Influence of CeO2 Support Morphology on the Structural and NO2-RR Performance of CeO2@Au Catalyst DOI
Jin Li,

Wei Zhang,

Xiujing Xing

и другие.

Materials Chemistry Frontiers, Год журнала: 2024, Номер 9(2), С. 223 - 233

Опубликована: Ноя. 7, 2024

The impact of different CeO 2 support morphology on the surface structure @Au catalyst, and its performance in electrocatalytic reduction nitrite to ammonia was investigated systematically.

Язык: Английский

Surface Structure Reformulation from CuO to Cu/Cu(OH)2 for Highly Efficient Nitrate Reduction to Ammonia DOI Creative Commons
Jin Li,

Qiuling Jiang,

Xiujing Xing

и другие.

Advanced Science, Год журнала: 2024, Номер 11(38)

Опубликована: Авг. 9, 2024

Abstract Electrochemical conversion of nitrate (NO 3 − ) to ammonia (NH is a potential way produce green NH and remediate the nitrogen cycle. In this paper, an efficient catalyst spherical CuO made by stacking small particles with oxygen‐rich vacancies reported. The yield Faraday efficiency are 15.53 mg h −1 cat 90.69%, respectively, in neutral electrolyte at voltage ‐0.80 V (vs. reversible hydrogen electrode). high activity electrodes results from changes phase structure during electrochemical reduction. Structurally, there shift dense accumulation layered network uniform distribution stacked on top each other, thus exposing more active sites. Furthermore, terms phase, electrode transitions Cu/Cu(OH) 2 . Density functional theory calculations showed that Cu(OH) formation enhances NO ‐ adsorption. Meanwhile, can inhibit competing evolution reaction, while Cu (111) crystal surfaces facilitates hydrogenation reaction. synergistic effect between two promotes Therefore, study provides new idea direction for Cu‐based oxides electrocatalytic production.

Язык: Английский

Процитировано

13

Cu‐Ru Bicenter Synergistically Triggers Tandem Catalytic Effect for Electroreduction of Nitrate to Ammonium DOI Open Access

Liyang Lv,

Hao Tan,

Yuying Liu

и другие.

Advanced Functional Materials, Год журнала: 2025, Номер unknown

Опубликована: Янв. 10, 2025

Abstract The electrochemical transformation of nitrate (NO 3 − ) into ammonia (NH holds significant promise to addresses nitration contamination and offers a sustainable alternative the Haber–Bosch process. However, sluggish kinetics hinders its large‐scale application. Herein, Cu‐doped SrRuO synergetic tandem catalyst is designed synthesized, which demonstrates exceptional performance in converting NO NH . Specifically, this achieves maximum Faradaic efficiency 95.4% for production, along with high yield rate 7196 µg h −1 mg cat. A series detailed characterizations reveals that doped Cu ions modify local electronic environment Ru 4 d e g orbital , thereby facilitating highly efficient electron transfer processes. In situ delta X‐ray absorption near‐edge structure (ΔXANES), synchrotron radiation‐based Fourier transform infrared (SR‐FTIR) Raman spectroscopy identified * 2 generated on active sites subsequently hydrogenated sites. Combined theoretical studies, it confirmed significantly reduces energy barriers rate‐determining step ( NOH), enhancing synthesis. This work not only fundamental insights mechanisms cation substitution regulating perovskite catalysts, but also provides promising avenue electro‐synthesis ammonia.

Язык: Английский

Процитировано

1

Enhanced activation of molecular oxygen for efficient chloroquine phosphate degradation with CuO@Co3O4/GF heterostructure: Promoting mechanisms of oxygen vacancy and interfacial electronic engineering DOI
Xuelin Shi, Zihao Yan, Tong Zhu

и другие.

Separation and Purification Technology, Год журнала: 2025, Номер unknown, С. 131745 - 131745

Опубликована: Янв. 1, 2025

Язык: Английский

Процитировано

1

When Electrocatalytic Nitrate Reduction Meets Copper-based Atomic Site Catalysts DOI
Xiaoqian Liu,

Tianyi Xiang,

Yuntao Liang

и другие.

Journal of Materials Chemistry A, Год журнала: 2024, Номер unknown

Опубликована: Янв. 1, 2024

This manuscript comprehensively reviews the recent advancements in Cu-based atomic site catalysts NO 3 RR, following a sequential order with six sections: Introduction, Mechanism, SACs, SAAs, DACs, and Perspectives.

