Strain Retarding in Multilayered Hierarchical Sn‐Doped Sb Nanoarray for Durable Sodium Storage DOI
Xinyan Li, Xin Zhang, Xiaobin Niu

и другие.

Advanced Functional Materials, Год журнала: 2023, Номер 33(33)

Опубликована: Май 5, 2023

Abstract Antimony (Sb) is a potential electrode material for sodium (Na) storage due to its high theoretical capacity of 660 mAh g −1 . Yet, the alloy/dealloy reaction between Na and Sb induces detrimental structural strain that inevitably leads failure, further resulting in deteriorated rate performance cycle life. Herein, inspired by multilayered structure pine trees, 3D hierarchical tin (Sn)‐doped nanoarray coated with thin carbon (C) layer (Sb(Sn)@C) developed. Density functional theory calculation results suggest Sb(Sn)@C offers better kinetic properties diffusion, lower volume expansion upon intercalation as compared counterparts without Sn dopant or coating. Moreover, simulation based on finite element analysis unique construction not only provides highly efficient + utilization, but also builds uniform von Mises stress distribution effectively confines induced during insertion. This verified nanoindentation measurement shows higher elastic modulus hardness than Sb(Sn) pure Sb, indicating best mechanical stability. As expected, achieves excellent electrochemical capability reversible capacity, enhanced cyclability, remarkable performance.

Язык: Английский

Recent advances in rational design for high-performance potassium-ion batteries DOI
Yifan Xu, Yichen Du,

Han Chen

и другие.

Chemical Society Reviews, Год журнала: 2024, Номер 53(13), С. 7202 - 7298

Опубликована: Янв. 1, 2024

The growing global energy demand necessitates the development of renewable solutions to mitigate greenhouse gas emissions and air pollution. To efficiently utilize yet intermittent sources such as solar wind power, there is a critical need for large-scale storage systems (EES) with high electrochemical performance. While lithium-ion batteries (LIBs) have been successfully used EES, surging price, coupled limited supply crucial metals like lithium cobalt, raised concerns about future sustainability. In this context, potassium-ion (PIBs) emerged promising alternatives commercial LIBs. Leveraging low cost potassium resources, abundant natural reserves, similar chemical properties potassium, PIBs exhibit excellent ion transport kinetics in electrolytes. This review starts from fundamental principles structural regulation PIBs, offering comprehensive overview their current research status. It covers cathode materials, anode electrolytes, binders, separators, combining insights full battery performance, degradation mechanisms,

Язык: Английский

Процитировано

148
Recent progress in the design of advanced MXene/metal oxides-hybrid materials for energy storage devices DOI
Muhammad Sufyan Javed, Abdul Mateen, Iftikhar Hussain

и другие.

Energy storage materials, Год журнала: 2022, Номер 53, С. 827 - 872

Опубликована: Окт. 6, 2022

Язык: Английский

Процитировано

114
Emerging carbon-based quantum dots for sustainable photocatalysis DOI
Jiamei Wang, Jizhou Jiang, Fangyi Li

и другие.

Green Chemistry, Год журнала: 2022, Номер 25(1), С. 32 - 58

Опубликована: Ноя. 19, 2022

This review focuses on the applications of emerging carbon-based QD materials ( i.e. , GQDs, CNQDs, MQDs, and GDQDs) in sustainable photocatalysis.

Язык: Английский

Процитировано

98
Element‐Doped Mxenes: Mechanism, Synthesis, and Applications DOI
Ronghao Wang, Muhan Li, Kaiwen Sun

и другие.

Small, Год журнала: 2022, Номер 18(25)

Опубликована: Май 9, 2022

Heteroatom doping can endow MXenes with various new or improved electromagnetic, physicochemical, optical, and structural properties. This greatly extends the arsenal of materials their potential for a spectrum applications. article comprehensively critically discusses syntheses, properties, emerging applications growing family heteroatom-doped materials. First, strategies, synthesis methods, theoretical simulations high-performance are summarized. In order to achieve materials, mechanism atomic element from three aspects lattice optimization, functional substitution, interface modification is analyzed summarized, aiming provide clues developing controllable synthetic routes. The mechanisms underlying advantageous uses energy storage, catalysis, sensors, environmental purification biomedicine highlighted. Finally, future opportunities challenges study application multifunctional presented. work could open up prospects development MXenes.

Язык: Английский

Процитировано

97
Challenges and Future Prospects of the MXene-Based Materials for Energy Storage Applications DOI Creative Commons

Svitlana Nahirniak,

Apurba Ray, Bilge Saruhan

и другие.

Batteries, Год журнала: 2023, Номер 9(2), С. 126 - 126

Опубликована: Фев. 10, 2023

In the past decade, MXenes, a new class of advanced functional 2D nanomaterials, have emerged among numerous types electrode materials for electrochemical energy storage devices. MXene and their composites opened up an interesting opportunity in field materials, owing to transition metal nitrides/carbides/carbonitride-based unique layered structures, higher electrical thermal conductivity, charge carrier mobility, high negative zeta-potential, mechanical properties, tunable bandgap, superior hydrophilicity, metallic nature rich surface chemistry, which enhance number active redox sites on short ion diffusion path. However, case applications, unavoidable problem aggregation nanosheet restacking significantly reduces accessibility electrolyte ions. Currently, there is research efforts devoted solutions order avoid these deficits. This Review complies extensively with recent advances application MXene-based devices such as batteries supercapacitors. Particular attention paid understanding relation MXenes chemical composition, morphology performances. Moreover, challenges composited commercial are considered ways overcome drawbacks provided. Finally, opportunities given future novel highlighted.

