Covalent organic framework nanomaterials: Syntheses, architectures, and applications
Advances in Colloid and Interface Science,
Год журнала:
2025,
Номер
339, С. 103427 - 103427
Опубликована: Фев. 6, 2025
Язык: Английский
Solubility Challenges and Strategies for Organic Sodium‐Ion Batteries: Status and Perspectives
Small,
Год журнала:
2025,
Номер
unknown
Опубликована: Фев. 24, 2025
Organic
sodium-ion
batteries
(OSIBs)
possessing
excellent
characteristics
of
low
price,
abundant
sources,
and
eco-compatibility
have
gained
numerous
attentions
in
the
recent
decade.
However,
solubility
is
one
main
severe
limitations
application
OSIBs,
especially
for
small
organic
molecules.
The
dissolution
molecules
into
electrolytes
can
cause
loss
active
materials,
pulverization
electrodes,
even
short
circuits
batteries,
as
materials
may
shuttle
through
separators,
thus
leading
to
poor
cycling
stability
batteries.
Thus,
there
an
urgent
need
develop
insoluble
OSIBs.
advanced
development
OSIBs
over
past
decades
overviewed,
primary
challenges
faced
by
long-cycling
terms
are
systematically
analyzed.
Focusing
on
three
core
components
battery
system
electrolytes,
targeted
optimization
strategies
proposed
mitigate
issues
enhance
performance.
In
addition,
prospects
toward
long-cycle
practical
explored.
Язык: Английский
Phenazinyl polymer@rGO composite cathode materials with fast charging and wide temperature adaptability for sodium dual-ion batteries
Electrochimica Acta,
Год журнала:
2025,
Номер
unknown, С. 146161 - 146161
Опубликована: Апрель 1, 2025
Язык: Английский
Geomimetic Thermosynthesis in Heterogeneous Structural Complexes of In Situ Growing Imine-Based COF on MXene for Enhanced Sodium Ion Storage
Xi‐Ping Luo,
M. D. Steven,
Zili Feng
и другие.
ACS Omega,
Год журнала:
2025,
Номер
unknown
Опубликована: Апрель 14, 2025
Covalent
organic
frameworks
(COFs)
have
gained
significant
attention
as
next-generation
electrode
materials
for
energy
storage,
owing
to
their
chemical
versatility,
ecofriendliness,
and
cost-effectiveness.
However,
practical
application
in
storage
systems
is
hindered
by
challenges
such
insufficient
exposure
of
functional
groups
sodium
poor
ion/electron
transport
kinetics.
In
this
work,
we
developed
an
organic-inorganic
heterojunction
structure
situ
growth
imine-based
COF
on
the
surface
MXene,
which
was
employed
anode
material
sodium-ion
batteries.
This
design
enhances
ion
electron
transport,
while
porous
layer
maximizes
active
sites.
FT-IR
Raman
spectroscopy
analyses
reveal
that
C=N
C=C
COF@D-Ti3C2T
x
enable
reversible
storage.
Furthermore,
flexible
hydrogen
bonds
between
MXene
layers
effectively
mitigate
volume
expansion
during
cycling,
improving
structural
stability
long-term
cycling
performance.
As
a
result,
composite
delivers
remarkable
capacity
401.6
mA
h
g-1
after
300
cycles
at
0.1
C.
work
not
only
introduces
novel
synthesis
strategy
COFs
but
also
explores
sodium-active
reaction
units
designs,
offering
new
insights
advancing
rechargeable
battery
technologies.
Язык: Английский
Trithiocyanuric acid trilithium salt: A low-cost, high-energy, reduction-state organic cathode material based on disulfide bond
Chemical Engineering Journal,
Год журнала:
2025,
Номер
unknown, С. 162734 - 162734
Опубликована: Апрель 1, 2025
Язык: Английский
Carbonyl based electrode materials for rechargeable sodium (Na)-ion batteries (SIBs): a review
Materials Today Chemistry,
Год журнала:
2025,
Номер
46, С. 102711 - 102711
Опубликована: Апрель 19, 2025
Язык: Английский
Covalent organic framework-based cathodes for beyond lithium-ion batteries
Communications Materials,
Год журнала:
2025,
Номер
6(1)
Опубликована: Апрель 21, 2025
Язык: Английский
Umpolung of Covalent Organic Framework Towards High-Performance Cathodic Sodium Ions Storage
Chemical Science,
Год журнала:
2025,
Номер
unknown
Опубликована: Янв. 1, 2025
The
rational
design
of
electrode
materials
to
modify
their
intrinsic
electronic
states
effectively
enhances
the
performance
rechargeable
batteries.
Herein,
an
umpolung
strategy
is
implemented
in
preparing
a
polyimide-linked
COF...
Язык: Английский