ACS Applied Materials & Interfaces,
Год журнала:
2025,
Номер
unknown
Опубликована: Янв. 30, 2025
Planar
1D
photonic
crystals
(1DPhCs),
owing
to
their
bandgaps
(PBGs)
formed
by
unique
structural
interference,
are
widely
utilized
in
light
protection
applications.
Multifunctional
coatings
that
integrate
various
management
functions
highly
desired.
In
this
study,
we
present
the
fabrication
of
dual-PBG
1DPhCs
with
high
reflectance
both
blue
and
near-infrared
(NIR)
regions.
The
were
constructed
through
alternating
stacking
hollow
SiO2
(HS)
nanoparticles
hybridized
poly(vinyl
alcohol)
(PVA),
referred
as
PHS,
TiO2
layers.
1DPhC
7
bilayers
demonstrated
remarkable
98.2%
93.4%
NIR
spectra,
respectively,
shielding
efficiencies
93.9%
85.6%.
Compared
bare
PC,
temperature
was
observed
be
10.6
°C
lower,
achieving
a
thermal
insulation
efficiency
44.8%
900
nm
range.
Additionally,
spectral
fitting
using
transfer
matrix
method
(TMM)
optimization
process
parameters,
including
PHS
concentration
spin-coating
speed,
enabled
tunable
optical
thickness
ratios.
fabricated
films
smooth
surface
morphology
flat
uniform
interfaces,
well
excellent
environmental
stability.
These
features
make
promising
for
applications
management.
This
study
provides
novel
approach
development
enhanced
protective
capabilities.
Journal of the American Chemical Society,
Год журнала:
2021,
Номер
144(1), С. 5 - 22
Опубликована: Дек. 22, 2021
The
production
of
elemental
sulfur
from
petroleum
refining
has
created
a
technological
opportunity
to
increase
the
valorization
by
synthesis
high-performance
sulfur-based
plastics
with
improved
optical,
electrochemical,
and
mechanical
properties
aimed
at
applications
in
thermal
imaging,
energy
storage,
self-healable
materials,
separation
science.
In
this
Perspective,
we
discuss
efforts
past
decade
that
have
revived
area
organosulfur
polymer
chemistry
afford
new
class
high-sulfur-content
polymers
prepared
polymerization
liquid
unsaturated
monomers,
termed
inverse
vulcanization.
Chemical Reviews,
Год журнала:
2019,
Номер
119(24), С. 12279 - 12336
Опубликована: Дек. 3, 2019
The
extraordinary
properties
of
biological
materials
often
result
from
their
sophisticated
hierarchical
structures.
Through
multilevel
and
cross-scale
structural
designs,
offset
the
weakness
individual
building
blocks
enhance
performance
at
multiple
length
scales
to
match
multifunctional
needs
organisms.
One
essential
merit
structure
is
that
it
can
optimize
interfacial
features
"building
blocks"
different
scales,
molecular
level
macroscale.
Understanding
roles
material
interfaces
(BMIs)
on
determination
functions
has
become
a
growing
interdisciplinary
research
area
in
recent
years.
A
pivotal
aim
these
studies
use
BMIs
as
inspiration
for
developing
bioinspired
biomimetic
devices
with
advanced
structures
functions.
Given
considerations,
this
review
aims
comprehensively
discuss
structure-property-function
relationships
nature.
We
particularly
focus
discussion
inspired
mechanical
optical
perspectives
because
two
directions
are
most
well-investigated
closely
related.
challenges
design
fabrication
BMI-inspired
also
discussed.
This
expected
garner
interest
communities
well
environmental,
nanotechnology,
food
processing,
engineering
fields.
Light Science & Applications,
Год журнала:
2022,
Номер
11(1)
Опубликована: Авг. 5, 2022
Abstract
Animals
can
modify
their
body
shape
and/or
color
for
protection,
camouflage
and
communication.
This
adaptability
has
inspired
fabrication
of
actuators
with
structural
changes
to
endow
soft
robots
additional
functionalities.
Using
liquid
crystal-based
materials
is
a
promising
approach.
In
this
review,
we
discuss
the
current
state
potential
applications
these
in
robotic
devices.
Advanced Materials,
Год журнала:
2023,
Номер
35(47)
Опубликована: Март 16, 2023
With
rapid
advances
in
optoelectronics,
electrochromic
materials
and
devices
have
received
tremendous
attentions
from
both
industry
academia
for
their
strong
potentials
wearable
portable
electronics,
displays/billboards,
adaptive
camouflage,
tunable
optics,
intelligent
devices,
etc.
