Advanced Functional Materials,
Год журнала:
2024,
Номер
unknown
Опубликована: Окт. 13, 2024
Abstract
Water
constitutes
a
huge
circulation
network
in
solid,
liquid
and
gaseous
forms
that
contains
inestimable
recyclable
energy.
Obtaining
energy
from
moisture
is
challenging
but
of
great
significance
to
promote
the
upgrading.
The
emergence
moisture‐driven
actuator
(MDA)
provides
an
effective
way
converting
mechanical
MDA
can
combine
with
water
molecules
through
hygroscopicity
swell
produce
macroscopic
deformation.
Due
wide
distribution
humidity
wireless
driving
mode,
shows
application
potential
fields
environmental
monitoring,
remote
control
harvesting.
This
paper
comprehensively
reviews
research
progress
aspects
hydrophilic
materials,
structures,
preparing
methods,
multi‐response
integration
applications,
aiming
at
providing
guidance
for
design,
preparation
MDA.
Besides,
challenges
faced
by
are
analyzed
corresponding
solutions
proposed,
which
points
out
next
stage
developing
direction
Journal of Applied Polymer Science,
Год журнала:
2025,
Номер
unknown
Опубликована: Янв. 15, 2025
ABSTRACT
Liquid
crystal
elastomers
(LCEs)
are
liquid
polymers
with
moderate
crosslinking
that
exhibit
elasticity
in
both
their
isotropic
and
states.
These
materials
can
be
programmed
through
chemical
design
geometric
configuration
to
achieve
autonomous
actuation
at
specific
temperatures.
Typically,
the
temperature
of
LCEs
exceeds
phase
transition
states,
most
reported
requiring
temperatures
above
100°C.
Such
high
pose
challenges
for
use
soft
robotics
due
increased
energy
consumption
limited
operational
flexibility.
In
this
study,
we
introduce
a
small
amount
polycaprolactone
(PCL)
into
main
chain
LCEs,
effectively
lowering
while
maintaining
over
90%
reversible
shrinkage
strain
characteristic
pure
LCEs.
By
adjusting
PCL
content,
number
twists,
helix
density,
successfully
obtained
an
LCE‐PCL
actuator
improved
performance
ranging
from
45°C
105°C.
Moreover,
by
modulating
degree
torsion
operating
temperature,
demonstrates
ability
perform
complex
motions,
such
as
reversing
parking.
This
work
offers
new
insights
application
reduced
enhanced
self‐driving
capabilities.
Polymers,
Год журнала:
2025,
Номер
17(4), С. 436 - 436
Опубликована: Фев. 7, 2025
Self-excited
systems
rely
on
stable
external
stimuli
to
initiate
and
sustain
oscillations
via
internal
processes.
However,
these
can
compromise
system
stability
increase
friction,
limiting
their
practical
applications.
To
overcome
this
issue,
we
propose
the
light-fueled
self-rolling
of
a
liquid
crystal
elastomer
(LCE)-based
wheel.
A
photothermal
response
model
based
an
LCE
was
used
analyze
temperature
distribution
within
rods.
The
driving
torque
for
is
generated
by
contraction
resulting
from
LCE's
response,
which
displaces
wheel's
center
mass.
We
then
derived
equilibrium
equations
identified
critical
conditions
achieving
motion.
Through
interaction
between
field
torque,
wheel
achieves
continuous
absorbing
thermal
energy
counteract
damping
dissipation.
Numerical
simulations
revealed
that
velocity
influenced
several
key
parameters,
including
heat
flux,
coefficient,
gravitational
acceleration,
initial
rolling
coefficient.
proposed
LCE-based
enhances
significantly
reduces
frictional
losses.
These
characteristics
make
it
promising
candidate
applications
in
autonomous
drive
systems,
micro-transportation
devices,
conversion
technologies.
Polymers,
Год журнала:
2025,
Номер
17(4), С. 494 - 494
Опубликована: Фев. 13, 2025
Liquid
crystal
elastomers
(LCE)
are
a
promising
material
to
achieve
reversible
actuation
while
being
able
perform
work,
showing
great
potential
as
artificial
muscles
in
soft
robotics
and
medical
technology.
Here,
wet
spinning
process
prepare
liquid
elastomer
fibers
(LCEF)
with
capability
is
presented.
Furthermore,
we
demonstrate
the
ability
side-chain
(LC)
4-Methoxyphenyl
4-(3-butenyloxy)benzoate
(MBB)
into
fiber,
enlarging
variance
available
this
field.
The
presented
discussed
terms
of
parameters
their
influence
on
fiber
properties,
especially
LC
orientation.
Moderate
draw
ratios
up
2.3
enable
highly
oriented
mesogens
(f
=
0.64),
enabling
contractile
behavior.
generated
MBB-based
LCEF
show
low
activation
temperature
(54.52
°C),
temperature-dependent
mechanical
contraction
behavior
lifting
140
times
own
weight
work
3.857
J
kg-1.
Actuation
properties
compared
human
skeletal
muscle,
possible
strategies
further
enhancing
performance
discussed.
data
features
for
use
muscle
applications,
e.g.,
prosthetics
cardiac
tissue.
Liquid
crystal
elastomers
with
near-ambient
temperature-responsiveness
(NAT-LCEs)
have
been
extensively
studied
for
building
biocompatible,
low-power
consumption
devices
and
robotics.
However,
conventional
manufacturing
methods
face
limitations
in
programmability
(e.g.,
molding)
or
low
nematic
order
DIW
printing).
Here,
a
hybrid
cooling
strategy
is
proposed
programmable
three-dimensional
(3D)
printing
of
NAT-LCEs
enhanced
order,
intricate
shape
forming,
morphing
capability.
By
integrating
low-temperature
nozzle
platform
into
3D
printer,
the
resulting
temperature
field
synergistically
facilitates
mesogen
alignment
during
extrusion
disruption-free
ultraviolet
(UV)
cross-linking.
This
method
achieves
3000%
higher
than
fabricated
using
traditional
room
printing.
Enabled
by
shifting
transition
printing,
printed
sheets
spontaneously
turn
structures
after
release
from
platform,
exhibiting
bidirectional
deformation
heating
cooling.
adjusting
plate
temperatures,
graded
properties
can
be
morphing.
A
wristband
system
heart
rate
monitoring
also
developed
based
on
3D-printed
NAT-LCE.
Our
developments
soft
robotics,
biomedical
devices,
wearable
electronics.
Stimuli-bent
cylinders
roll
continuously
on
a
surface.
The
1st
FEA
of
the
rolling
nonmechanically
bent
cylinders.
A
pseudo-thermal
field
method
for
eigenstrain
in
FEA.
Reproduces
several
modes
autonomous
locomotion
observed
experimentally.
Journal of Materials Chemistry A,
Год журнала:
2025,
Номер
unknown
Опубликована: Янв. 1, 2025
A
synchronous
differential
orientation
strategy
was
proposed
for
the
fabrication
of
programmable
liquid
crystal
elastomers
with
aid
dual
dynamic
covalent
bonds,
which
are
composed
boronic
ester
bonds
and
siloxane
bonds.