Organic Thermally Activated Delayed Fluorescence (TADF) Compound as The Photosensitizer in CO2 Photoreduction: Taking 4CzIPN as An Example DOI

Youting Fang,

Yilin Xue,

Duobin Chao

и другие.

Asian Journal of Organic Chemistry, Год журнала: 2025, Номер unknown

Опубликована: Апрель 25, 2025

Abstract Over the past decades, excessive CO₂ emissions have caused severe environmental problems, primarily global warming and climate change. To address these challenges, researchers developed photocatalytic approaches to convert into high‐value‐added chemicals. The development of efficient, green, cost‐effective reduction systems represents a crucial step toward sustainable energy solutions. However, replacing noble metal‐based photosensitizers, which are widely used in reduction, with more alternatives remains challenging. Thermally activated delayed fluorescence (TADF) compounds emerged as promising organic offering high quantum efficiency, long lifetimes, wide redox window. Notably, 1,2,3,5‐Tetrakis(carbazol‐9‐yl)‐4,6‐dicyanobenzene (4CzIPN), prototypical TADF compound, has demonstrated exceptional performance various systems. This review systematically summarizes recent advances TADF‐based particularly 4CzIPN, for while elucidating their underlying reaction mechanisms.

Язык: Английский

Boosting photocatalytic H2O2 production and non-biodegradable ofloxacin removal via a novel Ti3C2 MXene nanosheet-supported BiVO4/InVO4 Z-scheme heterojunction: Optimization and mechanism insights DOI
Jun Zhao,

Ali B.M. Ali,

Abdul Amir H. Kadhum

и другие.

Journal of Water Process Engineering, Год журнала: 2025, Номер 74, С. 107722 - 107722

Опубликована: Апрель 23, 2025

Язык: Английский

Процитировано

0
Organic Thermally Activated Delayed Fluorescence (TADF) Compound as The Photosensitizer in CO2 Photoreduction: Taking 4CzIPN as An Example DOI

Youting Fang,

Yilin Xue,

Duobin Chao

и другие.

Asian Journal of Organic Chemistry, Год журнала: 2025, Номер unknown

Опубликована: Апрель 25, 2025

Abstract Over the past decades, excessive CO₂ emissions have caused severe environmental problems, primarily global warming and climate change. To address these challenges, researchers developed photocatalytic approaches to convert into high‐value‐added chemicals. The development of efficient, green, cost‐effective reduction systems represents a crucial step toward sustainable energy solutions. However, replacing noble metal‐based photosensitizers, which are widely used in reduction, with more alternatives remains challenging. Thermally activated delayed fluorescence (TADF) compounds emerged as promising organic offering high quantum efficiency, long lifetimes, wide redox window. Notably, 1,2,3,5‐Tetrakis(carbazol‐9‐yl)‐4,6‐dicyanobenzene (4CzIPN), prototypical TADF compound, has demonstrated exceptional performance various systems. This review systematically summarizes recent advances TADF‐based particularly 4CzIPN, for while elucidating their underlying reaction mechanisms.

Язык: Английский

Процитировано

0