All-inorganic Mn²⁺-doped metal halide perovskite crystals for the late-time detection of X-ray afterglow imaging

Nanoscale, Год журнала: 2023, Номер 15(33), С. 13628 - 13634

Опубликована: Янв. 1, 2023

All-inorganic metal halide perovskite (MHP) materials have been widely studied because of their unique optoelectronic properties, whereas there has little research reported on X-ray afterglow imaging properties. Herein, we report the design and synthesis Mn2+-doped hexagonal CsCdCl3 MHP crystals with excellent scintillation induced afterglow. The orange emission from Mn2+ shows a red shift due to strong interaction Mn2+-Mn2+ dimers formed at higher doping concentrations. high-energy X-rays electron filling capacity feed shallow (0.71 eV) deep (0.90-1.08 traps enable long for more than 300 min. can be rejuvenated effectively by 870 nm stimulus or heating even after 72 h decay. Finally, demonstrate proof-of-concept applications fabricated flexible scintillator films real-time online spatial resolution 12.2 lp mm-1, as well time-lapse recorded cell phone, which promise being able do offline late-time detection in future.

Язык: Английский

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Large-Area Transparent Antimony-Based Perovskite Glass for High-Resolution X-ray Imaging

ACS Nano, Год журнала: 2024, Номер 18(26), С. 16715 - 16725

Опубликована: Июнь 14, 2024

Nonlead low-dimensional halide perovskites attract considerable attention as X-ray scintillators. However, most scintillation screens exhibit pronounced light scattering, which detrimentally reduces the quality of imaging. Herein, we employed a simple and straightforward solvent-free melt-quenching method to fabricate large-area zero-dimension (0D) antimony-based perovskite transparent medium, namely (C

Язык: Английский

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Unlocking the Potential of Organic‐Inorganic Hybrid Manganese Halides for Advanced Optoelectronic Applications

Advanced Materials, Год журнала: 2024, Номер unknown

Опубликована: Авг. 5, 2024

Organic-inorganic hybrid manganese(II) halides (OIMnHs) have garnered tremendous interest across a wide array of research fields owing to their outstanding optical properties, abundant structural diversity, low-cost solution processibility, and low toxicity, which make them extremely suitable for use as new class luminescent materials various optoelectronic applications. Over the past years, plethora OIMnHs with different dimensionalities multifunctionalities such efficient photoluminescence (PL), radioluminescence, circularly polarized luminescence, mechanoluminescence been newly created by judicious screening organic cations inorganic Mn(II) polyhedra. Specifically, through precise molecular engineering, series near-unity PL quantum yields, high anti-thermal quenching excellent stability in harsh conditions devised explored applications light-emitting diodes (LEDs), X-ray scintillators, multimodal anti-counterfeiting, fluorescent sensing. In this review, latest advancements development are summarized, covers from fundamental physicochemical properties advanced applications, an emphasis on functionality design especially LEDs detection imaging. Current challenges future efforts unlock potentials these promising also envisioned.

Язык: Английский

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Zn-Doped Organic–Inorganic Hybrid Mn(II) Halides with Ultra-High PLQY and Stability for Eco-Friendly Display Backlights

ACS Sustainable Chemistry & Engineering, Год журнала: 2025, Номер unknown

Опубликована: Март 14, 2025

Язык: Английский

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Bright green emitter of Mn-doped C4H12N2ZnX4 (X = Cl, Br) for X-ray radiography and WLEDs

Chemical Engineering Journal, Год журнала: 2023, Номер 468, С. 143818 - 143818

Опубликована: Июнь 1, 2023

Язык: Английский

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Blue‐Light‐Excitable Red‐to‐Near Infrared Photoluminescence in 0D Antimony(III) Bromide Hybrids for Supplemental Lighting

Advanced Optical Materials, Год журнала: 2024, Номер 12(16)

Опубликована: Фев. 21, 2024

Abstract Antimony (III)‐containing halide hybrids possess a distinctive stereoactivity with 5s 2 lone pair, which further induces significant structural distortions upon light excitation. Herein disordered dis ‐[TPPen] SbBr 5 (TPPen = triphenylpentylphosphonium) and ordered ord , have been synthesized exhibit self‐trapped excitons (STEs) emissions in the red‐to‐near infrared (NIR) range. Benefiting from high distortion degree of STEs confined within [SbBr ] 2− unit pronounced alterations Sb─Br bond lengths blue‐light excitation, achieves greater level excited state larger Stokes shift than those . The fabrication blue NIR light‐emitting device based on demonstrates prospective application night vision supplemental lighting non‐destructive examination. This work provides valuable molecular design strategies for luminescent materials hybrid metal halides.

