Abstract
Metal–organic
frameworks
(MOFs)
have
played
a
crucial
role
in
recent
advancements
developing
lithium‐based
battery
electrolytes,
electrodes,
and
separators.
Although
many
MOF‐based
components
rely
on
their
well‐defined
porosity
controllable
functionality,
they
also
boast
myriad
of
other
significant
properties
relevant
to
applications.
In
this
mini‐review,
the
distinct
advantages
MOFs
applications
are
discussed,
including
using
1)
scavenge
impurities
increase
cycling
stability,
2)
widen
operation
temperature
range
conventional
3)
voltage
common
4)
employ
as
artificial
solid‐electrolyte
interphases
prevent
lithium
dendrite
growth.
Furthermore,
subsisting
challenges
these
emerging
technologies
discussed
guidance
for
shaping
future
field
is
given.
Advanced Materials,
Год журнала:
2023,
Номер
35(48)
Опубликована: Июнь 29, 2023
The
use
of
conductive
MOFs
(c-MOFs)
in
zinc-based
batteries
has
been
a
popular
research
direction.
Zinc-based
are
widely
used
with
the
advantages
high
specific
capacity
and
safety
stability,
but
they
also
face
many
problems.
c-MOFs
have
excellent
conductivity
compared
other
primitive
MOFs,
therefore
better
applications
batteries.
In
this
paper,
transfer
mechanisms
unique
charges
c-MOFs:
hop
transport
band
transport,
respectively,
discussed
way
electron
is
further
addressed.
Then,
various
ways
to
prepare
introduced,
among
which
solvothermal,
interfacial
synthesis,
postprocessing
methods
used.
addition,
terms
their
role
performance
different
types
Finally,
current
problems
prospects
for
future
development
presented.
The
use
of
metal-organic
frameworks
(MOFs)
in
solid-state
electrolytes
(SSEs)
has
been
a
very
attractive
research
area
that
received
widespread
attention
the
modern
world.
SSEs
can
be
divided
into
different
types,
some
which
combined
with
MOFs
to
improve
electrochemical
performance
batteries
by
taking
advantage
high
surface
and
porosity
MOFs.
However,
it
also
faces
many
serious
problems
challenges.
In
this
review,
types
are
classified
changes
these
after
addition
described.
Afterward,
attached
introduced
for
battery
applications
effects
on
cells
Finally,
challenges
faced
materials
presented,
then
solutions
development
expectations
given.
Materials Chemistry Frontiers,
Год журнала:
2024,
Номер
8(6), С. 1421 - 1450
Опубликована: Янв. 1, 2024
In
this
review,
the
problems
of
interface
between
lithium
metal
anodes
and
all-solid-state
electrolytes
are
explored
modification
strategies
to
solve
these
summarized.
