Catenation Control in Stable Zr‐MOFs for Fine‐Tuning LNG‐ANG‐Related Methane Storage DOI
Si Ma, Le Shi,

Yuanlong Zhong

и другие.

Small, Год журнала: 2024, Номер unknown

Опубликована: Ноя. 22, 2024

Abstract The liquefied natural gas and adsorbed (LNG‐ANG) coupling systems are emerging as an attractive solution to solve boil‐off gases generated by LNG tanks. Metal‐organic frameworks (MOFs) promising candidates for methane storage delivery owing their high porosity, large specific surface area, tunable pore structures. However, systematically tuning LNG‐ANG‐related adsorption performance of MOFs has yet be explored. In this context, interpenetrated zirconium‐based (3,8)‐connected the ‐MOF, Zr‐TTB‐1, with limited porosity is synthesized. further delicate modulation reaction conditions allows assembly a non‐interpenetrated counterpart, Zr‐TTB‐2, significantly improved porosity. Such molecular‐level catenation control results in substantial increase low‐temperature related LNG‐ANG. volumetric working capacity Zr‐TTB‐2 up 255 cm 3 (standard temperature pressure, STP) −3 under LNG‐ANG condition (159 K, 6 bar, 298 5 bar), outperforms more than twice that counterpart—Zr‐TTB‐1 (115 (STP) ). To end, investigation provides efficacious example regulating through structural designed porous frameworks.

Язык: Английский

Enhanced removal of PFAS in water using activated ZIF-8 carbons: High adsorption efficiency, repeatable regenerability and reusability DOI
Ilango Aswin Kumar, Roopesh Mekkat,

Velu Jeyalakshmi

и другие.

Chemical Engineering Journal, Год журнала: 2025, Номер unknown, С. 160192 - 160192

Опубликована: Фев. 1, 2025

Язык: Английский

Процитировано

0
Pyridine-N-Anchored Ag Strategy Facilitated Br– Adsorption via Ultrahigh Exposure and Coordination Unsaturation of Ag DOI

Yini Chen,

Zirui Ma,

Lei Song

и другие.

Nano Letters, Год журнала: 2025, Номер unknown

Опубликована: Март 26, 2025

Traditional adsorbents using silver nanoparticles demonstrated exceptional adsorption capacities for Br–. However, the majority of sites in are situated on their surfaces, limiting interaction internal atoms with Therefore, we synthesized Ag/UiO-bpy MOF by utilizing two pyridine nitrogen ligand to anchor silver. So each atom was effectively exposed. Besides, owing coordinatively unsaturated state atoms, they exhibited a stronger affinity As result, an Br– capacity 362.6 mg/g. Notably, respect 2083.9 mg/gAg, which surpasses all previously reported values literature. Furthermore, rapid kinetics and selectivity experiments. This work not only fabricated adsorbent high but also proposed new innovative strategy subsequent preparation adsorbents.

Язык: Английский

Процитировано

0
Tetrathienylethene-based porous framework composites for boosting photocatalytic antibacterial activity DOI Creative Commons
Si Ma, Yintung Lam, Le Shi

и другие.

Proceedings of the National Academy of Sciences, Год журнала: 2025, Номер 122(15)

Опубликована: Апрель 7, 2025

In order to reduce the risk of high-threat pathogens, a photocatalytic antibacterial method with reputation for high efficiency and sustainability has attracted widespread attention. Recently, metal-organic frameworks (MOFs) have emerged as desirable platforms applications by virtue their structural diversity functional adjustability. Herein, we report that synthesized stable photosensitive zirconium-based MOF (Zr-MOF) photoactive tetrathienylethene-based organic linker, Zr-TSS-1. Compared all-carbocyclic Zr-MOF counterparts, Zr-TSS-1 shows substantial improvement in visible-light harvesting free-carrier generation, enabling it be promising candidate applications. validate advantages this framework an protective material, composite was fabricated incorporating robust onto sustainably accessible bacterial cellulose (BC) using situ growth method. This exhibits near-complete lethality toward typical Gram-negative Escherichia coli Gram-positive Staphylococcus aureus within 1 h under mild irradiation preserves outstanding capability after five cycles reutilization. addition, biocompatibility is confirmed low cytotoxicity human skin fibroblast, suggesting its potential biomedical healthcare research demonstrates efficacious integration purposely designed porous sustainable substrate synergistic functionality, paving practical way development next-generation high-efficiency antimicrobial technology.

Язык: Английский

Процитировано

0
A Self-Respiring Cathode Weaken the Competing Reactions of Electro-Fenton Synergistic Pms-Activated Systems for Activation of Dual Oxidants: Coupling System Powers Centralized Active Reaction Zone of Pfoa DOI
Fangke Yu, Yunlin Li, Jing Jiang

и другие.

