Advanced Functional Materials,
Journal Year:
2024,
Volume and Issue:
unknown
Published: June 3, 2024
Abstract
The
extensive
use
of
pesticides
to
ensure
global
food
production
presents
significant
threats
both
human
health
and
the
environment.
In
this
study,
photochemical,
redox,
acid‐base
properties
Zr‐metal‐organic
polyhedra
(Zr‐MOP)
polyoxometalates
(POM)
are
utilized
fabricate
functional
hybrid
salts,
denoted
as
[Zr‐MOP][POM],
designed
for
pesticide
detoxification.
Upon
light
irradiation,
[Zr‐MOP][POM]
salts
generate
a
charge‐separated
state
with
oxidizing
properties.
This
activated
selectively
photooxidizes
highly
toxic
persistent
fenamiphos
into
sulfoxide
subsequently
hydrolytically
breaks
down
it
non‐toxic
3‐methyl‐4‐(methylsulfinyl)phenol
phosphate
components.
hydrolytic
degradation
is
facilitated
by
reduced
basicity
3‐methyl‐4‐(methylsulfinyl)phenolate
residue
(ΔpK
b
=
‐2.4)
in
photooxidized
form
molecule.
Furthermore,
demonstrate
efficacy
breakdown
multicomponent
mixtures
such
methylparaoxon.
Journal of Materials Chemistry A,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Jan. 1, 2024
The
oxidative
desulfurisation
process
is
a
subject
of
considerable
interest
at
present
due
to
the
mild
reaction
conditions,
good
selectivity,
and
significant
removal
efficiency
for
aromatic
sulphides
promise
ultra-deep
desulfurisation.
Chemistry - A European Journal,
Journal Year:
2024,
Volume and Issue:
30(37)
Published: May 6, 2024
Abstract
Some
nanomaterials
with
intrinsic
protease‐like
activity
have
the
advantages
of
good
stability,
biosafety,
low
price,
large‐scale
preparation
and
unique
property
nanomaterials,
which
are
promising
alternatives
for
natural
proteases
in
various
applications.
An
especial
term,
“nanoprotease”,
has
been
coined
to
stress
proteolytic
these
nanomaterials.
As
a
new
generation
artificial
proteases,
they
become
burgeoning
field,
attracting
many
researchers
design
synthesize
high
performance
nanoproteases.
In
this
review,
we
summarize
recent
progress
on
all
types
nanoproteases
regard
their
activity,
mechanism
application
introduce
effective
strategy
engineering
high‐performance
addition,
discuss
challenges
opportunities
nanoprotease
research
future.
