Advanced Optical Materials,
Год журнала:
2024,
Номер
12(20)
Опубликована: Май 10, 2024
Abstract
Reflective
electrochromic
(EC)
technology
is
expected
to
e‐paper
display
field,
and
integrating
optical
reflective
electrolyte
as
the
layer
a
common
strategy
for
constructing
EC
devices.
Compositing
inorganic
particles
electrolytes
one
of
simplest
most
efficient
composite
methods,
but
these
usually
cannot
perform
well
together
in
terms
both
electrochemical
properties.
Herein,
TiO
2
nanoparticles
are
added
ethyl
viologen‐based
ionogel
(T‐EVG,
typical
kind
EC/electrolyte)
have
highest
visible
light
reflectivity
best
performance
compared
with
SiO
,
Al
O
3
ZnO
nanoparticles,
which
attributed
electro‐induced
self‐reduction
produced
T‐EVG
during
cycling.
Meanwhile,
corresponding
devices
can
red,
green,
blue,
high
contrast
(CIE
Lab:
ΔE>38),
fast
switching
spend
(<4
s,
fastest
5
Hz),
ultra‐low
power
density
(<4.0
mW
cm
−2
),
excellent
cycling
stability
(>85%
retained
after
10
000
cycles).
Finally,
simple
3×3
pixelated
array
prepared,
single‐
multi‐point
(including
diagonal
points)
multi‐color
effects
realized
through
active‐matrix
driving
high‐frequency
refresh,
demonstrating
its
application
value
high‐performance
display.
Inorganic Chemistry,
Год журнала:
2025,
Номер
unknown
Опубликована: Апрель 3, 2025
Construction
of
coordination
nanosheets
(CONASHs)
containing
both
inert
and
labile
metal
ions
together
is
fundamentally
significant
but
remains
synthetically
unachievable
until
now
difficult
to
realize
via
conventional
synthetic
approach
CONASHs
due
variable
complexation
conditions
between
heterometal
organic
ligands.
Here,
we
demonstrate
a
strategy
harness
into
structure
by
introducing
the
concept
metalloligand.
Metalloligands
comprising
ion
(Os2+/Ru2+)
free
coordinating
sites
are
designed
synthesized
can
be
further
used
as
ligand
bind
(Fe2+)
for
building
heterometallic
(HMCONASHs).
Following
this,
two
HMCONASHs
homoleptic
complexes
constructed
that
show
broad
absorption
electrochemical
window
with
reversible
dual
redox
activity.
Further,
HMCONASH
films
exhibit
multicolor
electrochromism
at
different
voltages,
indicating
their
potential
various
applications.
This
may
open
create
diverse
structures
functions
hard
achieve
traditional
approach.
Advanced Functional Materials,
Год журнала:
2023,
Номер
34(17)
Опубликована: Дек. 31, 2023
Abstract
Electrochromic
(EC)
technology
is
regarded
as
one
of
the
most
promising
candidates
for
next‐generation
reflective
displays,
owing
to
its
advantages
outstanding
color
adjustability,
low
energy
consumption,
vivid
color,
and
flexibility,
etc.
However,
current
EC
displays
are
seriously
restricted
by
complicated
expensive
patterned
methods.
Herein,
a
facile
low‐cost
route
developed
achieve
which
fabricated
based
on
combination
an
easily‐obtained
material
poly(3,4‐ethylenedioxythiophene):poly(styrenesulfonate)
(PEDOT:PSS)
efficient
photo‐crosslinked
additive
(2,4‐hexadiyne‐1,6‐diol,
HDDO).
The
micrometer‐scale
patterns
(<50
µm)
can
be
achieved
in
situ
process.
As‐prepared
devices
show
great
performances
containing
fast
response
(<0.5
s),
good
reversibility
(>10
000
cycles)
high
coloration
efficiency
(274.75
cm
2
C
−1
).
More
importantly,
applications
logo,
QR
code,
price
tag
demonstrated
successfully.
Overall,
exploration
suggests
efficient,
low‐cost,
method
produce
with
performance,
undoubtedly
promote
further
development
application
displays.
Advanced Optical Materials,
Год журнала:
2024,
Номер
12(20)
Опубликована: Май 10, 2024
Abstract
Reflective
electrochromic
(EC)
technology
is
expected
to
e‐paper
display
field,
and
integrating
optical
reflective
electrolyte
as
the
layer
a
common
strategy
for
constructing
EC
devices.
Compositing
inorganic
particles
electrolytes
one
of
simplest
most
efficient
composite
methods,
but
these
usually
cannot
perform
well
together
in
terms
both
electrochemical
properties.
Herein,
TiO
2
nanoparticles
are
added
ethyl
viologen‐based
ionogel
(T‐EVG,
typical
kind
EC/electrolyte)
have
highest
visible
light
reflectivity
best
performance
compared
with
SiO
,
Al
O
3
ZnO
nanoparticles,
which
attributed
electro‐induced
self‐reduction
produced
T‐EVG
during
cycling.
Meanwhile,
corresponding
devices
can
red,
green,
blue,
high
contrast
(CIE
Lab:
ΔE>38),
fast
switching
spend
(<4
s,
fastest
5
Hz),
ultra‐low
power
density
(<4.0
mW
cm
−2
),
excellent
cycling
stability
(>85%
retained
after
10
000
cycles).
Finally,
simple
3×3
pixelated
array
prepared,
single‐
multi‐point
(including
diagonal
points)
multi‐color
effects
realized
through
active‐matrix
driving
high‐frequency
refresh,
demonstrating
its
application
value
high‐performance
display.