Язык: Английский

Процитировано

97
Applications of MXene‐Based Single‐Atom Catalysts DOI Creative Commons
Xue Bai, Jingqi Guan

Small Structures, Год журнала: 2023, Номер 4(7)

Опубликована: Янв. 27, 2023

Single‐atom catalysts (SACs) consist of isolated metal sites on the support through stable coordination bond, which usually have high catalytic activity and selectivity. With large surface area electron tunability, metallic carbides, nitrides, or carbonic nitrides (MXenes) are suitable carriers for supporting single‐metal atoms. The abundant surface‐functional groups vacancy defects MXenes ideal anchoring Herein, advanced synthesis characterization methods MXene‐based SACs first introduced. Three strategies (adsorption at functional groups, vacancies, terminating group vacancies) appear to be feasible in ensuring non‐aggregation atoms, attributed strong bonding between atoms carrier. applications electrocatalysis (including hydrogen evolution reaction, oxygen reduction carbon dioxide nitrogen reaction), energy storage Li‐ion batteries, metal–air supercapacitors), sensors gas biological sensors) fundamentally reviewed. Finally, own insight current challenges prospects is presented.

Язык: Английский

Процитировано

96
Recent Advances in MXene‐Based Aerogels: Fabrication, Performance and Application DOI Open Access
Chunxiang Wei,

Quangang Zhang,

Zhen Wang

и другие.

Advanced Functional Materials, Год журнала: 2022, Номер 33(9)

Опубликована: Дек. 26, 2022

Abstract As one of the “miracle materials” in 21st century, aerogels with ultra‐low weight and remarkable mechanical performance have emerged shown incredible immunity to harsh working environments, attracting substantial research interests across a wide range areas. Recently, exploitation MXene nanosheets into represents new focus field materials science, on account their unique structures outstanding properties. In this review, aim is provide timely insightful overview for recent advances fabrication, performance, application MXene‐based aerogels. The main strategies constructing aerogels, directly from MXene‐dispersion or presence other functional components, are summarized. Furthermore, desirable related applications areas including electromagnetic management, sensors, solar steam generators, energy storage highlighted. A thorough investigation comparison mechanical, electrical, sensing, properties performed understand structure‐property relationships. At last, study concluded summary outlook section future development as well challenges that remained, thus bringing opportunities material engineering

Язык: Английский

Процитировано

88
MXene/0D nanocomposite architectures: Design, properties and emerging applications DOI
Poushali Das, Sayan Ganguly, Andreas Rosenkranz

и другие.

Materials Today Nano, Год журнала: 2023, Номер 24, С. 100428 - 100428

Опубликована: Ноя. 1, 2023

Язык: Английский

Процитировано

72
Fluorine- and Acid-Free Strategy toward Scalable Fabrication of Two-Dimensional MXenes for Sodium-Ion Batteries DOI
Yongling An, Yuan Tian, Quanyan Man

и другие.

Nano Letters, Год журнала: 2023, Номер 23(11), С. 5217 - 5226

Опубликована: Май 18, 2023

MXenes are emerging 2D materials that have gained great attention because of their unique physical-chemical properties. However, the wide application is prohibited by high cost and environmentally harmful synthesis process. Here a fluoride- acid-free physical vacuum distillation strategy proposed to directly synthesize series MXenes. Specifically, introducing low-boiling-point element into MAX subsequently evaporating A elements via distillation, fluoride-free (Ti3C2Tx, Nb2CTx, Nb4C3Tx, Ta2CTx, Ti2NTx, Ti3CNTx, etc.) fabricated. This green one-step process without any acid/alkaline involved with all reactions inside tube furnace, avoiding contamination external environments. Besides, synthetic temperature controlled regulate layered structures specific surface areas Accordingly, synthesized Ti3C2Tx MXene exhibits improved sodium storage performance. method may provide an alternative for scalable production other materials.

Язык: Английский

Процитировано

69
Emerging Xene‐Based Single‐Atom Catalysts: Theory, Synthesis, and Catalytic Applications DOI
Mengke Wang, Yi Hu,

Junmei Pu

и другие.

Advanced Materials, Год журнала: 2023, Номер 36(3)

Опубликована: Июнь 17, 2023

Abstract In recent years, the emergence of novel 2D monoelemental materials (Xenes), e.g., graphdiyne, borophene, phosphorene, antimonene, bismuthene, and stanene, has exhibited unprecedented potentials for their versatile applications as well addressing new discoveries in fundamental science. Owing to unique physicochemical, optical, electronic properties, emerging Xenes have been regarded promising candidates community single‐atom catalysts (SACs) active sites or support matrixes significant improvement intrinsic activity selectivity. order comprehensively understand relationships between structure property Xene‐based SACs, this review represents a comprehensive summary from theoretical predictions experimental investigations. Firstly, calculations regarding both anchoring on doping/substituting heteroatoms at are briefly summarized. Secondly, controlled synthesis precise characterization presented SACs. Finally, current challenges future opportunities development SACs highlighted.

Язык: Английский

Процитировано

66