Chemistry, Год журнала: 2025, Номер 7(3), С. 89 - 89

Опубликована: Май 29, 2025

Metal-free C(sp3)–S bond cleavage of thioethers was achieved using NCS as a critical additive. A wide range arylmethyl were successfully transformed into aryl aldehydes with satisfactory yields in chloroform. Meanwhile, employing fluorobenzene the solvent enables selective formation dithioacetals from thioethers, achieving moderate to good yields. Notably, first prepared through metal-free and subsequent thioacetalization process. Furthermore, these simple efficient approaches also provide complementary strategies for accessing important dithioacetals.

Язык: Английский