Critical Review of Techniques for Food Emulsion Characterization

Applied Sciences, Journal Year: 2024, Volume and Issue: 14(3), P. 1069 - 1069

Published: Jan. 26, 2024

Emulsions have garnered significant attention within a variety of industries, including pharmaceuticals, food production, and cosmetics. The importance emulsions across these sectors is attributed to their versatility unique properties, such as increased interfacial area the ability deliver compounds insoluble in water or mask flavor unpalatable ingredients. A comprehensive precise assessment physicochemical structural features, stability an indispensable phase pursuit new formulations improvement manufacturing protocols. characterization encompasses array methodologies designed determine attributes, droplet size, distribution, concentration, surface charge, others. In this review, we explore techniques most frequently used characterize critically assess significance each method holds understanding behavior predicting emulsions. We elucidate basic principles methods while emphasizing what information can be gathered from them, how effectively interpret optimize properties emulsions, crucial standpoints other long-term easy processing.

Language: Английский

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A perspective on the synergistic potential of artificial intelligence and product-based learning strategies in biobased materials education

Education for Chemical Engineers, Journal Year: 2023, Volume and Issue: 44, P. 164 - 180

Published: May 19, 2023

Language: Английский

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Enhancing Dehydration/Desalting Efficiency of Crude Oil Emulsions through Experimental and Computational Insights

Results in Engineering, Journal Year: 2024, Volume and Issue: 24, P. 103094 - 103094

Published: Oct. 9, 2024

Language: Английский

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Optimization of Toxicity, Biodegradability, and Skin Irritation in Formulations Containing Mixtures of Anionic and Nonionic Surfactants Combined with Silica Nanoparticles

Toxics, Journal Year: 2025, Volume and Issue: 13(1), P. 43 - 43

Published: Jan. 8, 2025

Surfactants play a crucial role in various industrial applications, including detergents and personal care products. However, their widespread use raises concerns due to potential environmental impact health risks, particularly aquatic ecosystems, where they can disrupt the balance of marine life accumulate water sources, posing challenges sustainable development. This study investigates implications anionic nonionic surfactants, focusing on toxicity, biodegradation, skin irritation profiles, especially when combined with silica nanoparticles. Toxicity assessments were conducted using bacteria Vibrio fischeri for toxicity Lepidium sativum seeds terrestrial plant effects, revealing that individual surfactants like alkyl ether carboxylic acid EC-R12-14E3 exhibit high levels, while fatty-alcohol ethoxylate FAE-R12-14E11 shows comparatively lower impact. The surfactant mixtures was analysed, both antagonistic synergistic effects depending used. addition nanoparticles generally mitigates overall whether used individually or mixtures. Biodegradation studies followed OECD 301E 301F guidelines, indicating meet approach mineralization threshold, whereas reduced biodegradation efficacy. Potential predicted through zein number (ZN), finding some combinations reduce highlighting safer formulation products come into direct contact skin. Overall, findings emphasize need careful selection nanoparticle integration minimize increase biodegradability.

Language: Английский

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Macroscopic thermodynamic properties of ionic micellar solutions depending on physicochemical formulation for the sodium dodecyl sulfate/sodium sulfate/water/n‐heptane/1‐pentanol system

Journal of Surfactants and Detergents, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 12, 2025

Abstract This work characterized the macroscopic thermodynamic properties of ionic micellar solutions. Formulation‐composition studies were done along one dimension by varying salinity (S) or oil–water ratio (WOR) in mixtures sodium dodecyl sulfate, water, n ‐heptane, and 1‐pentanol at 25°C 1 atm. Material balance multiple regression models used to get partial, mixed, excess molar volumes. The UNIFAC local composition model, coupled with Debye–Hückel theory, was employed calculate activity coefficients dimensionless Gibbs energies (partial, excess). equilibrium SOW systems exhibited phase transitions (WI‐WIII‐WII), solubilization increasing as increased constant WOR. Solubilization peaked optimal formulation, further increases WOR enhanced up formation a single‐phase system. Deviations from ideal behavior, between aqueous oil solutions, mainly due chemical interaction solutes () respect solvents (). Negative values energy mixing confirmed stability liquid phases their extension liquid–liquid equilibrium. response surfaces V = f(WOR, S) G E /RT represent behavior solutions function physicochemical formulation. These results can be extended other colloidal for design formulations surfactants anionic salts, oriented diagnosis resolution problems real systems, both laboratory industrial level.

Language: Английский

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Jean Louis Salager: A life of service to applied surfactant science

Journal of Surfactants and Detergents, Journal Year: 2025, Volume and Issue: unknown

Published: March 2, 2025

Abstract This article celebrates the illustrious career and scientific legacy of Prof. Jean‐Louis Salager, recipient prestigious Samuel Rosen Memorial Award presented by American Oil Chemists' Society (AOCS) in April 2020. The award acknowledges his over 50 years groundbreaking contributions to field surfactant chemistry, honoring individuals whose work has had a profound impact on both industry academia. tribute details Salager's lifelong contributions, which extend beyond remarkable discoveries encompass influence generations researchers, many whom now continue across globe. brings together reflections colleagues collaborators from global stage—scientists professionals inspired mentorship vision, representing Venezuelan diaspora careers he shaped with guidance support. Together, they underscore enduring Salager as teacher, mentor, friend, inspire shape chemistry interfacial science around world.