Опубликована: Янв. 1, 2025

Язык: Английский

Процитировано

0
In-situ growth of π conjugated-driven indium-organic frameworks for broad-spectrum and high-efficiency extraction DOI

Yixin Kuang,

Suxin Zhou,

Xiaoying Feng

и другие.

Chemical Engineering Journal, Год журнала: 2025, Номер unknown, С. 162906 - 162906

Опубликована: Апрель 1, 2025

Язык: Английский

Процитировано

0
Enhanced Selective Removal of PFAS at Trace Level Using Quaternized Cellulose-Functionalized Polymer Resin: Performance and Mechanism DOI

Jinjing Huang,

Kaixing Fu,

Zhuoya Fang

и другие.

Water Research, Год журнала: 2024, Номер 272, С. 122937 - 122937

Опубликована: Дек. 9, 2024

Язык: Английский

Процитировано

3
Enhanced PFOA degradation via non-radical PMS pathway through synergistic Fe single-atoms and Fe nanoparticles in Fe–N–C catalysts DOI
Changyu Li, Kang Lu, Suo Wang

и другие.

Chemical Engineering Journal, Год журнала: 2025, Номер unknown, С. 162424 - 162424

Опубликована: Апрель 1, 2025

Язык: Английский

Процитировано

0
Removal of Trace Benzene from Cyclohexane Using a MOF Molecular Sieve DOI

Rui-Chao Zhao,

Lin‐Hua Xie, Xiaomin Liu

и другие.

Journal of the American Chemical Society, Год журнала: 2024, Номер unknown

Опубликована: Дек. 5, 2024

Cyclohexane (Cy), commonly produced by the catalytic hydrogenation of benzene (Bz), is used in large quantities as a solvent or feedstock for nylon polymers. Removing trace unreacted Bz from Cy product technically difficult due to their similar molecular structures and physical properties. Herein, we report that metal-organic framework (MOF) adsorbent shows sieving effect with record-high Bz/Cy adsorption selectivities (216, 723, 1027) liquid mixtures (v/v = 1:1, 1:10, 1:20), traps molecules effectively even at low partial pressure vapor phase (e.g., 2.49 mmol/g 8.2 Pa) content liquid-phase 128 mg/g 20 ppm). Over 99% removal (1000 ppm) could be achieved one simple stripping step room temperature using this sorbent, producing >99.999% purity. Single-crystal structure analyses guest-free Bz-loaded phases MOF disclosed narrow slit-like pore aperture strong uniting multiple weak host-guest guest-guest interactions are co-origin its distinct property Cy.

Язык: Английский

Процитировано

2
Enhanced photocatalytic degradation of perfluorooctanoic acid using BiOCl@PMoV-X heterojunction photocatalyst coupled with persulfate activation DOI
Jiawei Wu,

Cuiqing Si,

Linyun Zhong

и другие.

Journal of Water Process Engineering, Год журнала: 2024, Номер 69, С. 106791 - 106791

Опубликована: Дек. 30, 2024

Язык: Английский

Процитировано

1
Catenation Control in Stable Zr‐MOFs for Fine‐Tuning LNG‐ANG‐Related Methane Storage DOI
Si Ma, Le Shi,

Yuanlong Zhong

и другие.

Small, Год журнала: 2024, Номер unknown

Опубликована: Ноя. 22, 2024

Abstract The liquefied natural gas and adsorbed (LNG‐ANG) coupling systems are emerging as an attractive solution to solve boil‐off gases generated by LNG tanks. Metal‐organic frameworks (MOFs) promising candidates for methane storage delivery owing their high porosity, large specific surface area, tunable pore structures. However, systematically tuning LNG‐ANG‐related adsorption performance of MOFs has yet be explored. In this context, interpenetrated zirconium‐based (3,8)‐connected the ‐MOF, Zr‐TTB‐1, with limited porosity is synthesized. further delicate modulation reaction conditions allows assembly a non‐interpenetrated counterpart, Zr‐TTB‐2, significantly improved porosity. Such molecular‐level catenation control results in substantial increase low‐temperature related LNG‐ANG. volumetric working capacity Zr‐TTB‐2 up 255 cm 3 (standard temperature pressure, STP) −3 under LNG‐ANG condition (159 K, 6 bar, 298 5 bar), outperforms more than twice that counterpart—Zr‐TTB‐1 (115 (STP) ). To end, investigation provides efficacious example regulating through structural designed porous frameworks.

Язык: Английский

Процитировано

0