Chemical Communications,
Год журнала:
2025,
Номер
unknown
Опубликована: Янв. 1, 2025
In
this
review,
we
outline
the
interface-assisted
methods,
growth
mechanisms
and
applications
of
C-MOF
films,
propose
future
development
possible
challenges
preparation
membrane/films.
Nanoscale Advances,
Год журнала:
2025,
Номер
unknown
Опубликована: Янв. 1, 2025
The
fabrication
and
electrochemical
characterization
of
multifunctional
energy
storage
devices
using
biomass-derived
activated
carbon
sourced
from
indigenous
European
deciduous
trees.
Inorganic Chemistry Frontiers,
Год журнала:
2025,
Номер
unknown
Опубликована: Янв. 1, 2025
MOF-derived
carbons
are
a
class
of
porous
material
that
combine
the
stability
carbon
with
functionality
and
versatility
MOFs.
This
review
describes
systematic
design,
characterization,
application
these
materials.
Dalton Transactions,
Год журнала:
2025,
Номер
unknown
Опубликована: Янв. 1, 2025
A
novel
carboxyl
functionalized
Co-MOF
(–COOH)
which
can
be
used
to
prepare
Co-MOF-
g
-CTS
by
a
one-pot
method
with
CTS
was
designed.
(Co-MOF-
-CTS)-900
derived
from
exhibited
the
best
4-NP
catalytic
reduction
activity.
Advanced Functional Materials,
Год журнала:
2025,
Номер
unknown
Опубликована: Апрель 28, 2025
Abstract
Efficient
bifunctional
oxygen
catalysts
are
essential
to
construct
high‐performance
rechargeable
zinc‐air
batteries
(RZABs).
The
excessive
hydrogen
bond
energy
and
the
slow
kinetics
of
H─O
reconstruction
result
in
low
efficiency.
Herein,
an
atomic
confinement
regulation
strategy
is
proposed
prepare
a
novel
catalyst
CoFe
DA
/HC
3
N
4
by
combining
DACs
(dual
catalysts)
confined
on
hollow
carbon
nitride
with
overboiling
point
hydrogen‐bonding
dissociation.
This
new
combination
can
rationally
regulate
reaction
pathways
water
molecule
dissociation
achieve
optimized
performance.
exhibits
excellent
ORR
OER
catalytic
activity
half‐wave
potential
0.90
V
overpotential
251
mV
at
10
mA
cm
−2
,
fully
demonstrating
stable
synergistic
effect
dual
coordinated
Co─N
2
Fe─N
sites.
Furthermore,
assembled
RZAB
equipped
achieves
super‐high‐energy
efficiency
(EE
=
88.1%)
superb
cycling
stability
(a
decay
rate
0.0203%@20
)
120
°C,
revealing
that
over‐boiling
environment
significantly
enhances
molecules
during
charge
discharge
processes.
work
provides
design
direction
for
rational
control
isolated
widen
operating
temperature
window
secondary
batteries.