Language: Английский

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Meta-Analysis and Analytical Methods in Cosmetics Formulation: A Review

Cosmetics, Journal Year: 2023, Volume and Issue: 11(1), P. 1 - 1

Published: Dec. 19, 2023

The ever-evolving cosmetic industry requires advanced analytical techniques to explore, understand, and optimize product performance at nano, micro, macroscopic levels. Nowadays, these insights are crucial for translating microstructure behavior into properties. This knowledge is essential formulate products with a lower carbon footprint higher sustainability profile, incorporating, the same time, natural or biobased raw materials. These materials may present challenges formulators scientists due either an inferior when compared their fossil-derived counterparts costs. comprehensive review covers spectrum of methodologies employed in formulation, including chromatographic analyses, olfactometry, electronic nose technology. characterization stability involving assessing parameters such as droplet size, zeta potential, viscosity, centrifugation, surface tension, interfacial tension also explored. discussion this paper extends role rheology understanding molecular structure behavioral dynamics samples. concludes overview colorimetric analysis, aspect related consumer perception, followed by on opportunities associated using meta-analysis cosmetics. formulation cosmetics employing feedstocks included, highlighting evolving landscape science integration sustainable practices. stands interface between performance, which attained through detailed examination each method. know-how shared serves valuable resource formulators, researchers, professionals real-world applications field formulation.

Language: Английский

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Review on Some Confusion Produced by the Bicontinuous Microemulsion Terminology and Its Domains Microcurvature: A Simple Spatiotemporal Model at Optimum Formulation of Surfactant-Oil-Water Systems

ACS Omega, Journal Year: 2023, Volume and Issue: 8(10), P. 9040 - 9057

Published: March 2, 2023

Fundamental studies have improved understanding of molecular-level properties and behavior in surfactant-oil-water (SOW) systems at equilibrium under nonequilibrium conditions. However, confusion persists regarding the terms "microemulsion" "curvature" these systems. Microemulsion refers to a single-phase system that does not contain distinct oil or water droplets but least four different structures with globular domains nanometer size sometimes arbitrary shape. The significance such is unclear. At high surfactant concentrations (typically 30 wt % more), single phase zone has been identified which complex molecular arrangements may result light scattering. As concentration decreases, referred as bicontinuous microemulsion, known middle Winsor III triphasic system. Its structure described involving simple multiple films surrounding more less elongated excess globules. In cases where separates into two three phases, I II systems, one containing most surfactant, also confusedly microemulsion. this surfactant-rich phase, only curved objects are micellar soluble no real interface rather exchange molecules external liquid an ultrafast pace. use term context microemulsion confusing, particularly when applied merged nanometer-size percolating domains. work, we discuss "curvature", four-dimensional spatiotemporal model proposed concerning SOW equilibrated near optimum formulation. This explains motion due Brownian movement, quick thermal fluctuation, limited short distance. resulting observation will be average time space, leading permanent change local microcurvature aggregate, thus changing from micelle-like inverse order over extremely time. "microcurvature" used explain small variations globule indicates close-to-zero mean curvature surfactant-containing film surface

Language: Английский

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Advantages and limitations of different methods to determine the optimum formulation in surfactant–oil–water systems: A review

Journal of Surfactants and Detergents, Journal Year: 2023, Volume and Issue: 27(1), P. 5 - 36

Published: Sept. 11, 2023

Abstract The optimum formulation in a surfactant–oil–water (SOW) system is defined as the physicochemical situation at which surfactant adsorbed interface exhibits exactly equal interactions for both oil and water. Identifying of SOW systems crucial various industrial applications, ranging from pharmaceuticals to cosmetics petroleum issues like dehydration enhanced recovery. Multiple techniques are available identify formulation, often with its own advantages limitations. In this comprehensive review, we provide an in‐depth analysis systematic use scans systems. We critically assess different methods, including conventional ones, such phase behavior observation, determination minimum interfacial tension equilibrated systems, localization emulsion stability using scans. also mention new promising technique that can be applied practice, oscillating spinning drop rheology (OSDIR) well others allow understanding some structural features domains present surfactant‐rich Among these dynamic light scattering (DLS), small angle (SAXS SANS), nuclear magnetic resonance (NMR), X‐ray microcomputed tomography (Micro‐CT), differential scanning calorimeter (DSC), found literature. Finally, discuss potentially unusual behaviors appear complex thus providing guidance on selection most suitable method tailored specific application.

Language: Английский

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Surfactants produced from carbohydrate derivatives: Part 2. A review on the value chain, synthesis, and the potential role of artificial intelligence within the biorefinery concept

Journal of Surfactants and Detergents, Journal Year: 2024, Volume and Issue: unknown

Published: May 21, 2024

Abstract This comprehensive and critical review explores the synthesis applications of carbohydrate‐based surfactants within biorefinery concept, focusing on biobased sugar‐head molecules suitable for use across several manufacturing sectors, including cosmetics, pharmaceuticals, household products, detergents, foods. The main focus relies sustainable alternatives to conventional surfactants, which could reduce final carbon footprint industrial feedstocks products. A thorough analysis raw materials, highlighting significance feedstock sources, current rhamnolipid biosurfactants production trends, is presented. Key organic reactions sorbitan esters, sucrose alkyl polyglycosides, fatty acid glucamines, such as glycosidation, acylation, etherification, well rhamnolipids through fermentation are described. Given scarce literature characterization these surfactant types hydrophilic–lipophilic deviation (HLD) framework, contribution parameter (SCP) in HLD equation critically assessed. economic landscape also discussed, noting significant growth biosurfactant market, driven by environmental awareness regulatory changes, with projections indicating a substantial market increase forthcoming years. Finally, promising potential generative artificial intelligence (AI) developing customized molecules, optimized properties targeted applications, emphasized avenue future research.

Language: Английский

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