Machine learning-driven discovery of high-performance hole-conducting organic materials for solar cells and synthetic accessibility assessment DOI

Jameel Ahemd Bhutto,

Zia-ur Rahman, Muhammad Aamir

et al.

Chemical Engineering Science, Journal Year: 2025, Volume and Issue: unknown, P. 121748 - 121748

Published: April 1, 2025

Language: Английский

Annual research review of perovskite solar cells in 2023 DOI Creative Commons

Qisen Zhou,

Xiaoxuan Liu, Zonghao Liu

et al.

Materials Futures, Journal Year: 2024, Volume and Issue: 3(2), P. 022102 - 022102

Published: April 24, 2024

Abstract Perovskite (PVK) solar cells (PSCs) have garnered considerable research interest owing to their cost-effectiveness and high efficiency. A systematic annual review of the on PSCs is essential for gaining a comprehensive understanding current trends. Herein, analysis papers reporting key findings in 2023 was conducted. Based results, were categorized into six classifications, including regular n–i–p PSCs, inverted p–i–n PVK-based tandem cells, PVK modules, device stability, lead toxicity green solvents. Subsequently, detailed overview summary advancements within each classification presented. Overall, this serves as valuable resource guiding future endeavors field PSCs.

Language: Английский

Citations

20
Unveiling the Intrinsic Photophysics in Quasi-Two-Dimensional Perovskites DOI
Bohan Li, Haipeng Di, Huang Li

et al.

Journal of the American Chemical Society, Journal Year: 2024, Volume and Issue: 146(10), P. 6974 - 6982

Published: Feb. 28, 2024

The two-dimensional (2D) perovskites have drawn intensive attention due to their unique stability and outstanding optoelectronic properties. However, the debate surrounding spatial phase distribution band alignment among different 2D phases in quasi-2D perovskite has created complexities understanding carrier dynamics, hindering material device development. In this study, we employed highly sensitive transient absorption spectroscopy investigate dynamics of (BA)2(MA)n−1PbnI3n+1 Ruddlesden–Popper thin films, nominally prepared as n = 4. We observed carrier-density-dependent electron hole transfer between three-dimensional (3D) phases. Under a low density within linear response range, successfully resolved three ultrafast processes both transfers, spanning from hundreds femtoseconds several picoseconds, tens picoseconds nanoseconds, which can be attributed lateral-epitaxial, partial-epitaxial, disordered-interface heterostructures 3D By considering interplay structure, alignment, proposed synthesis strategies aimed at enhancing transport. Our results not only provide deep insights into an accurate intrinsic photophysics but also inspire advancements practical application these materials.

Language: Английский

Citations

15
Optimization Charge-Carrier Properties of 2D Ruddlesden–Popper Perovskite for Solar Cells DOI
Ting Zhang,

Zhipeng Miao,

Rudai Zhao

et al.

ACS Energy Letters, Journal Year: 2024, Volume and Issue: 9(5), P. 2248 - 2256

Published: April 17, 2024

Two-dimensional (2D) perovskites are tailored-photoelectric-responsive materials owing to their lattice softness and designable multifunctional spacer cations. However, the inferior charge-carrier characteristics in these 2D systems intolerable for photovoltaic devices. Here, we introduced a novelty cation 3,3-difluoropyrrolidinium (DFP) synthesize Ruddlesden–Popper (RP) perovskite, (DFP)2PbI4. The multiple hydrogen bonds spacing region of (DFP)2PbI4 drive structure toward uniqueness with average Pb─I─Pb bond angles over 170°. This merit coupled large dipole moment DFP demonstrates unique bandgap (2.20 eV) small exciton binding energies (99.76 meV) With stacking inorganic layers, (DFP)2MA4Pb5I16 (MA+: CH3NH3+) film demonstrated an improved electron diffusion length (920 nm) fast carrier extraction (0.73 μs) at device level. resultant solar cells achieved champion power conversion efficiency (PCE) 19.43%. Furthermore, unencapsulated devices exhibited excellent stability under continuous illumination persistent heating conditions.

Language: Английский

Citations

15
Generation of library of dyes for photovoltaic applications: A machine learning assisted framework DOI
Nafees Ahmad, Bandar R. Alsehli, Asif Mahmood

et al.

