Strategies to achieve effective nitrogen activation

Carbon Energy, Год журнала: 2024, Номер 6(5)

Опубликована: Фев. 23, 2024

Abstract Ammonia serves as a crucial chemical raw material and hydrogen energy carrier. Aqueous electrocatalytic nitrogen reduction reaction (NRR), powered by renewable energy, has attracted tremendous interest during the past few years. Although some achievements have been revealed in aqueous NRR, significant challenges also identified. The activity selectivity are fundamentally limited activation competitive evolution. This review focuses on hurdles of delves into complementary strategies, including materials design system optimization (reactor, electrolyte, mediator). Then, it introduces advanced interdisciplinary technologies that recently emerged for using high‐energy physics such plasma triboelectrification. With better understanding corresponding mechanisms coming years, these potential to be extended further applications. provides insight stability different systems. We then recommend rigorous detailed protocol investigating NRR performance highlight several research directions this exciting field, coupling with applications, situ/operando characterizations, theoretical calculations.

Язык: Английский

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Defect Engineering in a Nanoporous Thulium–Organic Framework in Catalyzing Knoevenagel Condensation and Chemical CO₂ Fixation

Inorganic Chemistry, Год журнала: 2024, Номер unknown

Опубликована: Сен. 23, 2024

Defect engineering is an extremely effective strategy for modifying metal-organic frameworks (MOFs), which can break through the application limitations of traditional MOFs and enhance their functionality. Herein, we report a highly robust nanoporous thulium(III)-organic framework, {[Tm

Язык: Английский

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Recent Progress and Perspectives on Metal–Organic Framework-Based Electrode Materials for Metal-Ion Batteries and Supercapacitors

Energy & Fuels, Год журнала: 2024, Номер 38(15), С. 13796 - 13818

Опубликована: Июль 11, 2024

Язык: Английский

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Microenvironment Engineering of Heterogeneous Catalysts for Liquid-Phase Environmental Catalysis

Chemical Reviews, Год журнала: 2024, Номер 124(20), С. 11348 - 11434

Опубликована: Окт. 9, 2024

Environmental catalysis has emerged as a scientific frontier in mitigating water pollution and advancing circular chemistry reaction microenvironment significantly influences the catalytic performance efficiency. This review delves into engineering within liquid-phase environmental catalysis, categorizing microenvironments four scales: atom/molecule-level modulation, nano/microscale-confined structures, interface surface regulation, external field effects. Each category is analyzed for its unique characteristics merits, emphasizing potential to enhance efficiency selectivity. Following this overview, we introduced recent advancements advanced material system design promote (e.g., purification, transformation value-added products, green synthesis), leveraging state-of-the-art technologies. These discussions showcase was applied different reactions fine-tune regimes improve from both thermodynamics kinetics perspectives. Lastly, discussed challenges future directions engineering. underscores of intelligent materials drive development more effective sustainable solutions decontamination.

Язык: Английский

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Bifunctional two-dimensional copper-organic framework for high catalytic performance on cycloaddition of CO2 with epoxides and deacetalization-Knoevenagel condensation

Journal of Molecular Structure, Год журнала: 2024, Номер 1306, С. 137849 - 137849

Опубликована: Фев. 22, 2024

Язык: Английский

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