Recent Advances in Electrochemical Carboxylation with CO₂

Accounts of Chemical Research, Journal Year: 2024, Volume and Issue: 57(18), P. 2728 - 2745

Published: Sept. 3, 2024

ConspectusCarbon dioxide (CO

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Visible-light-driven alkene dicarboxylation with formate and CO₂ under mild conditions

Chemical Science, Journal Year: 2024, Volume and Issue: 15(16), P. 6178 - 6183

Published: Jan. 1, 2024

Low-cost formate salt was used as the reductant and part of carboxyl source in a visible-light-driven dicarboxylation diverse alkenes, including simple styrenes. The highly competing hydrocarboxylation side reaction successfully overridden. Good yields products were obtained under mild conditions at ambient temperature pressure CO

Language: Английский

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Anodic reactions matter for cathodic electrocarboxylation with CO2

Chem Catalysis, Journal Year: 2025, Volume and Issue: unknown, P. 101263 - 101263

Published: Feb. 1, 2025

Language: Английский

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Recent Advances toward Electro- and Electrophotochemical 2,3-Dichloro-5,6-dicyano-1,4-benzoquinone (DDQ)-Catalyzed C—H/C—F Bonds Functionalization

Chinese Journal of Organic Chemistry, Journal Year: 2025, Volume and Issue: 45(2), P. 668 - 668

Published: Jan. 1, 2025

Language: Английский

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Encapsulation of chiral CoII(R,R)(salen) in mesocellular foam as an efficient heterogeneous catalyst for asymmetric electrocarboxylation of 1-phenylethyl chloride with CO2

Journal of Organometallic Chemistry, Journal Year: 2025, Volume and Issue: unknown, P. 123621 - 123621

Published: March 1, 2025

Language: Английский

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Pairing Electrocarboxylation of Unsaturated Bonds with Oxidative Transformation of Alcohol and Amine

ChemSusChem, Journal Year: 2023, Volume and Issue: 16(19)

Published: June 27, 2023

A parallel paired electrosynthetic method, coupling electrocarboxylation incorporating CO2 into ketone, imine, and alkene with alcohol oxidation or oxidative cyanation of amine, was developed for the first time. Various carboxylic acids as well aldehyde/ketone α-nitrile amine were prepared at cathode anode respectively in a divided cell. Its utility merits on simultaneously achieving high atom-economic utilization, elevated faradaic efficiency (FE, total FE up to 166 %), broad substrate scope demonstrated. The preparation pharmaceutical intermediates Naproxen Ibuprofen via this approach proved its potential application green organic electrosynthesis.

Language: Английский

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Recent Advances in Electrochemical Carboxylation of Inert Chemical Bonds with Carbon Dioxide

Chinese Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: 44(10), P. 3043 - 3043

Published: Jan. 1, 2024

Language: Английский

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Electrochemical Oxidation Decarboxylative Cyclization of α-Keto Acid with o-Aminobenzylamine

Chinese Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: 44(3), P. 972 - 972

Published: Jan. 1, 2024

Language: Английский

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Synthesis of CO2-Based Re-processable Slight Cross-Linked Polyurea Thermosets

Chinese Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: 44(10), P. 3178 - 3178

Published: Jan. 1, 2024

Language: Английский

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Advances in Electrochemical Cathodic Reductive Reactions Involving Carbon-Nitrogen Bonds

Chinese Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: 44(3), P. 825 - 825

Published: Jan. 1, 2024

Language: Английский

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