Optimizing Aqueous Zinc‐Sulfur Battery Performance via Regulating Acetonitrile Co‐Solvents and Carbon Nanotube Carriers DOI Open Access

Zhenqiang Ge,

Hangning Liu,

Shan Wang

и другие.

ChemSusChem, Год журнала: 2024, Номер unknown

Опубликована: Окт. 21, 2024

Abstract Rechargeable aqueous zinc‐sulfur batteries (AZSBs) are gaining attention due to their high energy density, ultra‐stable discharge platform, and safety. However, poor liquid/solid reaction processes at the anode cathode reduce kinetics, severe dissolution of polysulfides causes shuttle effects during discharge/charge cycles, hindering practical applications. Improving performance requires optimizing both electrolyte. Herein, we design an organic‐inorganic hybrid electrolyte (zinc trifluoromethanesulfonate trace iodine monomer dissolved in acetonitrile/water co‐solvent (AN‐X)) a partially exfoliated multi‐walled carbon nanotube (PECNT) hosted sulfur (S@PECNTs) for AZSBs. The is highly dispersed along PECNTs with appropriate wettability electrode/electrolyte interface using AN‐3 as Meanwhile, this inhibits hydrogen evolution negative potentials promotes uniform Zn ion stripping/plating. Expressively, AN‐3‐based AZSB exhibits capacity 1370 mAh g −1 excellent Coulombic efficiency (79.9 %), outstanding rate capability, cycling performance. These improvements attributed synergistic effect between S@PECNTs electrolyte, which reduces R ct enhance kinetics blocks polysulfides, ensuring reversible zinc sulfur.

Язык: Английский

Dopant-induced electronic state modulation of ruthenium oxide for enhanced acidic oxygen evolution reaction DOI
Lu Lu,

Zijing Xu,

Shuaichong Wei

и другие.

Chemical Engineering Journal, Год журнала: 2024, Номер unknown, С. 157107 - 157107

Опубликована: Окт. 1, 2024

Язык: Английский

Процитировано

7

Biomimetic urchin-like structure of Re/ReS2/ZnS/NDC for high performance photothermal water evaporation and electricity generation DOI

Zhijun Lai,

Xuyan Zhang,

Shule Huang

и другие.

Chemical Engineering Journal, Год журнала: 2025, Номер unknown, С. 160550 - 160550

Опубликована: Фев. 1, 2025

Язык: Английский

Процитировано

1

In-situ generated sulfur/porous carbon nanocomposites featuring enhanced specific surface area for aqueous zinc-sulfur batteries with small electrochemical polarization DOI

Zuoshu Wang,

Xiaoyu Yang, Yujie Wei

и другие.

Journal of Power Sources, Год журнала: 2024, Номер 627, С. 235829 - 235829

Опубликована: Ноя. 17, 2024

Язык: Английский

Процитировано

4

Optimization strategies for high-performance aqueous zinc-sulfur batteries: challenges and future perspectives DOI Open Access

Yunyan Chen,

Jiaoyi Ning, Yumei Wen

и другие.

Energy Materials, Год журнала: 2025, Номер 5(4)

Опубликована: Янв. 23, 2025

Aqueous zinc-sulfur batteries (AZSBs) have emerged as promising candidates for high-energy density, cost-effective, and environmentally sustainable energy storage systems. Despite their potential, several challenges hinder the realization of high-performance AZSBs, including sluggish reaction kinetics, disproportionation reactions ZnS in water, low conductivity volume expansion sulfur cathode, poor wetting properties, dendrite growth issues zinc anode. This review comprehensively summarizes optimization strategies overcoming these challenges. We discuss cathode modification approaches, such sulfur/carbon composites, sulfide catalytic matrices, which address while enhancing conversion kinetics. Additionally, electrolyte engineering strategies, use iodide-based additives co-solvent modifications, are examined effectiveness improving kinetics properties. advancements, AZSBs still face with long-cycle stability. Therefore, this proposes future perspectives development AZSBs. aim to provide valuable insights into sulfur-based materials advance achievement

Язык: Английский

Процитировано

0

Aqueous Zinc‐Based Batteries: Active Materials, Device Design, and Future Perspectives DOI Creative Commons
Ran Yan,

Fang Dong,

Shuhui Sun

и другие.

