Dual Ligands Unlocking Iron and Halogen-Containing Carboxylates-based Photocatalysis for Chloro/Fluoro-Polyhaloalkylation of Alkenes

Chemical Science, Год журнала: 2024, Номер unknown

Опубликована: Янв. 1, 2024

Dual ligand-enabled iron photocatalysis for the conversion of all kinds halogen-containing carboxylates (C n X m COO − , X: F, Cl, Br) to C radicals is disclosed chloro/fluoro-polyhaloalkylation non-activated alkenes.

Язык: Английский

Chloride Induced S-C bond Selective Cleavage of Disulfides to Access Unsymmetrical β-Fluorodisulfides

Chemical Communications, Год журнала: 2024, Номер unknown

Опубликована: Янв. 1, 2024

This work describes a novel chloride anion induced radical-triggered S–C bond selective cleavage of disulfides to access unsymmetrical β-fluorodisulfides by disulfidefluorination alkenes.

Язык: Английский