A Cellulose Encapsulated Composite Electrolyte Design: Towards Chemically and Mechanically Enhanced Solid-sodium Batteries DOI Creative Commons
Dong Shu, Geng Xie, Shihong Xu

и другие.

Опубликована: Март 25, 2024

Replacing liquid electrolytes with solid ionic conductors attracts increasing attention due to the potential of improved battery safety. Solid-state batteries show for further increased energy/power density by eliminating use packaging accessories unit cells. Sulfide- and halide-based ceramic exhibit comparable conductivity electrolytes. These materials, however, are inherently brittle, making them unfavorable applications. Here, we report a mechanically enhanced composite Na+ conductor that contains 92.5 wt% sodium thioantimonate (Na3SbS4, NSS) 7.5 carboxymethylcellulose (CMC); latter serves as binder an electrochemically inert encapsulation layer. The constituents were integrated at particle level, providing NSS-level in NSS-CMC composite, more than five-fold decrease electrolyte thickness obtained provided increase conductance compared NSS pellets. Resulting from CMC encapsulation, this shows moisture resistivity electrochemical stability, which significantly promotes cycling performance NSS- based solid-state batteries, improves ductility material. This work demonstrates well-controlled, orthogonal process ceramic-rich, processing – independent streams formation along solvent-assisted environment. provides insights into interplay among solvent, polymeric binder, particles synthesis, implies critical importance identifying appropriate solvent/binder system precise control complicated process. Finally, also valuable designing tailorable components via fundamental understanding effect on overall ductility.

Язык: Английский

Recent advances on cellulose-based solid polymer electrolytes DOI Creative Commons

Xiaoqi Gong,

Jiasheng Wang,

Linfeng Zhong

и другие.

Industrial Chemistry and Materials, Год журнала: 2024, Номер unknown

Опубликована: Янв. 1, 2024

We comprehensively reviewed the recent achievements in cellulose-based solid electrolytes, including diverse modifications and compositing strategies for improving ionic conductivity, current challenges future prospects are discussed.

Язык: Английский

Процитировано

9
Na‐K Interlayer Driven Na‐NASICON Solid‐State Batteries DOI Open Access
Yang Li, Zhichao Wang, Chen Sun

и другие.

Advanced Functional Materials, Год журнала: 2025, Номер unknown

Опубликована: Фев. 10, 2025

Abstract Solid‐state sodium batteries are deemed as a highly promising candidate for medium and long‐term stationary energy storage. But, the solid‐state electrolyte with desirable ionic conductivity high stability against solid metal electrodes remains significant challenge research development of batteries. In this research, approach in‐situ formed Na‐K interlayer is put forward, wherein K + electrochemically migrates from K‐substituted NASICON‐structure ceramic toward interface Na electrode, locally dynamically forming metal. Therefore, compatibility between electrolytes electrode obviously enhanced. Accordingly, area specific resistance solid/solid contact gets reduced to 29.9 Ω cm 2 room temperature critical current density 1.3 mA −2 achieved. meantime, Na/Na 3 Zr Si PO 12 ‐0.005K/Na can steadily operate 1400 h at 0.2 . Moreover, electrolyte‐based paired polyanion layered ion cathodes constructed highlight superiority well‐designed electrolyte/metal interface.

Язык: Английский

Процитировано

1
Anion trapping-coupling strategy driven asymmetric nonflammable gel electrolyte for high performance sodium batteries DOI
Meng Yang, Fan Feng,

Junhong Guo

и другие.

Energy storage materials, Год журнала: 2024, Номер 70, С. 103492 - 103492

Опубликована: Май 16, 2024

Язык: Английский

Процитировано

5
High-Strength, Thin, and Lightweight Solid Polymer Electrolyte for Superior All-Solid-State Sodium Metal Batteries DOI
Jinbo Zhang,

Yanxia Su,

Yuqian Qiu

и другие.

ACS Applied Materials & Interfaces, Год журнала: 2024, Номер 16(23), С. 30128 - 30136

Опубликована: Июнь 4, 2024

The utilization of solid polymer electrolytes (SPEs) in all-solid-state sodium metal batteries has been extensively explored due to their excellent flexibility, processability adaptability match roll-to-roll manufacturing processes, and good interfacial contact with a high-capacity Na anode; however, SPEs are still impeded by inadequate mechanical strength, excessive thickness, poor stability anodes. Herein, robust, thin, cost-effective polyethylene (PE) film is employed as skeleton for infiltrating poly(ethylene oxide)-sodium bis(trifluoromethanesulfonyl)imide (PEO/NaTFSI) fabricate PE-PEO/NaTFSI SPE. resulting SPE features remarkable thickness 25 μm, lightweight property (2.1 mg cm-2), superior strength (tensile = 100.3 MPa), flexibility. also shows an ionic conductivity 9.4 × 10-5 S cm-1 at 60 °C enhanced anode. Benefiting from these advantages, the assembled Na-Na symmetric cells show high critical current density (1 mA cm-2) long-term cycling (3000 h 0.3 cm-2). Na||PE-PEO/NaTFSI||Na3V2(PO4)3 coin exhibit performance, retaining 93% initial capacity 190 cycles when matched 6 cm-2 cathode loading. Meanwhile, pouch cell can work stably after abuse testing, proving its flexibility safety. This offers promising strategy simultaneously achieve high-strength, safe solid-state batteries.

