmental issues, the conversion and utilization of CO2 have received increasing attention. its high efficiency potential for industrial applications, converting into value-added chemicals via thermocatalytic hydrogenation is a highly effective route among electrocatalytic, photocatalytic, conversion. In past two decades, our group has developed novel technologies produce such as aliphatic hydrocarbons, methanol (MeOH), ethanol, aromatics (especially para-xylene, PX). this review, we summarize strategy rational design catalysts, including low-temperature MeOH synthesis capsule catalysts tandem catalysis. We also discuss challenges opportunities hydrogenation, capture, H2 prices, taxes. hope inspire new ideas through exploration reaction paths.

Language: Английский

Citations

57
Metal oxides heterojunction derived Bi-In hybrid electrocatalyst for robust electroreduction of CO2 to formate DOI

Runze Ye,

Jiaye Zhu,

Yun Tong

et al.

Journal of Energy Chemistry, Journal Year: 2023, Volume and Issue: 83, P. 180 - 188

Published: May 3, 2023

Language: Английский

Citations

52