Three-dimensional interface engineering via CoMoO4@Co3O4 immobilized on nickel foam for sulfamethoxazole degradation with enhanced electron transfer and high-efficiency peroxymonosulfate activation DOI
Hairui Li, Jikai Liu, Xiaoxue Zhang

и другие.

Applied Catalysis B Environment and Energy, Год журнала: 2025, Номер unknown, С. 125453 - 125453

Опубликована: Май 1, 2025

Язык: Английский

Site-designed dual-active-center catalysts for co-catalysis in advanced oxidation processes DOI Creative Commons
Wenxin Sun, Guoshuai Liu,

Hua Zou

и другие.

npj Materials Sustainability, Год журнала: 2025, Номер 3(1)

Опубликована: Янв. 7, 2025

Abstract Advanced Oxidation Processes (AOPs) are promising for treating persistent pollutants, yet challenges arise due to the step-wise oxidants activation process, which traditional single-active-center catalysts struggle facilitate effectively. Recently, dual-active-center have emerged as a solution by enabling synergistic reactions. This review covers advances in these catalysts, their co-catalytic mechanisms, and applications electro-Fenton, photocatalytic, peroxymonosulfate-, pollutant-as-electron-donor based Fenton-like processes, along with active site design considerations future challenges.

Язык: Английский

Процитировано

6

Modulation of sulfur vacancies in MoS2/Fe3P enhancing non-radical pathway of the Fenton-like reaction for complex real water DOI
Chao Zhong, Junfeng Wang, Yongjia Liu

и другие.

Applied Catalysis B Environment and Energy, Год журнала: 2025, Номер unknown, С. 125193 - 125193

Опубликована: Фев. 1, 2025

Язык: Английский

Процитировано

4

Application of metal-based catalysts for Fenton reaction: from homogeneous to heterogeneous, from nanocrystals to single atom DOI

Shangkun Pei,

Sheng Wang,

Yuxin Lu

и другие.

Nano Research, Год журнала: 2024, Номер unknown

Опубликована: Сен. 3, 2024

Язык: Английский

Процитировано

16

Microenvironment Engineering of Heterogeneous Catalysts for Liquid-Phase Environmental Catalysis DOI

Zhong‐Shuai Zhu,

Shuang Zhong, Cheng Cheng

и другие.

Chemical Reviews, Год журнала: 2024, Номер 124(20), С. 11348 - 11434

Опубликована: Окт. 9, 2024

Environmental catalysis has emerged as a scientific frontier in mitigating water pollution and advancing circular chemistry reaction microenvironment significantly influences the catalytic performance efficiency. This review delves into engineering within liquid-phase environmental catalysis, categorizing microenvironments four scales: atom/molecule-level modulation, nano/microscale-confined structures, interface surface regulation, external field effects. Each category is analyzed for its unique characteristics merits, emphasizing potential to enhance efficiency selectivity. Following this overview, we introduced recent advancements advanced material system design promote (e.g., purification, transformation value-added products, green synthesis), leveraging state-of-the-art technologies. These discussions showcase was applied different reactions fine-tune regimes improve from both thermodynamics kinetics perspectives. Lastly, discussed challenges future directions engineering. underscores of intelligent materials drive development more effective sustainable solutions decontamination.

Язык: Английский

Процитировано

14

Coordination Anions Dimensionality-Engineered Dual-Atom Catalysts for Enhanced Fenton-Like Reactions: 3D Coordination Induced Spin-State Transition DOI
Yanling Chen, Han Zhang, Yao Li

и другие.

ACS Nano, Год журнала: 2025, Номер unknown

Опубликована: Апрель 4, 2025

Dual-atom catalysts (DACs) have shown significant application potential in Fenton-like reactions. However, effectively modulating their electronic structure and fully understanding the mechanisms driving high catalytic activity remain challenging. Herein, we propose a coordination anions dimensionality engineering strategy to synthesize biomass-derived dual-atom FeCo-N4O1C catalysts, which Fe Co atoms are bridged by two-dimensional planar N three-dimensional (3D) axial O atom. Experimental data theoretical calculations reveal that 3D of induces spin state undergo transition from low an intermediate compared with single-atom Fe-N4O1C, resulting moderate adsorption desorption intermediates, thus reducing energy barriers for generating more singlet oxygen high-valent cobalt-oxo species during peroxymonosulfate activation. The electron transfer neighboring through can prevent poisoning active species. Benefiting synergistic effects multiple sites, catalyst-dose normalized reaction rate constant reaches 14.5 L min-1 g-1 under concentrations─an improvement 1 ∼ 2 orders magnitude over most reported catalysts. practical applicability is demonstrated nearly 100% pollutant removal 7 days continuous operation membrane filtration system. This study provides deep insights into relationship between performance spin-state regulation DACs, introduces promising approach large-scale synthesis low-cost, highly efficient DACs

Язык: Английский

Процитировано

2

Spatial Axial Oxygen Coordination of CoSA-N2O1/MXene Single-Atom Catalyst with Electron-Depleted Active Site for Selective 1O2 Generation DOI
Yuxuan Bai, Ganbing Zhang,

Mingwang Liu

и другие.

Applied Catalysis B Environment and Energy, Год журнала: 2025, Номер unknown, С. 125378 - 125378

Опубликована: Апрель 1, 2025

Язык: Английский

Процитировано

2

Fe-doped g-C3N4 activated peroxymonosulfate to effectively remove tetracycline in water DOI
Lingfang Tang,

Daixi Zhou,

Qinqin Chen

и другие.

Surfaces and Interfaces, Год журнала: 2025, Номер unknown, С. 106269 - 106269

Опубликована: Март 1, 2025

Язык: Английский

Процитировано

1

Oriented Generation of 1O2 from Peroxymonosulfate via Co3O4 Facet Engineering DOI Creative Commons
Huan Wang, Dashuai Wang, Chen Sun

и другие.

Applied Catalysis B Environment and Energy, Год журнала: 2024, Номер unknown, С. 124854 - 124854

Опубликована: Ноя. 1, 2024

Язык: Английский

Процитировано

8

Microenvironment Modulation of Carbon-Based Single-Atom Catalysts for Advanced Oxidation Processes DOI Creative Commons

Zhong‐Shuai Zhu,

Pengtang Wang, Ya Liu

и другие.

Environmental Functional Materials, Год журнала: 2025, Номер unknown

Опубликована: Янв. 1, 2025

Язык: Английский

Процитировано

1

Carbonized nitrogen-containing conjugated microporous polymers: Versatile platforms for high-performance carbon catalytic membranes and their angstrom-confined activation mechanism on peroxymonosulfate DOI

Jiaqiang Li,

Wei Lyu,

Xuejin Mi

и другие.

Journal of Hazardous Materials, Год журнала: 2025, Номер 491, С. 137862 - 137862

Опубликована: Март 14, 2025

Язык: Английский

Процитировано

1