Role of “post-coordination interaction” boosted performance of rare-earth based MOFs derived catalyst for hydrogenation-alkylation cascade reaction

Molecular Catalysis, Год журнала: 2024, Номер 572, С. 114735 - 114735

Опубликована: Ноя. 29, 2024

Язык: Английский

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Peripheral effect promotes single-atom catalysis

Coordination Chemistry Reviews, Год журнала: 2025, Номер 536, С. 216649 - 216649

Опубликована: Апрель 6, 2025

Язык: Английский

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Revolutionizing heterogeneous catalysis: Dual-atom catalysts as the next frontier in green chemistry

Fuel, Год журнала: 2025, Номер 396, С. 135262 - 135262

Опубликована: Апрель 8, 2025

Язык: Английский

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Carbon nanotube-supported Co-N-C with enriched mesopores for hydrogenation of nitro compounds

Journal of Catalysis, Год журнала: 2025, Номер unknown, С. 116152 - 116152

Опубликована: Апрель 1, 2025

Язык: Английский

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Synergistic adsorption-catalysis system based on the advanced oxidation technology of single-atom MOFs: Selective degradation and contribution to different ionization potential pollutants

Chemical Engineering Journal, Год журнала: 2025, Номер unknown, С. 163031 - 163031

Опубликована: Апрель 1, 2025

Язык: Английский

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Cobalt-Catalyzed Diester Formation with CO at Atmospheric Pressure via Three-Component Reactions

The Journal of Organic Chemistry, Год журнала: 2025, Номер unknown

Опубликована: Апрель 28, 2025

We propose a cobalt-catalyzed three-component reaction conducted under mild conditions. Following the carbonyl insertion at atmospheric pressure, proceeds via nucleophilic attack by alcohols to form diesters. Notably, scope of reagents can be extended include range anilines. Furthermore, products this transformation serve as crucial synthetic building blocks for diverse organic synthesis processes, with subsequent derivatizations yielding promising results.

Язык: Английский

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Robust “MOFs Plus MOFs” Hybrid Catalyst for Alcoholysis of Epoxides Reaction Integrated by Coordination

Applied Organometallic Chemistry, Год журнала: 2025, Номер 39(6)

Опубликована: Май 12, 2025

ABSTRACT In this study, a type of highly distinctive functional cerium‐based metal–organic frameworks (MOFs) materials was successfully prepared. The prominent feature material lies in the fact that it contains considerable number uncoordinated imine groups, and labeled as Ce‐H 2 salen. Meanwhile, by taking advantage unique complexation reaction between iron element hexamethylenetetramine, two MOFs were combined to form named Fe‐ hmta . species uniformly systematically dispersed within molecular structure This arrangement not only optimized material's microscopic but also established foundation for enhancing its subsequent performance. Subsequently, above with different functions innovatively integrated organically, finally, @Ce‐H salen composite obtained. A variety characterization techniques employed, including XPS, FT‐IR, UV–Vis, HADDF‐STEM, investigate interaction mechanisms analyze distribution on MOFs. Importantly, as‐synthesized catalyst demonstrates exceptional performance alcoholysis epoxides. indicates has potential be promising other epoxides well.

Язык: Английский

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Atomically dispersed catalysts: for the efficient and stable industrial electrosynthesis of H₂O₂

Energy & Environmental Science, Год журнала: 2025, Номер unknown

Опубликована: Янв. 1, 2025

This review focuses on the sustainable synthesis of hydrogen peroxide (H 2 O ) via 2e − ORR. It emphasizes ADC design strategies. bridges fundamental research and industrial practices to drive advancement green chemical synthesis.

Язык: Английский

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Modulating tin phthalocyanine single-atom catalyst anchored onto N and S co-doped graphene-based framework for selective electrochemical reduction of CO2 to formic acid

International Journal of Hydrogen Energy, Год журнала: 2024, Номер 99, С. 241 - 255

Опубликована: Дек. 17, 2024

Язык: Английский

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