Journal of Water Process Engineering, Год журнала: 2024, Номер 69, С. 106876 - 106876
Опубликована: Дек. 30, 2024
Язык: Английский
Journal of Water Process Engineering, Год журнала: 2024, Номер 69, С. 106876 - 106876
Опубликована: Дек. 30, 2024
Язык: Английский
Journal of environmental chemical engineering, Год журнала: 2025, Номер unknown, С. 115552 - 115552
Опубликована: Янв. 1, 2025
Язык: Английский
Процитировано
3Separation and Purification Technology, Год журнала: 2024, Номер unknown, С. 129768 - 129768
Опубликована: Сен. 1, 2024
Язык: Английский
Процитировано
14Applied Catalysis B Environment and Energy, Год журнала: 2024, Номер unknown, С. 124706 - 124706
Опубликована: Окт. 1, 2024
Язык: Английский
Процитировано
9Small, Год журнала: 2024, Номер unknown
Опубликована: Ноя. 3, 2024
Abstract Olefin‐linked covalent organic frameworks (OL‐COFs) show great promise for visible‐light‐driven photocatalysis. Manipulating atomic‐level donor–acceptor interactions in OL‐COFs is key to understanding their exciton effects this system. Here, three are presented with orthorhombic lattice structures, synthesized via Knoevenagel polycondensation reaction of terephthalaldehyde and tetratopic monomers featuring phenyl, benzo[c][1,2,5]oxadiazole, benzo[c][1,2,5]thiadiazole moieties. These feature tunable interactions, making them ideal studying olefin‐linked systems. Comprehensive analyses, including temperature‐dependent photoluminescence spectra, ultrafast spectroscopy, theoretical calculations, reveal that stronger lead reduced binding energy ( E b ), accelerated dissociation, longer‐lived photogenerated charges, thereby enhancing photocatalytic performance. Notably, The TMO‐BDA COF, the lowest , demonstrates superior activity one‐pot sequential transformation excellent catalytic performance gram‐scale reactions, highlighting its potential practical applications. This work provides valuable insights into regulating effect at molecular level OL‐COFs, offering pathways enhance efficiency.
Язык: Английский
Процитировано
5Chemical Engineering Journal, Год журнала: 2024, Номер unknown, С. 158649 - 158649
Опубликована: Дек. 1, 2024
Язык: Английский
Процитировано
5Sustainable materials and technologies, Год журнала: 2024, Номер unknown, С. e01189 - e01189
Опубликована: Ноя. 1, 2024
Язык: Английский
Процитировано
4Journal of Material Science and Technology, Год журнала: 2025, Номер unknown
Опубликована: Март 1, 2025
Язык: Английский
Процитировано
0ACS Applied Nano Materials, Год журнала: 2025, Номер unknown
Опубликована: Март 28, 2025
Язык: Английский
Процитировано
0Sustainable materials and technologies, Год журнала: 2025, Номер unknown, С. e01376 - e01376
Опубликована: Март 1, 2025
Язык: Английский
Процитировано
0Chemical Physics Reviews, Год журнала: 2025, Номер 6(2)
Опубликована: Апрель 7, 2025
Ultrasmall metal nanoclusters are revolutionary developments in sustainable chemical synthesis and electrochemical energy conversion. Critical activities including the oxygen evolution reaction, reduction electrosynthesis of urea via nitrate carbon dioxide co-reduction addressed by their distinctive atomic-scale designs, which provide remarkable catalytic activity, selectivity, stability. Recent advancements design these materials compiled this study, highlights how electrical characteristics structural tunability enable high-efficiency conversions. Important issues examined critically, along with new approaches to overcome them, such as operational stability, scalable manufacturing, financial constraints noble metals. Innovative strategies machine learning-guided catalyst tuning, hybrid material systems, synergistic effects given special attention. This analysis offers a road map for overcoming sophisticated catalysts' present drawbacks combining computational modeling experimental observations. Their potential transform technologies promote creation environmentally benign, solutions applications is highlighted debate. The importance single-atom catalysts ultrasmall meeting urgent worldwide need study.
Язык: Английский
Процитировано
0