Photocatalytic Hydrogen Evolution Driven by Advanced Metal Sulfides from Sustainable Multilevel Biomass and Waste Plastics DOI

Lin Ban,

Yan Zhang, Daofeng Sun

и другие.

Advanced Functional Materials, Год журнала: 2025, Номер unknown

Опубликована: Июнь 1, 2025

Abstract Promoted by the goal of global energy transformation and carbon neutrality, green hydrogen production technology driven solar has become a key strategic direction to break through bottleneck environment. Traditional photocatalytic water decomposition method for is limited low kinetic efficiency oxidation half‐reaction dependence on high‐cost harmful sacrifice agents, therefore it urgent seek potential sustainable alternative. In this review work, relevant research progress different metal sulfide photocatalysts in evolution (PHE) multilevel biomass resources waste plastics reviewed. First, structure modification strategy sulfides are discussed, PHE mechanism multi‐scale synergistic effect analyzed. Second, effective strategies process summarized. addition, vital industrialization also evaluated from aspects environmental impact economic feasibility. Finally, development material‐process‐artificial intelligence integration innovation prospected, providing theoretical guidance technical path laboratory large‐scale application.

Язык: Английский

Chemical Depolymerization of Polyethylene Terephthalate and Its Blends: Enhanced Strategies for Efficient Circularity DOI
Shun Zhang, Xuan Zhao, Xuehui Liu

и другие.

Progress in Polymer Science, Год журнала: 2025, Номер unknown, С. 101958 - 101958

Опубликована: Апрель 1, 2025

Язык: Английский

Процитировано

0

Yeast Inherited Phosphide/Bio‐Carbon for Controllable Polyethylene Terephthalate Upcycling DOI
Tian Xia,

Zhengjie Chen,

Chung‐Li Dong

и другие.

Advanced Functional Materials, Год журнала: 2025, Номер unknown

Опубликована: Апрель 30, 2025

Abstract Electrochemical reforming of polyethylene terephthalate (PET) coupled with hydrogen production is great significance to realize the sustainable development clean energy technologies. Nevertheless, precisely controlling reaction pathways and selectively converting key intermediates during glycol oxidation (EGOR) pose considerable challenges. Herein, theoretical calculations experiments reveal that intermediate (*CHO‐CHO) role P in promoting reconstruction transition metal phosphides surface EGOR process. Consequently, bio‐template strategy introduced design bimetal phosphide@bio‐carbon pre‐catalyst toward efficient evolution (HER). This enables controlled *CHO‐CHO formation transformation through enhanced adsorption OH* *CHO‐CHO, leading a highly selective EGOR. The C1 product formic acid exhibits superior Faradaic efficiency (99.1%) at 1.35 V. In addition, this constructed catalyst only requires 1.76 V@500 mA cm −2 can stably perform for more than 240 h 500 HER PET hydrolysate. work proposes novel construct upcycling HER, which crucial multidisciplinary integration biology conversion

Язык: Английский

Процитировано

0

Photocatalytic Hydrogen Evolution Driven by Advanced Metal Sulfides from Sustainable Multilevel Biomass and Waste Plastics DOI

Lin Ban,

Yan Zhang, Daofeng Sun

и другие.

Advanced Functional Materials, Год журнала: 2025, Номер unknown

Опубликована: Июнь 1, 2025

Abstract Promoted by the goal of global energy transformation and carbon neutrality, green hydrogen production technology driven solar has become a key strategic direction to break through bottleneck environment. Traditional photocatalytic water decomposition method for is limited low kinetic efficiency oxidation half‐reaction dependence on high‐cost harmful sacrifice agents, therefore it urgent seek potential sustainable alternative. In this review work, relevant research progress different metal sulfide photocatalysts in evolution (PHE) multilevel biomass resources waste plastics reviewed. First, structure modification strategy sulfides are discussed, PHE mechanism multi‐scale synergistic effect analyzed. Second, effective strategies process summarized. addition, vital industrialization also evaluated from aspects environmental impact economic feasibility. Finally, development material‐process‐artificial intelligence integration innovation prospected, providing theoretical guidance technical path laboratory large‐scale application.

Язык: Английский

Процитировано

0