Two stable metal–organic frameworks with new topology constructed from formic acid-coordinated trinuclear clusters for natural gas purification
Separation and Purification Technology,
Год журнала:
2025,
Номер
363, С. 132308 - 132308
Опубликована: Фев. 28, 2025
Язык: Английский
ROS-related nanoparticles for the management of Alzheimer’s disease: Wielding the double-edged sword
Chemical Engineering Journal,
Год журнала:
2025,
Номер
unknown, С. 161784 - 161784
Опубликована: Март 1, 2025
Язык: Английский
Dual-Functional Amino-MOF with Enhanced Ice Suppression and Intrinsic Photothermal Activity for High-Performance Oocyte Cryopreservation
ACS Applied Bio Materials,
Год журнала:
2025,
Номер
unknown
Опубликована: Апрель 28, 2025
The
current
vitrification-based
oocyte
cryopreservation
relies
on
inherently
cytotoxic
high-concentration
cryoprotective
agents
(CPAs),
leading
to
suboptimal
post-thaw
survival
rates
and
diminished
developmental
competence.
To
address
this,
we
developed
a
series
of
highly
biocompatible
amino-functionalized
iron-based
metal-organic
frameworks
(Fe-MOFs)
via
facile
hydrothermal
method
synergistically
suppress
ice
crystallization
minimize
the
reliance
toxic
CPAs.
Among
synthesized
materials,
2NH2-MIL88(Fe)
demonstrated
exceptional
ice-inhibition
performance,
reducing
crystal
size
16.78%
that
observed
in
pure
water,
significantly
outperforming
its
nonaminated
counterpart
MIL88(Fe)
monoaminated
NH2-MIL88(Fe).
Notably,
exhibited
an
unprecedented
intrinsic
photothermal
response
without
requiring
photosensitizer
modification,
achieving
rapid
temperature
elevation
from
25
86.6
°C
under
808
nm
laser
irradiation
(1
W/cm2,
1
min).
When
applied
mouse
cryopreservation,
this
dual-functional
amino-MOF
enabled
complete
elimination
dimethyl
sulfoxide
(DMSO)
CPAs
while
maintaining
rate
95.1%.
Our
findings
establish
dual
correlation
between
amino
group
density
both
ice-growth
suppression
efficiency
revealing
synergistic
mechanism
for
enhancement.
This
structure-function
relationship
provides
critical
insights
rational
design
next-generation
nano-CPAs.
Язык: Английский
Nanochannel functionalization using POFs: Progress and prospects
Advances in Colloid and Interface Science,
Год журнала:
2025,
Номер
342, С. 103533 - 103533
Опубликована: Апрель 28, 2025
Язык: Английский
Sustainable Green Synthesis, Characterization and Anti-Microbial Testing of Cu-Based Metal-Organic Framework (MOF)/TiO2 Nanocomposites Derived from Cinnamomum Verum Bark
Rohini Sumitra Rajdatta Kadam,
Deepashree D. Kamble,
Aslam Khan
и другие.
Journal for Research in Applied Sciences and Biotechnology,
Год журнала:
2025,
Номер
4(2), С. 18 - 26
Опубликована: Апрель 12, 2025
This
research
work
is
aimed
at
green
synthesis
with
sustainability
towards
the
production
of
copper
(Cu)-Based
Metal
Organic
Framework
(MOF)
and
their
doping
in
titanium
dioxide
(TiO₂)
nanoparticles
synthesized
using
a
natural
reductant
stabilizer,
Cinnamomum
verum
(C.
verum)
bark
extract.
It
an
eco-friendly
technique
because
bioactive
compounds
such
as
flavonoids
polyphenols
present
C.
help
reduce
stabilize
metal
ions,
thus
replacing
toxic
chemicals.
The
Cu-doped
TiO₂
nanocomposites
are
found
to
absorb
increased
visible
light
owing
reduced
bandgap
from
doping,
observed
by
UV-Vis
Diffuse
Reflectance
Spectroscopy
(UV-DRS).
scanning
electron
microscopy
energy-dispersive
X-ray
spectroscopy
analysis
indicates
that
distribution
Cu
matrix
uniform,
which
offers
structural
stability
functional
efficacy.
Well-diffusion
experiments
on
antimicrobial
studies
reveal
produced
this
process
have
excellent
activity,
especially
Staphylococcus
aureus.
attributed
photoinduced
generation
ROS,
can
break
cell
walls
interfere
microbial
metabolism.
for
Cu-TiO2
nanocomposite
totally
compliance
chemistry
principles
produces
having
strong
photocatalytic
action.
These
results
outline
grand
potential
methods-prepared
be
used
coatings,
environmental
remediation,
much
more
-
opening
promising
route
sustainable
nanotechnology
development.
Язык: Английский
Climate friendly MOFs synthesis for drug delivery systems by integrating AI, intelligent manufacturing, and quantum solutions in industry 6.0 sustainable approach
Toxicology Research,
Год журнала:
2024,
Номер
14(1)
Опубликована: Дек. 31, 2024
Abstract
Since
the
Industrial
Revolution,
ecological
damage,
ecosystem
disruption,
and
climate
change
acceleration
have
frequently
resulted
from
human
advancement
at
price
of
environment.
Due
to
rise
in
illnesses,
Industry
6.0
calls
for
a
renewed
dedication
sustainability
with
latest
technologies.
Focused
research
creative
solutions
are
needed
achieve
UN
Sustainable
Development
Goals
(SDGs),
especially
3,
9,
13,
14,
15,
17.
A
promising
sustainable
technology
enhancing
healthcare
while
reducing
environmental
effect
is
Metal
Organic
Frameworks
(MOFs).
MOFs
perfect
drug
administration
because
their
high
surface
areas,
adjustable
pore
sizes,
remarkable
drug-loading
capacities.
They
created
by
combining
advanced
artificial
intelligence,
intelligent
manufacturing,
quantum
computing.
Researchers
can
create
functional
groups
or
ligands
that
bind
selectively
target
cells
tissues,
minimizing
off-target
effects,
thanks
distinct
benefits
families
like
MIL,
HKUST,
UiO,
ZIF
etc.
offer
targeted
delivery.
Combining
other
nanomaterials
results
multipurpose
systems
handle
challenging
biomedical
issues.
Despite
its
promise,
there
still
issues
MOFs’
possible
toxicity
long-term
stability
physiological
settings.
To
advance
medicinal
applications,
these
problems
must
be
resolved.
increase
usefulness
medicine
critically
analysing
limitations
putting
up
alternatives.
The
creation
technologies
(additive
manufacturing
etc.)
delivery
prime
example
how
scientific
stewardship
may
coexist
provide
advantageous
both
people
Язык: Английский