Energetic Metal Imidazolate-Dicyanamide Frameworks for Hypergolic Solid Fuels: Ignition Property Tuning through Construction of Diverse Structural Linking Modes
Crystal Growth & Design,
Год журнала:
2025,
Номер
unknown
Опубликована: Янв. 30, 2025
Язык: Английский
Host–Guest Synergy of Metal–Organic Frameworks for Enhanced Near-Infrared Ultrafast Laser Responsiveness
ACS Central Science,
Год журнала:
2025,
Номер
unknown
Опубликована: Март 18, 2025
Host–guest
metal–organic
frameworks
(MOFs)
offer
significant
potential
and
value
in
regulating
optimizing
novel
material
properties
functionalities,
owing
to
the
synergistic
effects
between
host
framework
guest
units.
This
study
reported
two
silver-based
host–guest
MOFs,
[Ag(ATRZ)(BrO3)]n
(CMOF-1)
[Ag(ATRZ)1.5(ClO4)]n
(CMOF-2),
as
promising
candidates
for
laser-responsive
materials.
These
materials
feature
1D
3D
structures,
respectively,
comprising
Ag-ATRZ
cationic
MOF
integrated
with
distinct
oxidizing
anionic
guests,
BrO3–
ClO4–.
CMOF-1
CMOF-2
are
synthesized
through
straightforward,
environmentally
benign
methods,
enabling
rapid
fabrication.
The
exceptional
near-infrared
(NIR)
laser
responsiveness
of
was
achieved
modulation
MOFs
(CMOFs)
architectures
interactions
components.
Moreover,
both
exhibit
ultrafast
deflagration-to-detonation
transition
(DDT)
capabilities,
alongside
excellent
thermal
stability.
work
expands
application
scope
provides
an
effective
strategy
developing
high-performance
Язык: Английский
Comparative study of two copper perchlorate hydrazide complexes: impact of coordination chemistry on laser sensitivity and energetic properties
CrystEngComm,
Год журнала:
2025,
Номер
unknown
Опубликована: Янв. 1, 2025
By
modulating
the
coordination
chemistry
through
varying
reaction
conditions,
two
novel
energetic
complex
compounds,
ECCs-1
and
ECCs-2,
exhibited
different
structures,
thermal
stabilities,
mechanical
sensitivities,
laser
ignition
performances.
Язык: Английский