With
the
development
of
white
light-emitting
diode
(LED)
technology,
near-infrared
(NIR)
phosphor-converted
(pc)
LED
is
becoming
a
new
emerging
light
source.
However,
due
to
lack
long
wavelength
components
phosphors,
application
NIR
pc-LED
restricted.
In
this
work,
continuous
ultra-broadband
emission
without
gap
in
850–950
nm
region
has
been
realized
Mg4Nb2O9
(MNO):Cr3+,
Yb3+
phosphor.
Meanwhile,
when
compared
MNO:Cr3+,
an
improved
internal
quantum
efficiency
(from
55.4%
72.6%)
and
thermal
stability
39%
63%
at
100
°C)
have
obtained
for
Yb3+,
which
attributed
combined
effect
efficient
energy
transfer
from
Cr3+
its
nearest
unique
levels
Yb3+.
The
performances
fabricated
devices
by
combining
with
460
chips
were
also
given,
results
demonstrate
that
phosphor
may
potential
practical
pc-LED.
Laser & Photonics Review,
Год журнала:
2024,
Номер
unknown
Опубликована: Авг. 20, 2024
Abstract
Far‐red
(FR)
and
near‐infrared
(NIR)
spectroscopy
technologies
have
attracted
extensive
attention.
How
to
obtain
luminescent
materials
suitable
FR‐NIR
phosphor‐converted
light‐emitting
diodes
(pc‐LEDs)
is
a
crucial
challenge.
Herein,
Si
3
N
4
‐substitution
strategy
employed
regulate
the
luminescence
of
Gd
Ga
5
O
12
:Cr
3+
(GGG:Cr
)
phosphors.
The
bandwidth
GGG:Cr
95
nm,
then
it
broadened
116
nm
due
‐substitution.
Furthermore,
at
423
K
thermal
stability
enhanced
98.7%
that
room
temperature,
which
higher
than
reported
92.7%@423
for
‐free
sample.
intensity
optimal
specimen
elevated
2.9
times
compared
with
sample
sintered
same
condition.
FR
pc‐LED
manufactured
by
using
optimized
sample,
its
output
power
47.1
mW
conversion
efficiency
15.9%
driven
100
mA.
This
work
paves
new
way
design
high‐performance
NIR
With
the
development
of
white
light-emitting
diode
(LED)
technology,
near-infrared
(NIR)
phosphor-converted
(pc)
LED
is
becoming
a
new
emerging
light
source.
However,
due
to
lack
long
wavelength
components
phosphors,
application
NIR
pc-LED
restricted.
In
this
work,
continuous
ultra-broadband
emission
without
gap
in
850–950
nm
region
has
been
realized
Mg4Nb2O9
(MNO):Cr3+,
Yb3+
phosphor.
Meanwhile,
when
compared
MNO:Cr3+,
an
improved
internal
quantum
efficiency
(from
55.4%
72.6%)
and
thermal
stability
39%
63%
at
100
°C)
have
obtained
for
Yb3+,
which
attributed
combined
effect
efficient
energy
transfer
from
Cr3+
its
nearest
unique
levels
Yb3+.
The
performances
fabricated
devices
by
combining
with
460
chips
were
also
given,
results
demonstrate
that
phosphor
may
potential
practical
pc-LED.