International Journal of Biological Macromolecules, Год журнала: 2023, Номер 245, С. 125545 - 125545
Опубликована: Июнь 23, 2023
Язык: Английский
Advanced Science, Год журнала: 2023, Номер 10(9)
Опубликована: Янв. 19, 2023
Abstract The utilization of lignin, the most abundant aromatic biomass component, is at forefront sustainable engineering, energy, and environment research, where its abundance low‐cost features enable widespread application. Constructing lignin into material parts with controlled desired macro‐ microstructures properties via additive manufacturing has been recognized as a promising technology paves way to practical application lignin. Considering rapid development significant progress recently achieved in this field, comprehensive critical review outlook on three‐dimensional (3D) printing highly desirable. This article fulfils demand an overview structure presents state‐of‐the‐art 3D pristine lignin‐based composites, highlights key challenges. It attempted deliver better fundamental understanding impacts morphology, microstructure, physical, chemical, biological modifications, composition/hybrids rheological behavior lignin/polymer blends, well as, mechanical, chemical performance printed materials. main points toward future developments involve hybrid manufacturing, situ polymerization, surface tension or energy driven molecular segregation are also elaborated discussed promote high‐value
Язык: Английский
Процитировано
71
Fuel, Год журнала: 2024, Номер 365, С. 130751 - 130751
Опубликована: Фев. 19, 2024
Язык: Английский
Процитировано
28
Cleaner Materials, Год журнала: 2024, Номер 13, С. 100253 - 100253
Опубликована: Июнь 13, 2024
The development of sustainable and effective methods for extracting lignin is crucial achieving the advantages promoting shift towards a more circular bioeconomy. This study addresses use environmentally friendly processes, including organosolv technique, supercritical fluid (SCF), non-thermal plasma (NTP), ionic liquids (ILs), deep eutectic solvents (DES), microwave assisted extraction (MAE) techniques extraction. Organosolv treatment offers high selectivity purity make this process economically feasible. Using water, carbon dioxide, or ethanol to extract without harmful successful customizable. NTP technologies break down lignin, simplifying processing increasing its value. Whereas ILs may boost synthesis change properties via solvent design. DES-based can efficiently specifically lignin. rapid MAE method employs radiation reduce times yields These feature selectivity, little environmental impact, capacity target fractions. describes fundamentals, benefits, drawbacks each process, focusing on their ability large scale future usage. Additionally, review explores most recent advancements in application sector, as well challenges potential valorizing streams derived from extraction, thereby fostering solutions. research concludes that overcome challenges, need address concerns, cost, emissions, efficient use.
Язык: Английский
Процитировано
20
Science Advances, Год журнала: 2024, Номер 10(11)
Опубликована: Март 15, 2024
Natural wood has served as a foundational material for buildings, furniture, and architectural structures millennia, typically shaped through subtractive manufacturing techniques. However, this process often generates substantial waste, leading to inefficiency increased production costs. A potential opportunity arises if complex can be created additive processes. Here, we demonstrate an additive-free, water-based ink made of lignin cellulose, the primary building blocks natural wood, that used three-dimensional (3D) print architecturally designed via direct writing. The resulting printed structures, after heat treatment, closely resemble visual, textural, olfactory, macro-anisotropic properties, including mechanical wood. Our results pave way 3D-printed wooden construction with sustainable pathway upcycle/recycle
Язык: Английский
Процитировано
16
Advanced Functional Materials, Год журнала: 2025, Номер unknown
Опубликована: Янв. 7, 2025
Abstract Bio‐based hydrogels, valued for their flexibility, tunable mechanical properties, and biocompatibility, are promising materials wearable skins sensing devices in bionic hand control systems. Lignin, a biopolymer rich functional groups, can be modified into UV‐curable monomers, enabling the development of 3D‐printed hydrogels via photopolymerization. However, inherent rigidity lignin's aromatic rings, coupled with covalent cross‐linking between lignin other often limits hydrogel's stretchability (poor strain) compressibility. Additional challenges, including poor moisture retention freeze resistance, further hinder wider application. In this study, lignin‐based hydrogel is developed high tensile strain (≥350%), compressive (≈95%), fatigue resistance (up to 10 000 cycles under 50% strain, 200–800 95% strain), which achieved by incorporating glycerol lithium chloride facilitate dynamic hydrogen ion bonds, while accordingly reducing sites monomers. The enhanced allow effective performance at −40±1 °C. Afterward, using 3D printing technology, sensors ripple‐shaped 3 × Matrix pressure fabricated, demonstrated uniform stress distribution improved controlling complex movements, underscoring application advancing human–machine interfaces.
Язык: Английский
Процитировано
4
Materials Science and Engineering R Reports, Год журнала: 2023, Номер 156, С. 100761 - 100761
Опубликована: Окт. 31, 2023
Язык: Английский
Процитировано
36
Industrial Crops and Products, Год журнала: 2023, Номер 204, С. 117342 - 117342
Опубликована: Авг. 21, 2023
Язык: Английский
Процитировано
31
Scientific Reports, Год журнала: 2024, Номер 14(1)
Опубликована: Фев. 23, 2024
Abstract In this article, the formation of laser-induced graphene on two natural polymers, cellulose, and lignin, as precursors was investigated with molecular dynamics simulations some experiments. These eco-friendly polymers provide significant industrial advantages due to their low cost, biodegradability, recyclable aspects. It discovered during simulation that LIG has numerous defects a porous structure. Carbon monoxide, H 2 , water vapor are gases released by cellulose lignin substrates. O CO when polymer transforms into an amorphous Later on, structure changes ordered graphitic structure, is continuously. Since monomer higher mass proportion oxygen (49%) than (29%), it emits more CO. The contains many 5- 7-carbon rings, which cause have bends undulations go out plane. addition, verify results experimental tests, we used carbon dioxide laser transform filter paper, material, coconut shell, graphene. Surprisingly, empirical experiments confirmed results.
Язык: Английский
Процитировано
13
Advanced Materials, Год журнала: 2024, Номер 36(27)
Опубликована: Апрель 9, 2024
Abstract Accurate dosing for various liquids, especially highly viscous is fundamental in wide‐ranging from molecular crosslinking to material processing. Despite droppers or pipettes being widely used as pipetting devices, they are powerless quantificationally splitting and liquids (>100 mPa s) like polymer due the intertwined macromolecular chains strong cohesion energy. Here, a transparent photopyroelectric slippery (PS) platform provided achieve noncontact self‐splitting with viscosity high 15 000 s, just assistance of sunlight cooling source provide local temperature difference ( ΔT ). Moreover, guarantee accuracy (>80%), ultrathin MXene film (within thickness 20 nm) self‐assembled photo‐thermal layers, overcoming trade‐off between transparency photothermal property. Compared traditional strategies (≈1.3% liquids), this accurate microfluidic chip shows great potential adhesive systems (bonding strength, twice than using pipettes).
Язык: Английский
Процитировано
11
Chemical Engineering Journal, Год журнала: 2024, Номер 484, С. 149549 - 149549
Опубликована: Фев. 16, 2024
Язык: Английский
Процитировано
10