Enhancing Methanol/Water Activation for Photothermal Hydrogen Production: Modulation of Cu-pyridine Sites in UiO-67 Metal-Organic Frameworks DOI
Shuting Liu,

Ziyu Zengcai,

Jingyao Yang

и другие.

Applied Catalysis B Environment and Energy, Год журнала: 2025, Номер unknown, С. 125376 - 125376

Опубликована: Апрель 1, 2025

Язык: Английский

High-Intensity Interfacial Electric Fields between Co-catalysts and Semiconductor: A Determinant Factor in Enhancing Photocatalytic Hydrogen Production DOI

Guanyu Wu,

Xue Gao, Peipei Sun

и другие.

Applied Catalysis B Environment and Energy, Год журнала: 2025, Номер unknown, С. 125265 - 125265

Опубликована: Март 1, 2025

Язык: Английский

Процитировано

1
Advanced TiO2-Based Photocatalytic Systems for Water Splitting: Comprehensive Review from Fundamentals to Manufacturing DOI Creative Commons

Tarek Ahasan,

E.M.N. Thiloka Edirisooriya, Punhasa S. Senanayake

и другие.

Molecules, Год журнала: 2025, Номер 30(5), С. 1127 - 1127

Опубликована: Фев. 28, 2025

The global imperative for clean energy solutions has positioned photocatalytic water splitting as a promising pathway sustainable hydrogen production. This review comprehensively analyzes recent advances in TiO2-based systems, focusing on materials engineering, source effects, and scale-up strategies. We recognize the advancements nanoscale architectural design, engineered heterojunction of catalysts, cocatalyst integration, which have significantly enhanced efficiency. Particular emphasis is placed crucial role chemistry system performance, analyzing how different sources-from wastewater to seawater-impact evolution rates stability. Additionally, addresses key challenges scaling up these including optimization reactor light distribution, mass transfer. Recent developments artificial intelligence-driven discovery process are discussed, along with emerging opportunities bio-hybrid systems CO2 reduction coupling. Through critical analysis, we identify fundamental propose strategic research directions advancing technology toward practical implementation. work will provide comprehensive framework exploring advanced composite developing efficient scalable multifunctional simultaneous

Язык: Английский

Процитировано

0
Silver-modified Bi2WO6 nanosheets for efficient hydrogen production via piezo-photo-catalysis DOI

Lujie Ruan,

Honglin Zhou, Xiangyu Li

и другие.

Surfaces and Interfaces, Год журнала: 2025, Номер unknown, С. 106263 - 106263

Опубликована: Март 1, 2025

Язык: Английский

Процитировано

0
Engineering copper single sites in conjugated microporous polymers to enhance selective photocatalytic CO2 methanation DOI

Meng Fanyu,

R. Zhang, Haobo Xu

и другие.

Chemical Engineering Journal, Год журнала: 2025, Номер unknown, С. 162017 - 162017

Опубликована: Март 1, 2025

Язык: Английский

Процитировано

0
Simultaneously Tailoring Hydrostability and Photoelectroactivity in Heterocluster Metal–Organic Frameworks for Efficient Photocatalytic Hydrogen Production DOI
Yeqian Cheng, Jianqiang Zhao, Xiongfeng Ma

и другие.

Advanced Materials, Год журнала: 2025, Номер unknown

Опубликована: Апрель 3, 2025

The simultaneous enhancement of structural stability and photoelectroactivity in metal-organic frameworks (MOFs) remains a critical challenge for sustainable photocatalytic hydrogen (H2) production. Herein, an atomically-precise heterocluster assembly approach is presented to construct two isostructural 3D MOFs, CuSL-CuX (X = Cl, Br), featuring cds net. CuSL-CuXs integrate hexanuclear copper-sulfur {Cu6S6} cluster dinuclear copper-halogen {Cu2X2} cluster, which not only impart exceptional across broad pH range (1-14) but also enable wide visible-light absorption, tailored redox potentials, efficient charge-carrier dynamics. Notably, halogen substitution markedly boosts activity: CuSL-CuBr achieves H2 evolution rate 50.28 mmol g-1 h-1 without noble metals, doubling that CuSL-CuCl (26.99 h-1) surpassing most reported MOF-based photocatalysts. Both experimental theoretical investigations indicate bromine optimizes electronic structure, refines orbital distribution, accelerates charge separation, ultimately leading promoted efficiency. This research provides insights into the structure-property interplay MOFs establishes paradigm designing robust, high-performance photocatalysts through precise engineering.

Язык: Английский

Процитировано

0
Cu Metal-Modified Nb2O5 Microspheres Boost Photoreduction of CO2 to CH4 via Enhanced Adsorption of C1 Intermediates DOI

Wenjing Ji,

Xie Hongtao,

Bangwei Deng

и другие.

Industrial & Engineering Chemistry Research, Год журнала: 2025, Номер unknown

Опубликована: Апрель 11, 2025

Язык: Английский

Процитировано

0
Enhancing Methanol/Water Activation for Photothermal Hydrogen Production: Modulation of Cu-pyridine Sites in UiO-67 Metal-Organic Frameworks DOI
Shuting Liu,

Ziyu Zengcai,

Jingyao Yang

и другие.

Applied Catalysis B Environment and Energy, Год журнала: 2025, Номер unknown, С. 125376 - 125376

Опубликована: Апрель 1, 2025

Язык: Английский

Процитировано

0