Язык: Английский

Процитировано

5
Cellulose-Encapsulated Composite Electrolyte Design: Toward Chemically and Mechanically Enhanced Solid-Sodium Batteries DOI
Dong Shu, Geng Xie, Shihong Xu

и другие.

ACS Nano, Год журнала: 2024, Номер 18(25), С. 16285 - 16296

Опубликована: Июнь 12, 2024

Sulfide- and halide-based ceramic ionic conductors exhibit comparable conductivity with liquid electrolytes are candidates for high-energy- high-power-density all-solid-state batteries. These materials, however, inherently brittle, making them unfavorable applications. Here, we report a mechanically enhanced composite Na+ conductor that contains 92.5 wt % of sodium thioantimonate (Na3SbS4, NSS) 7.5 carboxymethyl cellulose (CMC); the latter serves as binder an electrochemically inert encapsulation layer. The constituents were integrated at particle level, providing NSS-level in NSS–CMC composite. more than 5-fold decrease electrolyte thickness obtained provided increase conductance compared to NSS pellets. As result CMC encapsulation, this shows increased moisture resistivity electrochemical stability, which significantly promotes cycling performance NSS-based solid-state This work demonstrates well-controlled, orthogonal process ceramic-rich, processing: independent streams formation along solvent-assisted environment. also provides insights into interplay among solvent, polymeric binder, particles synthesis implies critical importance identifying appropriate solvent/binder system precise control complicated process.

Язык: Английский

Процитировано

5
Structural Engineering Developments in Sulfide Solid-State Electrolytes for Lithium and Sodium Solid-State Batteries DOI

Mohammad Sufiyan Nafis,

Zhiming Liang, Se-Hee Lee

и другие.

Nano Energy, Год журнала: 2024, Номер 133, С. 110447 - 110447

Опубликована: Ноя. 7, 2024

Язык: Английский

Процитировано

5
Inorganic Solid‐State Electrolytes for Solid‐State Sodium Batteries: Electrolyte Design and Interfacial Challenges DOI Creative Commons
Dongsoo Lee, Ashok Kumar Kakarla, Seho Sun

и другие.

ChemElectroChem, Год журнала: 2025, Номер 12(3)

Опубликована: Янв. 6, 2025

Abstract Recent advancements in inorganic solid electrolytes (ISEs), achieving sodium (Na)‐ion conductivities exceeding 10 ‐2 S cm ‐1 at room temperature (RT), have generated significant interest the development of solid‐state batteries (SSSBs). However, ISEs face challenges such as their limited electrochemical stability windows (ESWs) and compatibility issues with high‐capacity, high‐voltage cathode materials Na metal anodes. The success high‐performance SSSBs hinges on developing ideal that deliver high + ion conductivities, robust chemical stability, well constructed electrode/ISE interfaces. This review explores fundamental principles strategies to optimize SSSB performance by addressing related interfaces, emphasizing many interfacial are intrinsically linked ISE properties. It highlights recent research, including mechanisms Na‐ion conduction key factors influencing it, crystal structure, lattice dynamics, point defects, grain boundaries. also discusses prototyping for cell design from perspectives material defect chemistry. Additionally, identifies future opportunities advancing provides rational solutions guide research toward practical realization SSSBs. Keywords: Solid‐state batteries; Inorganic electrolytes; Interfacial mechanism; Electrochemical window; Ionic conductivity; Modification

Язык: Английский

Процитировано

0
Aliovalent Cation Substitution in Na3Zr2Si2PO12 for Practical Solid-State Sodium Metal Batteries DOI

Jingxin He,

Shuaishuai Yang, Xiong Xiao

и другие.

Energy storage materials, Год журнала: 2025, Номер unknown, С. 104037 - 104037

Опубликована: Янв. 1, 2025

Язык: Английский

Процитировано

0
Ca‐substituted Na3SbS4 glass–ceramic electrolytes: Achieving high conductivity and excellent interfacial stability DOI

Yu Shen,

Huan Tao,

Jingxin Lu

и другие.

Journal of the American Ceramic Society, Год журнала: 2025, Номер unknown

Опубликована: Янв. 15, 2025

Abstract Super conductor Na 3 SbS 4 has received substantial attention in electrolyte research because of its high ionic conductivity and low grain boundary resistance. A breakthrough electrochemical stability with good yet to be captured. Calcium (Ca) appears as an ideal substitute for sodium (Na) due abundance geological resources, nontoxic properties, equivalent radius. The proposed 3‐2 x Ca glass–ceramic electrolytes were subsequently manufactured using ball milling heat treatment. results acquired the maximum 1.59 mS cm −1 at room temperature, which reached commercial use level when compared current popular lithium‐ion battery. Moreover, calcium ions partially replaced sites while creating massive vacancies maintain charge neutrality, resulting fast ion transport. Furthermore, a more stable bond Ca–S was formed interface, inhibited additional reactions electrolyte–metal interface demonstrated exceptional cyclic stability, making it viable solid‐state sodium‐ion batteries.

Язык: Английский

Процитировано

0
Sodiophilic design for sodium-metal batteries: progress and prospects DOI

Wanjie Gao,

Yinxu Lu,

Xu Tan

и другие.

Energy & Environmental Science, Год журнала: 2025, Номер unknown

Опубликована: Янв. 1, 2025

In this review, the formation mechanism of sodium dendrite and corresponding battery failure causes are introduced in detail, latest advances sodiophilic design strategies systematically discussed.

Язык: Английский

Процитировано

0