Ultraselective Permeable Polyamide Membranes Prepared via Interfacial Polymerization of Alkane and Deep Eutectic Solvent DOI
Jun S. Liu, Yang Yang, Shuai Gu

и другие.

Angewandte Chemie, Год журнала: 2025, Номер unknown

Опубликована: Май 28, 2025

Abstract Conventional alkane/water interfacial polymerization encounters significant challenges in constructing polyamide membranes with precise nanoconfinement. This requires advanced strategies that simultaneously slow the diffusion kinetics and suppress side reactions, facilitating formation of a well‐defined pore architecture. Herein, we introduced an alkane/deep eutectic solvent (DES) approach, allowing preparation ultraselective permeable membranes. The DES, acting as anhydrous solvent, effectively prevents while its robust hydrogen bonding network finely regulates behavior amine monomers induces assembly oligomers, affording membrane uniform subnanometer pores. Notably, strong DES enhances solvation monomers, which further promotes tuning structures functions. produced using specific (D‐PA) revealed exceptional NaCl/Na 2 SO 4 (165.8) separation selectivity, order magnitude larger than conventional membranes, coupled impressive water permeance up to 18.4 L m −2 h −1 bar . strategy offers paradigm shift fabrication for purification system.

Язык: Английский

Construction of Ti3C2Tx MXene with Hopping Migration Mechanism via Deep Eutectic Supramolecular Polymers Anode for Sodium Ion Batteries DOI

Guanghuan Ma,

Xin Jin,

Jiangpu Yang

и другие.

Advanced Functional Materials, Год журнала: 2025, Номер unknown

Опубликована: Апрель 16, 2025

Abstract The potential applications of high‐power sodium‐ion batteries are numerous, including use in distributed energy storage power plants and electric vehicles. In order to develop anode materials with fast reaction kinetics high reversibility, the deep eutectic supramolecular polymers electrode is pioneered. LA‐DESP situ polymerized on Ti 3 C 2 T x MXene surface, resulting that exhibit rapid high‐capacity retention. polymer network constructs channels for high‐speed transport ions electrons, also provides more Na + pseudocapacitance sites. addition, superior mechanical properties help protect structure from damage during cycling, ultrastable storage. hopping migration mechanism through polymer‐constructed ion proposed. As SIBs half‐cells, it exhibits remarkable cycling performance 114.4 mAh g −1 a capacity loss only 5.1% at 1000 mA after 1500 cycles. This study opens new way rationally design promotes application electrodes.

Язык: Английский

Процитировано

0

Fast, ultradeep, and continuous desulfurization of heavy gasoil in novel oscillatory basket central baffled reactor using MnO2-incorparted Fe2O3- supported activated carbon catalyst DOI

Jasim I. Humadi,

Wadood T. Mohammed

Fuel, Год журнала: 2025, Номер 400, С. 135716 - 135716

Опубликована: Май 24, 2025

Язык: Английский

Процитировано

0

Efficient oxidative desulfurization of high-sulfur petroleum coke over polyoxometalates HPA coupled CeO2 DOI
Fengxin Li, Yan Wang, Fumin Li

и другие.

Surfaces and Interfaces, Год журнала: 2025, Номер unknown, С. 106821 - 106821

Опубликована: Май 1, 2025

Язык: Английский

Процитировано

0

Ultraselective Permeable Polyamide Membranes Prepared via Interfacial Polymerization of Alkane and Deep Eutectic Solvent DOI
Jun S. Liu, Yang Yang, Shuai Gu

и другие.

Angewandte Chemie International Edition, Год журнала: 2025, Номер unknown

Опубликована: Май 28, 2025

Conventional alkane/water interfacial polymerization encounters significant challenges in constructing polyamide membranes with precise nanoconfinement. This requires advanced strategies that simultaneously slow the diffusion kinetics and suppress side reactions, facilitating formation of a well-defined pore architecture. Herein, we introduced an alkane/deep eutectic solvent (DES) approach, allowing preparation ultraselective permeable membranes. The DES, acting as anhydrous solvent, effectively prevents while its robust hydrogen bonding network finely regulates behavior amine monomers induces assembly oligomers, affording membrane uniform subnanometer pores. Notably, strong DES enhances solvation monomers, which further promotes tuning structures functions. produced using specific (D-PA) revealed exceptional NaCl/Na2SO4 (165.8) separation selectivity, order magnitude larger than conventional membranes, coupled impressive water permeance up to 18.4 L m-2 h-1 bar-1. strategy offers paradigm shift fabrication for purification system.

Язык: Английский

Процитировано

0

Ultraselective Permeable Polyamide Membranes Prepared via Interfacial Polymerization of Alkane and Deep Eutectic Solvent DOI
Jun S. Liu, Yang Yang, Shuai Gu

и другие.

Angewandte Chemie, Год журнала: 2025, Номер unknown

Опубликована: Май 28, 2025

Abstract Conventional alkane/water interfacial polymerization encounters significant challenges in constructing polyamide membranes with precise nanoconfinement. This requires advanced strategies that simultaneously slow the diffusion kinetics and suppress side reactions, facilitating formation of a well‐defined pore architecture. Herein, we introduced an alkane/deep eutectic solvent (DES) approach, allowing preparation ultraselective permeable membranes. The DES, acting as anhydrous solvent, effectively prevents while its robust hydrogen bonding network finely regulates behavior amine monomers induces assembly oligomers, affording membrane uniform subnanometer pores. Notably, strong DES enhances solvation monomers, which further promotes tuning structures functions. produced using specific (D‐PA) revealed exceptional NaCl/Na 2 SO 4 (165.8) separation selectivity, order magnitude larger than conventional membranes, coupled impressive water permeance up to 18.4 L m −2 h −1 bar . strategy offers paradigm shift fabrication for purification system.

Язык: Английский

Процитировано

0