Язык: Английский

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Near-Unity Green Luminescent Hybrid Manganese Halides as X-ray Scintillators

Inorganic Chemistry, Год журнала: 2024, Номер unknown

Опубликована: Янв. 23, 2024

The increasing demands in optoelectronic applications have driven the advancement of organic–inorganic hybrid metal halides (OIMHs), owing to their exceptional optical and scintillation properties. Among them, zero-dimensional (0D) low-toxic manganese-based scintillators garnered significant interest due transparency elevated photoluminescence quantum yields (PLQYs), making them promising for colorful light-emitting diodes X-ray imaging applications. In this study, two OIMH single crystals (Br-PrTPP)2MnBr4 (Br-PrTPP = (3-bromopropyl) triphenylphosphonium) (Br-BuTPP)2MnBr4 (Br-BuTPP (4-bromobutyl) were prepared via a facile saturated crystallization method. Benefiting from tetrahedrally coordinated [MnBr4]2– polyhedron, both exhibited strong green emissions peaked at 517 nm d–d electron transition Mn2+ with near-unity PLQYs 99.33 86.85%, respectively. Moreover, benefiting high transparencies remarkable luminescence properties, these manganese also exhibit excellent radioluminescent performance highest light yield up 68,000 photons MeV–1, negligible afterglow (0.4 ms), linear response dose rate lowest detection limit 45 nGyair s–1. imaging, flexible film made by composite PDMS shows an ultrahigh spatial resolution 12.78 lp mm–1, which provides potential visualization tool radiography.

Язык: Английский

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Low‐Dimensional Metal Halide for High Performance Scintillators

Advanced Functional Materials, Год журнала: 2024, Номер 34(38)

Опубликована: Апрель 25, 2024

Abstract Inorganic scintillators play a pivotal role in diverse fields like medical imaging, nondestructive detection, homeland security, and high‐energy physics. However, traditional inorganic encounter challenges such as high fabrication costs low light yield. Recently, low‐dimensional metal halide (LDMHS) have witnessed rapid progress, owing to their distinctive crystal structure superior radioluminescence performance. Herein, an overview of recent advancements proposed instructive pathways for achieving high‐performance LDMHS is provided. First, the scintillation physical mechanism emphasis on essential requirements applications are elucidated. Furthermore, classified according B‐site cations, respective characteristics introduced. This encompasses understanding structure‐property relationships routes rules optimizing Finally, persisting this burgeoning field potential research directions future exploration discussed.

Язык: Английский

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Temperature-dependent self-trapped exciton emission in Cu(I) doped zinc-based metal halides from well-resolved excited state structures

Nano Research, Год журнала: 2024, Номер 17(8), С. 7768 - 7775

Опубликована: Май 2, 2024

Язык: Английский

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Surfactant-Assisted Synthesis of Hybrid Copper(I) Halide Nanocrystals for X-ray Scintillation Imaging

Chemistry of Materials, Год журнала: 2024, Номер 36(6), С. 2963 - 2970

Опубликована: Март 13, 2024

Processing luminescent metal halide microcrystals into counterpart nanocrystals (NCs) can rationally enhance the resolution in X-ray scintillation imaging. It remains a challenge for controlled synthesis of hybrid NC luminescence materials, which is important fabrication organic films. Herein, we design copper(I)-based Cu6I8(bu-ted)2 (Cu6I8C20H42N4) (bu-ted: 1-butyl-1,4-diazabicyclo [2.2.2] octan-1-ium) NCs via surfactant-assisted method utilizing surface tension to limit crystal size. with prominent near-to-unity photoluminescence quantum yield results ultrahigh light output that calculated be 480% commercial Lu3Al5O12:Ce3+ scintillator low detection 32 nGy/s. imaging spatial 17 lp mm–1 demonstrated based on large-area composite screens. This study provides foundation nanocrystallize scintillators

Язык: Английский

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