Inorganic Chemistry, Год журнала: 2024, Номер unknown
Опубликована: Сен. 23, 2024
Defect engineering is an extremely effective strategy for modifying metal-organic frameworks (MOFs), which can break through the application limitations of traditional MOFs and enhance their functionality. Herein, we report a highly robust nanoporous thulium(III)-organic framework, {[Tm
Язык: Английский
Angewandte Chemie International Edition, Год журнала: 2024, Номер 63(28)
Опубликована: Апрель 27, 2024
Abstract The poor electrocatalytic stability and rapid deactivation of metal electrocatalysts are always present in the conversion carbon dioxide (CO 2 ) due to harsh reduction condition. Herein, we demonstrate controllable dispersion ultrafine bismuth nanoparticles among hollow shell (Bi@C‐700‐4) simply by a thermal‐driven diffusion process. confinement effect nitrogen‐doped matrix is able low surface energy against easy aggregation commonly observed for thermal treatment. On basis synergistic between matrix, highly dispersed active sites render obviously improved activity CO into formate. situ experimental observations on process theoretical calculations reveal that incorporation with would promote activation formation key intermediate (*OCHO), thus leading enhanced activity, Faradaic Efficiency (FE) formate about 94.8 % long‐time stability. Furthermore, coupling an anode 5‐hydroxymethylfurfural oxidation reaction (HMFOR) solar‐driven system renders high 2,5‐furandicarboxylic acid (FDCA) yield 81.2 %, presenting impressive solar‐to‐fuel conversion.
Язык: Английский
Процитировано
17
Angewandte Chemie International Edition, Год журнала: 2024, Номер 63(38)
Опубликована: Июнь 21, 2024
Electrochemical reduction reactions, as cathodic processes in many energy-related devices, significantly impact the overall efficiency determined mainly by performance of electrocatalysts. Metal-organic frameworks (MOFs) derived carbon-supported metal materials have become one star electrocatalysts due to their tunable structure and composition through ligand design screening. However, for different electroreduction required active species vary phase component, electronic state, catalytic center configuration, hence requiring effective customization. From this perspective, review comprehensively analyzes structural principles, loading strategies, practical performance, complex mechanisms, thereby providing insights guidance future rational such catalysts.
Язык: Английский
Процитировано
15
ACS Applied Materials & Interfaces, Год журнала: 2024, Номер 16(2), С. 2397 - 2407
Опубликована: Янв. 5, 2024
Hard carbons (HCs), while a leading candidate for sodium-ion battery (SIB) anode materials, face challenges in their unfavorable sodiation kinetics since the intricate microstructure of HCs complicates Na+ diffusion channel. Herein, Hovenia dulcis-derived HC realizes markedly enhanced high-rate performance virtue dual-functionalized Ca. The interlayer doped Ca2+ effectively enlarges spacing, situ-formed CaSe templates induce formation hierarchical pore structures and intrinsic defects, significantly providing fast channels abundant active sites thus enhancing sodium storage kinetics. Achieved by synergistic effect regulation microcrystalline structures, optimized shows remarkable enhancements, including high reversible capacity 350.3 mA h g–1 after 50 cycles at g–1, high-capacity retention rate 95.3% 1000 cycles, excellent (108.4 2 A g–1). This work sheds light on valuable insight into structural adjustment HCs, facilitating widespread utilization SIBs.
Язык: Английский
Процитировано
14
Small, Год журнала: 2024, Номер 20(26)
Опубликована: Янв. 14, 2024
Abstract Featured with the attractive properties such as large surface area, unique atomic layer thickness, excellent electronic conductivity, and superior catalytic activity, layered metal chalcogenides (LMCs) have received considerable research attention in electrocatalytic applications. In this review, approaches developed to synthesize LMCs‐based electrocatalysts are summarized. Recent progress composites for electrochemical energy conversion applications including oxygen reduction reaction, carbon dioxide evolution hydrogen overall water splitting, nitrogen reaction is reviewed, potential opportunities practical obstacles development of high‐performing active substances also discussed. This review may provide an inspiring guidance developing high‐performance LMCs
Язык: Английский
Процитировано
14
Inorganic Chemistry, Год журнала: 2024, Номер unknown
Опубликована: Сен. 23, 2024
Defect engineering is an extremely effective strategy for modifying metal-organic frameworks (MOFs), which can break through the application limitations of traditional MOFs and enhance their functionality. Herein, we report a highly robust nanoporous thulium(III)-organic framework, {[Tm
Язык: Английский
Процитировано
14