Solvent‐Free Synthesis of Carvone Oxime Ester and Carvone Oxime Sulfonic Esters
ChemistrySelect,
Год журнала:
2024,
Номер
9(38)
Опубликована: Окт. 1, 2024
Abstract
A
ZnO‐mediated
benzoylation
between
carvone
oxime
and
acyl
is
reported,
enabling
access
to
diverse
ester
sulfonic
esters
under
solvent‐free
conditions.
The
operationally
simple
procedure
provides
a
novel
method
for
the
synthesis
of
oxime‐ester
bonds
with
excellent
chemo
selectivity.
This
strategy
mild,
direct,
green
approach
synthesizing
in
moderate
yields
good
substrate
tolerance.
In
addition,
was
synthesized
Язык: Английский
Decarboxylative Xanthylation under Photocatalytic Conditions
Organic Letters,
Год журнала:
2024,
Номер
26(44), С. 9574 - 9579
Опубликована: Окт. 24, 2024
Xanthates
are
widely
used
in
organic
synthesis
for
the
construction
of
various
molecules
and
have
numerous
applications
as
bioactive
compounds.
Here,
we
present
their
preparation
via
a
straightforward
photocatalytic
decarboxylative
xanthylation
process
involving
readily
available
oxime
esters
xanthate
dimers.
This
approach
provides
access
to
wide
variety
compounds
moderate
good
yields,
including
xanthates
derived
from
relevant
pharmaceutical
molecules.
Язык: Английский