Small, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 26, 2024

In the era of atomic manufacturing, precise manipulation structures to engineer highly active catalytic sites has become a central focus in catalysis research. Dual-atom catalysts (DACs) have garnered significant attention for their superior activity, selectivity, and stability compared single-atom (SACs). However, comprehensive review that integrates geometric electronic factors influencing DAC performance remains limited. This systematically explores structure DAC, addressing key macroscopic parameters, such as spatial arrangements interatomic distances, well microscopic factors, including local coordination environments structures. Additionally, metal-support interactions (MSI) long-range (LSI) are comprehensively analyzed, which play pivotal yet underexplored role governing behavior. integration tailored functional groups is further discussed fine-tune properties, thereby optimizing intermediate adsorption, enhancing reaction kinetics, expanding multifunctionality various electrochemical environments. offers novel insights into rational design by elucidating intricate mechanisms underlying DACs' exceptional performance. Ultimately, DACs positioned critical players precision catalysis, highlighting potential drive breakthroughs across broad spectrum applications.

Language: Английский