Advanced Energy Materials, Год журнала: 2025, Номер unknown

Опубликована: Март 5, 2025

Abstract Aqueous zinc‐based batteries (AZBs) are emerging as a compelling candidate for large‐scale energy storage systems due to their cost‐effectiveness, environmental friendliness, and inherent safety. The design development of high‐performance AZBs have thus been the focus considerable study efforts; yet, certain properties electrode materials electrolytes still limit development. Here, comprehensive overview evaluation current progress, existing limitations, potential solutions achieve long‐cycle stability fast kinetics in is provided. Detailed analyses structural design, electrochemical behavior, zinc‐ion mechanisms various presented. Additionally, key issues research directions related zinc anodes selection systematically discussed guide future with superior performance. Finally, this review provides outlook on AZBs, highlighting challenges opportunities, foster continued rapid advancement broader practical applications field.

Язык: Английский

Процитировано

0

Carboxyl-rich honeycomb carbon enabling enhanced Cu2+ diffusion and suppressed CuS formation for high-performance decoupled Zn-S batteries DOI
Haoliang Chen, Wenjie Huang, Yida Deng

и другие.

Chemical Engineering Journal, Год журнала: 2025, Номер unknown, С. 161887 - 161887

Опубликована: Март 1, 2025

Язык: Английский

Процитировано

0

Aqueous Zinc‐Sulfur Batteries: From Challenges to Strategies DOI

Beijia Lu,

J. Deng,

Zening Wu

и другие.

Advanced Materials, Год журнала: 2025, Номер unknown

Опубликована: Июнь 1, 2025

Abstract Aqueous Zn‐S batteries (AZSBs), including conventional and decoupled AZSBs, are suitable options for advanced electrochemical energy storage systems. They cost‐effective with safety, high theoretical capacity, power density. Nevertheless, many inherent hurdles need to be overcome make AZSBs practically feasible, irreversible transformation of the sulfur cathode, instability Zn anode, incompatibility electrolyte. This review presents a comprehensive evaluation emphasizing configurations electrode reactions, challenges, strategies, prospects future. First, electrochemistry behavior is reviewed, encompassing both battery configurations, along their respective reactions. Second, various sources, hosts, additives identified that can effectively enhance reversibility cathode. Third, approaches constructing solid electrolyte interphase on anode facilitating alloying discussed as key strategies protection. Fourth, selection zinc salts employment organic co‐solvents explored regulate electrolytes. Finally, thoughts future research development in presented build better aqueous batteries.

Язык: Английский

Процитировано

0

Sulfur-based cathodes for aqueous zinc ion batteries DOI
Yuwei Zhao, Jiaxiong Zhu, Chuan Li

и другие.

Journal of Materials Chemistry C, Год журнала: 2024, Номер 12(37), С. 14809 - 14815

Опубликована: Янв. 1, 2024

We propose strategies for sulfur-based cathodes in aqueous zinc-ion batteries, using molecular engineering, adsorption-catalysis, and electrolyte chemistry to boost performance, conductivity, stability, making them ideal grid energy storage.

Язык: Английский

Процитировано

2

Optimizing Aqueous Zinc‐Sulfur Battery Performance via Regulating Acetonitrile Co‐Solvents and Carbon Nanotube Carriers DOI Open Access

Zhenqiang Ge,

Hangning Liu,

Shan Wang

и другие.

ChemSusChem, Год журнала: 2024, Номер unknown

Опубликована: Окт. 21, 2024

Abstract Rechargeable aqueous zinc‐sulfur batteries (AZSBs) are gaining attention due to their high energy density, ultra‐stable discharge platform, and safety. However, poor liquid/solid reaction processes at the anode cathode reduce kinetics, severe dissolution of polysulfides causes shuttle effects during discharge/charge cycles, hindering practical applications. Improving performance requires optimizing both electrolyte. Herein, we design an organic‐inorganic hybrid electrolyte (zinc trifluoromethanesulfonate trace iodine monomer dissolved in acetonitrile/water co‐solvent (AN‐X)) a partially exfoliated multi‐walled carbon nanotube (PECNT) hosted sulfur (S@PECNTs) for AZSBs. The is highly dispersed along PECNTs with appropriate wettability electrode/electrolyte interface using AN‐3 as Meanwhile, this inhibits hydrogen evolution negative potentials promotes uniform Zn ion stripping/plating. Expressively, AN‐3‐based AZSB exhibits capacity 1370 mAh g −1 excellent Coulombic efficiency (79.9 %), outstanding rate capability, cycling performance. These improvements attributed synergistic effect between S@PECNTs electrolyte, which reduces R ct enhance kinetics blocks polysulfides, ensuring reversible zinc sulfur.

Язык: Английский

Процитировано

1