However,
conventional
typically
present
some
serious
limitations
such
as
undesirable
dull
colors,
long
switching
time,
hindering
deeper
development.
Optical
resonators
been
proven
to
be
the
most
powerful
platform
providing
optical
confinement
controllable
lightmatter
interactions.
They
generate
locally
enhanced
electromagnetic
near-fields
that
can
convert
small
refractive
index
changes
into
high-contrast
color
variations,
enabling
multicolor
or
even
panchromatic
tuning
of
materials.
Here,
resonant-cavity-enhanced
an
advanced
emerging
trend
electrochromics,
are
reviewed.
In
this
review,
w
e
will
focus
on
progress
based
different
types
applications,
including
multichromatic
displays,
visible
visualized
energy
storage,
applications
multispectral
tunability.
Among
these
topics,
principles
resonators,
related
materials/devices
properties
comprehensively
discussed
summarized.
Finally,
challenges
prospects
presented.
Advanced Optical Materials,
Год журнала:
2021,
Номер
9(21)
Опубликована: Авг. 12, 2021
Abstract
The
self‐assembly
of
block
copolymers
(BCPs)
into
photonic
materials
has
drawn
significant
attention
due
to
the
flexibility
and
diversity
building
blocks
that
can
be
synthesized.
This
review
provides
a
brief
overview
development
this
research
area
then
discusses
in
detail
recent
advances
use
BCPs
as
pigments.
In
particular,
role
confinement
upon
process
form
well‐ordered
lamellae
is
described
compared
correlated
disordered
structures
derived
from
densely
packed
micelles.
These
systems
respectively
act
1D
(multilayered)
crystals
glasses
are
here
critically
terms
their
structural
characteristics
optical
performance.
Finally,
based
on
understanding,
current
challenges
field
discussed
potential
for
future
developments
explored.
Molecular Physics,
Год журнала:
2022,
Номер
121(1)
Опубликована: Ноя. 22, 2022
The
end-capped
modelling
of
non-fullerene
acceptor
(NFA)
units
have
been
performed
onto
the
structure
a
dithiophene-based
6,6′-di(thiophen-2-yl)-4,4′-bipyrimidine
(DTB)
moiety
to
design
nine
new
dyes
(DTIT1–DTIT9).
All
calculations
were
by
density
functional
theory
(DFT)
and
time
dependent
DFT
(TD-DFT)
based
calculations.
Their
molecular
geometries
optimised
their
ground
state
energies
at
CAM-B3LYP
with
6–31+G(d,p).
maximum
absorbance
(λmax)
DTB
was
noted
431
nm
all
DTIT1–DTIT9
displayed
λmax
frequencies
around
432–498
nm.
natural
transition
orbital
(NTO)
analysis
has
for
each
dye
molecule
only
excited
highest
oscillator
strength
(f).
bond
(NBO)
used
determine
stability
greatest
hyper
conjugation
related
interactions.
had
smaller
HOMO–LUMO
energy
gaps
(Egaps)
than
ranging
between
0.38
5.79
eV,
resulting
in
significant
nonlinear
optical
(NLO)
response.
DTIT7
NLO
response
compounds
studied,
owing
inclusion
four
cyanide
(CN)
groups.
activation
higher
designed
substances
DTB.
may
be
potential
contenders
applications.
ACS Applied Electronic Materials,
Год журнала:
2023,
Номер
5(5), С. 2454 - 2481
Опубликована: Апрель 21, 2023
In
recent
years,
the
emergence
of
memory
devices,
especially
resistive
random-access
memories
(RRAM),
has
been
a
front-runner
in
many
technological
applications.
This
is
due
to
its
high-speed
operation,
structural
simplicity,
low
power
consumption,
scalability
potential,
and
high-density
storage
features.
To
develop
an
efficient
miniaturized
device
based
on
switching
effect,
it
necessary
study
range
materials
their
fabrication
techniques.
this
review
article,
we
have
summarized
diverse
organic
inorganic
performance.
Furthermore,
reviewed
some
potential
for
next-generation
devices.
front,
numerous
physical,
chemical,
biological-based
synthesis
techniques
were
briefly
reviewed.
The
influence
preparative
parameters
was
also
discussed.
Finally,
current
status
future
directions
field
are
present
article
provides
important
details
promising
materials,
various
improve
device's
performance
