Journal of Chromatography A, Год журнала: 2024, Номер 1740, С. 465561 - 465561
Опубликована: Ноя. 27, 2024
Язык: Английский
Chemical Engineering Journal, Год журнала: 2025, Номер unknown, С. 160043 - 160043
Опубликована: Янв. 1, 2025
Язык: Английский
Процитировано
1
Journal of Chromatography A, Год журнала: 2025, Номер 1743, С. 465652 - 465652
Опубликована: Янв. 2, 2025
Язык: Английский
Процитировано
1
Separation and Purification Technology, Год журнала: 2024, Номер 355, С. 129624 - 129624
Опубликована: Сен. 13, 2024
Язык: Английский
Процитировано
6
Journal of Materials Chemistry A, Год журнала: 2024, Номер unknown
Опубликована: Дек. 10, 2024
This review focuses on pore engineering (intrinsic size, extrinsic porosity, and environment) in porous organic cages summarizes the roles of various fields.
Язык: Английский
Процитировано
3
Advanced Energy Materials, Год журнала: 2025, Номер unknown
Опубликована: Янв. 31, 2025
Abstract The advancement of nanofluidic membranes is critical for mimicking bioelectrogenic ion‐channel mechanisms and boosting output power density, essential sustainable energy applications. conversion efficiency these devices significantly relies on the ion conductivity permselectivity membranes. Membranes with aligned one‐dimentional (1D) pores, high pore organized dangling ionic groups are theorized to offer superior permeability selectivity, yet configurations remain underexplored. Herein, successful fabrication oriented covalent organic framework (COF) presented. These exhibit precisely cationic anionic sites within their channels, achieved through post‐synthetic modification using click chemistry, which shows conductivity. When incorporated into full‐cell thermo‐osmotic generators, deliver an impressive density 195 W m −2 under a 50‐fold salinity gradient (NaCl: 0.01 ‖ 0.5 ) along 35 K temperature differential. This substantially increases 2.41 times 471 −2 when enhanced tenfold, surpassing performance existing similar conditions thus offering promising avenue enhancing in resource utilization.
Язык: Английский
Процитировано
0
Smart Molecules, Год журнала: 2025, Номер unknown
Опубликована: Март 25, 2025
Abstract Covalent organic cages (COCs) are three‐dimensional molecules with permanent cavities, known for their ordered pore structures, excellent processability, and modular design. They have shown significant potential in applications such as gas adsorption, molecular separation, catalysis. Introducing chiral elements into COCs results confined which endows them unique functions expands application prospects. This review summarizes the research progress on covalent cages, focusing strategies incorporating elements, structures synthesis methods of representative COCs, advancements functions. Additionally, we provide perspectives future directions. We hope this will inspire further interest creativity among researchers field leading to development materials
Язык: Английский
Процитировано
0
Coordination Chemistry Reviews, Год журнала: 2025, Номер 535, С. 216648 - 216648
Опубликована: Апрель 2, 2025
Процитировано
0
Journal of Separation Science, Год журнала: 2025, Номер 48(4)
Опубликована: Апрель 1, 2025
In this study, reduced porous organic cages with homochiral secondary amine structure were immobilized on a silica gel surface, and derivative of 3,5-dimethyl phenyl carbamate amylose was coated onto the molecular cage-modified sphere to prepare chiral stationary phase co-modified cages. The prepared characterized using techniques such as scanning electron microscopy, infrared spectroscopy, thermogravimetric analysis. results confirmed successful preparation phase. 10 compounds selected systematically evaluate enantioselective performance new normal-phase chromatography for enantiomeric separation. experimental demonstrated that well separated phase, complete separation achieved trans-stilbene oxide, phenylethanol, 1-phenyl-1-propanol, all showing resolution greater than 1.5. contrast, showed only partial these compounds. study highlights synergistic effect in enhancing separation, demonstrating their significant potential development phases.
Язык: Английский
Процитировано
0
Advanced Materials, Год журнала: 2025, Номер unknown
Опубликована: Апрель 24, 2025
Abstract Advancements in membrane‐based separation hinge on the design of materials that transcend conventional limitations. Microporous materials, including metal–organic frameworks (MOFs), covalent–organic (COFs), macrocycles, and porous organic cages (POCs) offer unprecedented control over pore architecture, chemical functionality, transport properties, making them promising candidates for next‐generation membrane technologies. The well‐defined tunable micropores provide a pathway to directly address permeability‐selectivity trade‐off inherent polymer membranes. Here, this review explores latest advancements these four representative microporous membranes, emphasizing their breakthroughs hydrocarbon separation, liquid‐phase molecular sieving, ion‐selective transport, particularly focusing structure‐performance relationships. While tailored structures enable exceptional performance, practical adoption requires overcoming hurdles scalability, durability, compatibility with industrial processes. By offering insights into structure optimization innovative strategies, provides roadmap advancing membranes from laboratory innovation real‐world implementation, ultimately supporting global sustainability goals through energy‐efficient
Язык: Английский
Процитировано
0
Journal of Zhejiang University. Science A, Год журнала: 2025, Номер 26(4), С. 285 - 304
Опубликована: Апрель 1, 2025
Язык: Английский
Процитировано
0