Angewandte Chemie,
Journal Year:
2024,
Volume and Issue:
136(26)
Published: April 15, 2024
Abstract
The
synthesis
and
characterization
of
porphyrin
center
regulated
three‐dimensional
covalent
organic
frameworks
(COFs)
with
2‐fold
interpenetrated
scu
or
sqc
topology
have
been
investigated.
These
COFs
exhibit
unique
structural
features
properties,
making
them
promising
candidates
for
photocatalytic
applications
in
CO
2
reduction
artemisinin
synthesis.
serves
as
an
anchor
metal
ions,
allowing
precise
control
over
structures
functions
the
frameworks.
Furthermore,
coordination
within
framework
imparts
desirable
catalytic
enabling
their
potential
use
reactions.
Overall,
these
metal‐controlled
offer
exciting
opportunities
development
advanced
materials
tailored
functionalities.
The Journal of Physical Chemistry Letters,
Journal Year:
2025,
Volume and Issue:
unknown, P. 3888 - 3903
Published: April 10, 2025
Organic
grido-architectures
offer
not
only
state-of-the-art
models
for
exploring
the
complex
relationships
of
multicarrier
coherence
among
excitons,
charges,
photons,
electrons,
and
phonons
but
also
organic
high-dimensional
nanomaterials
flexible
electronics
intelligence.
Herein,
we
initiate
fundamental
progress
perspective
on
gridofluorene-based
zero-,
one-,
two-,
three-dimensional
nanomolecules
their
optoelectronic
features.
From
future
point
view,
sterically
trans-dimensional
hierarchically
cross-scale
effects
these
covalent
frameworks
nanostructures
are
discussed
photophysical,
electrical,
mechanical
thermal
properties.
multiscale
systems,
with
feature
synergistically
molecule-programmable
integration
diverse
functionalities,
open
a
bright
door
to
electronics,
intelligent
molecules,
devices,
even
organobots
as
well
artificially
robotic
chemists
(AiRCs).
Angewandte Chemie,
Journal Year:
2024,
Volume and Issue:
136(26)
Published: April 15, 2024
Abstract
The
synthesis
and
characterization
of
porphyrin
center
regulated
three‐dimensional
covalent
organic
frameworks
(COFs)
with
2‐fold
interpenetrated
scu
or
sqc
topology
have
been
investigated.
These
COFs
exhibit
unique
structural
features
properties,
making
them
promising
candidates
for
photocatalytic
applications
in
CO
2
reduction
artemisinin
synthesis.
serves
as
an
anchor
metal
ions,
allowing
precise
control
over
structures
functions
the
frameworks.
Furthermore,
coordination
within
framework
imparts
desirable
catalytic
enabling
their
potential
use
reactions.
Overall,
these
metal‐controlled
offer
exciting
opportunities
development
advanced
materials
tailored
functionalities.
