ACS Applied Materials & Interfaces,
Год журнала:
2022,
Номер
14(8), С. 9970 - 9986
Опубликована: Фев. 17, 2022
The
development
of
materials
with
outstanding
performance
for
sensitive
and
selective
detection
multiple
analytes
is
essential
the
human
health
society.
Luminescent
metal-organic
frameworks
(LMOFs)
have
controllable
surface
pore
sizes
excellent
optical
properties.
Therefore,
a
variety
LMOF-based
sensors
diverse
functions
can
be
easily
designed
applied.
Furthermore,
introduction
energy
transfer
(ET)
into
LMOFs
(ET-LMOFs)
could
provide
richer
design
concept
much
more
accurate
sensing
performance.
In
this
review,
we
focus
on
recent
five
years
advances
in
ET-LMOF-based
materials,
an
emphasis
photochemical
photophysical
mechanisms.
We
discuss
detail
possible
processes
within
MOF
structure
or
between
MOFs
guest
materials.
Finally,
applications
are
highlighted.
Chemical Reviews,
Год журнала:
2022,
Номер
122(24), С. 17241 - 17338
Опубликована: Ноя. 1, 2022
Current
energy
and
environmental
challenges
demand
the
development
design
of
multifunctional
porous
materials
with
tunable
properties
for
catalysis,
water
purification,
conversion
storage.
Because
their
amenability
to
de
novo
reticular
chemistry,
metal-organic
frameworks
(MOFs)
have
become
key
in
this
area.
However,
usefulness
is
often
limited
by
low
chemical
stability,
conductivity
inappropriate
pore
sizes.
Conductive
two-dimensional
(2D)
robust
structural
skeletons
and/or
functionalized
surfaces
can
form
stabilizing
interactions
MOF
components,
enabling
fabrication
nanocomposites
characteristics.
Graphene
its
functional
derivatives
are
largest
class
2D
possess
remarkable
compositional
versatility,
diversity,
controllable
surface
chemistry.
Here,
we
critically
review
current
knowledge
concerning
growth,
structure,
graphene
derivatives,
MOFs,
graphene@MOF
composites
as
well
associated
structure-property-performance
relationships.
Synthetic
strategies
preparing
tuning
also
comprehensively
reviewed
together
applications
gas
storage/separation,
catalysis
(organo-,
electro-,
photocatalysis),
electrochemical
storage
conversion.
hybrids
practical
addressed,
revealing
areas
future
investigation.
We
hope
that
will
inspire
further
exploration
new
energy,
electronic,
biomedical,
photocatalysis
studies
on
previously
unreported
known
reveal
potential
"diamonds
rough".
Catalysis Science & Technology,
Год журнала:
2021,
Номер
11(12), С. 3946 - 3989
Опубликована: Янв. 1, 2021
The
presented
review
focuses
on
design
strategies
to
develop
tailor-made
MOFs/CPs
of
main
group,
transition
and
inner-transition
elements
their
photocatalytic
properties
decompose
dyes
in
wastewater
discharge
mechanism.
ACS Applied Materials & Interfaces,
Год журнала:
2022,
Номер
14(8), С. 9970 - 9986
Опубликована: Фев. 17, 2022
The
development
of
materials
with
outstanding
performance
for
sensitive
and
selective
detection
multiple
analytes
is
essential
the
human
health
society.
Luminescent
metal-organic
frameworks
(LMOFs)
have
controllable
surface
pore
sizes
excellent
optical
properties.
Therefore,
a
variety
LMOF-based
sensors
diverse
functions
can
be
easily
designed
applied.
Furthermore,
introduction
energy
transfer
(ET)
into
LMOFs
(ET-LMOFs)
could
provide
richer
design
concept
much
more
accurate
sensing
performance.
In
this
review,
we
focus
on
recent
five
years
advances
in
ET-LMOF-based
materials,
an
emphasis
photochemical
photophysical
mechanisms.
We
discuss
detail
possible
processes
within
MOF
structure
or
between
MOFs
guest
materials.
Finally,
applications
are
highlighted.
