Xonotlite Nanowire Interfacial Layer with Zincophilic Behavior and Ion Confinement Effect Guiding Inerratic Zn Deposition DOI

Mengyu Rong,

Na Gao,

Shuaiyu Chen

и другие.

Опубликована: Янв. 1, 2023

Aqueous Zn-ion batteries (AZIBs) have garnered huge attention for grid-scale energy storage systems owing to their eco-friendliness, affordability, safety, and high specific capacity. Nonetheless, recyclability is hindered by the corrosion, zinc dendrite hydrogen evolution reaction. The development of protecting layer Zn anode great meaningful challenge. In this work, a nanowire-structured xonotlite (calcium silicate hydrate, Ca6Si6O17(OH)2, denoted as CaSi) successfully synthesized facile green route it used construct (named Zn@CaSi), where CaSi functions an artificial interfacial with zincophilic behavior guiding inerratic deposition interaction between electrolyte anode. Owing numerous pores nanowires, Zn@CaSi offers vast stable avenues facilitating enhancement Zn2+ kinetics. Regarding crystal structure, featuring 4.38 Å nanopore channels can facilitate desolvation hydrated ion via confinement effect, therefore effectively inhibiting reaction accumulation by-products. Compared bare Zn, significant improvement in overall performance achieved. symmetric cell runs smoothly 1580 hours at current density 1 mA cm−2, which approximately 13 times than that Zn//Zn cell. full enhanced electrochemical performances also demonstrates boost charge transfer plating/stripping Reconstruction electrolyte/anode interface using nanowire-formulated porous structure expected provide new ideas engineering interfaces achieve high-performance AZIBs.

Язык: Английский

Manufacturing strategies and emerging directions of mixed-matrix membranes based on natural Halloysite nanotubes DOI
Xinyu Lei, Guocheng Lv,

Xiuxin Xie

и другие.

Sustainable materials and technologies, Год журнала: 2023, Номер 38, С. e00766 - e00766

Опубликована: Ноя. 8, 2023

Язык: Английский

Процитировано

2
Improved Stability of Zinc Anodes by a Trace Amount of Xylitol DOI
Shan Li,

Yan Xu,

Xuena Xu

и другие.

Journal of Electronic Materials, Год журнала: 2023, Номер 53(1), С. 408 - 417

Опубликована: Ноя. 7, 2023

Язык: Английский

Процитировано

1
Preparation of polyaniline coated MnV2O6 as cathode material for Advanced Zinc Ion Batteries DOI Creative Commons

Yinjie Shi,

Gemeng Liang, Chuang Yue

и другие.

International Journal of Electrochemical Science, Год журнала: 2022, Номер 17(12), С. 221289 - 221289

Опубликована: Дек. 1, 2022

Язык: Английский

Процитировано

1
Xonotlite Nanowire Interfacial Layer with Zincophilic Behavior and Ion Confinement Effect Guiding Inerratic Zn Deposition DOI

Mengyu Rong,

Na Gao,

Shuaiyu Chen

и другие.

Опубликована: Янв. 1, 2023

Aqueous Zn-ion batteries (AZIBs) have garnered huge attention for grid-scale energy storage systems owing to their eco-friendliness, affordability, safety, and high specific capacity. Nonetheless, recyclability is hindered by the corrosion, zinc dendrite hydrogen evolution reaction. The development of protecting layer Zn anode great meaningful challenge. In this work, a nanowire-structured xonotlite (calcium silicate hydrate, Ca6Si6O17(OH)2, denoted as CaSi) successfully synthesized facile green route it used construct (named Zn@CaSi), where CaSi functions an artificial interfacial with zincophilic behavior guiding inerratic deposition interaction between electrolyte anode. Owing numerous pores nanowires, Zn@CaSi offers vast stable avenues facilitating enhancement Zn2+ kinetics. Regarding crystal structure, featuring 4.38 Å nanopore channels can facilitate desolvation hydrated ion via confinement effect, therefore effectively inhibiting reaction accumulation by-products. Compared bare Zn, significant improvement in overall performance achieved. symmetric cell runs smoothly 1580 hours at current density 1 mA cm−2, which approximately 13 times than that Zn//Zn cell. full enhanced electrochemical performances also demonstrates boost charge transfer plating/stripping Reconstruction electrolyte/anode interface using nanowire-formulated porous structure expected provide new ideas engineering interfaces achieve high-performance AZIBs.

Язык: Английский

Процитировано

0