Journal of Photochemistry and Photobiology A Chemistry, Journal Year: 2024, Volume and Issue: unknown, P. 116053 - 116053

Published: Sept. 1, 2024

Language: Английский

Citations

9
Interface Engineering with KI Modifier Enhances Performance of CsPbBr3 Perovskite Solar Cells DOI

Ruowei He,

Zhihang Jin,

Xuanheng Chen

et al.

Materials Research Bulletin, Journal Year: 2025, Volume and Issue: 186, P. 113332 - 113332

Published: Feb. 6, 2025

Language: Английский

Citations

1
Computational design of new polymers having low exciton binding energy for organic solar cells fabrication: Chemical generation and visualization DOI
Fatimah Mohammed Alzahrani, Alvi Muhammad Rouf, Jawayria Najeeb

et al.

Journal of Photochemistry and Photobiology A Chemistry, Journal Year: 2024, Volume and Issue: 450, P. 115457 - 115457

Published: Jan. 4, 2024

Language: Английский

Citations

5
Structural Tailoring the Phenylenediamine Isomers to Obtain 2D Dion–Jacobson Tin Perovskite Solar Cells with Record Efficiency DOI
Huanhuan Yao, Tai‐Sing Wu, Cheng Wu

et al.

Advanced Functional Materials, Journal Year: 2023, Volume and Issue: 34(12)

Published: Dec. 14, 2023

Abstract 2D Dion–Jacobson (DJ) tin halide perovskite shows impressive stability by introducing diamine organic spacer. However, due to the dielectric confinement and uncontrollable crystallization process, DJ usually exhibits large exciton binding energy poor film quality, resulting in unfavorable charge dissociation, carrier transport device performance. Here, ortho ‐, meta para ‐isomers of phenylenediamine (PDA) are designed for perovskites. Theoretical simulation experimental characterizations demonstrate that compared with p ‐PDA m ‐PDA, o larger dipole moment, which further reduces Besides, there is a strong hydrogen bond interaction between cation inorganic octahedron, not only improves structural stability, but also induces aggregates precursor form dense uniform high‐quality films, strengthens antioxidant barrier. More interestingly, femtosecond transient absorption proves spacers can reduce small n‐phases, sufficient effective transfer different n‐value. As result, ( ‐PDA)FA 3 Sn 4 I 13 solar cells achieve record power conversion efficiency 7.18%. The study furnishes an method optimize performance tailoring chemical structure spacers.

Language: Английский

Citations

12
Progress of 2D Perovskite Solar Cells: Structure and Performance DOI Open Access
Liyan Yang,

Xiaofang Li,

Mufang Li

et al.

Small, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 2, 2025

Abstract 2D perovskite has demonstrated great potential for application in photovoltaic devices due to the tunable energy bands, suppressed ion migration, and high stability. However, solar cells (PSCs) display suboptimal efficiency comparison 3D cells, which can be attributed quantum confinement dielectric effects resulting from intercalation of organic spacer cations into lattice. This review starts with fundamental structural characteristics, optoelectronic properties, carrier transport dynamics PSCs, followed by discussion approaches improve performance including manipulation crystal orientation, phase distribution, pure phase, layer, device engineering. Then advancements structural, humidity, thermal, maximum power point tracking stability PSCs are summarized. Afterward, applications 2/3D discussed. provides a comprehensive understanding relationship between structure as well offers insights constructing efficient stable integrating perovskites.

Language: Английский

Citations

0
Data-driven designing of conjugated organic chromophores: chemical space generation and property prediction DOI
Numan Khan, Mahmoud A. A. Ibrahim, Shaban R. M. Sayed

et al.

Journal of Solid State Chemistry, Journal Year: 2025, Volume and Issue: unknown, P. 125201 - 125201

Published: Jan. 1, 2025

Language: Английский

Citations

0
Dielectric constant prediction of polymers for organic solar cells and generation of library of new organic compounds DOI
Mudassir Hussain Tahir, Mahmoud A. A. Ibrahim, Shaban R. M. Sayed

et al.

Journal of Solid State Chemistry, Journal Year: 2025, Volume and Issue: unknown, P. 125213 - 125213

Published: Jan. 1, 2025

Language: Английский

Citations

0