Язык: Английский

Процитировано

6

Construction of Fe3O4@Au catalysts via the surface functional group effect of ferric oxide for efficient electrocatalytic nitrite reduction DOI
Wei Zhang, Jin Li,

Cuilian Sun

и другие.

Dalton Transactions, Год журнала: 2024, Номер unknown

Опубликована: Янв. 1, 2024

Surface modification is one of the effective strategies to control morphology and electrocatalytic performance noble metal/transition metal oxide matrix composite catalysts. In this work, we successfully introduced groups such as -NH

Язык: Английский

Процитировано

3

Endowing Cu-Based Oxide with a Self-Healing Feature via High-Entropy Doping toward Ampere-Level Electrochemical Nitrate Reduction to Ammonia DOI

Zebin Zhu,

Yuanbo Zhou, Mengfan Wang

и другие.

ACS Materials Letters, Год журнала: 2025, Номер unknown, С. 938 - 946

Опубликована: Фев. 10, 2025

Язык: Английский

Процитировано

0

Metastable Phase Noble-Metal-Free Core–Shell Structure for Efficient Electrocatalytic Nitrobenzene Transfer Hydrogenation DOI
Yutian Xiong, Jinxin Chen, Yue Wang

и другие.

Nano Letters, Год журнала: 2025, Номер 25(9), С. 3383 - 3390

Опубликована: Фев. 19, 2025

In order to study the catalytic behavior of a metastable-phase catalyst in electrocatalytic hydrogenation, we report new noble-metal-free core–shell with metastable hexagonal closest packed (hcp) phase Ni as shell and face-centered-cubic (fcc) Cu core (Cu@hcp NPs) for hydrogenation nitrobenzene (Ph-NO2) aniline (Ph-NH2). Using H2O hydrogen source, it achieves up 99.63% Ph-NO2 conversion ∼100% Ph-NH2 selectivity, an improved activity turnover frequency (TOF: 6640 h–1), much higher than those hcp NPs (5183.7 h–1) commercial Pt/C (3537.6 h–1). It can also deliver variety aminoarenes outstanding selectivity excellent functional group compatibility several groups. Mechanistic studies have shown that introduction enhances Ni's ability dissociate water situ produce H* improves rate, resulting rapid final product Ph-NH2.

Язык: Английский

Процитировано

0

Ambient and Selective Electrochemical Dinitrogen Fixation to NH3 Catalyzed by Microporous Organic–Inorganic Hybrid Copper Phosphonate DOI

Smruti Vardhan Purohit,

Bibek Dash, Prashanth W. Menezes

и другие.

ACS Sustainable Chemistry & Engineering, Год журнала: 2025, Номер unknown

Опубликована: Март 9, 2025

Язык: Английский

Процитировано

0

Preparation of Copper Oxide Film at Low Temperature in Basic Conditions on a Copper Substrate DOI Open Access
Francesca Irene Barbaccia, Tilde de, F. Federici

и другие.

Materials, Год журнала: 2025, Номер 18(7), С. 1487 - 1487

Опубликована: Март 26, 2025

Copper is widely used in both its metallic form and as oxide across numerous scientific industrial domains. The primary copper oxides, cuprite (Cu2O) tenorite (CuO), naturally on the surface play a crucial role advanced technologies, such solar cells, lithium batteries, sensors. Tenorite appreciated for optical properties, stability, low toxicity, reactivity. While thin films are traditionally synthesized through thermal treatments oxidation alkaline environments, these conventional high-temperature methods not only require significant energy consumption but can also compromise metal-film interface. This study aims to develop sustainable alternative approach forming homogeneous CuO layer substrate environmentally friendly based temperature, cost-effective, time-saving procedures. Three different eco-conscious were investigated: (i) immersion NaOH basic solution, (ii) exposure solution vapours, (iii) combined treatment involving vapour exposure. green synthesis significantly reduces compared traditional while maintaining product quality. was investigated an microscope (OM), scanning electron microscopy (SEM), spectrocolorimetric analysis, peel-off test, µ-Raman X-ray photoelectron spectroscopy (XPS) analysis investigate state.

Язык: Английский

Процитировано

0

Hydrogen radical-mediated efficient electrocatalytic N2 reduction by bimetallic sulfides DOI
Nana Li, Jing Zhang, Zhiqiang Qiao

и другие.

Chemical Engineering Journal, Год журнала: 2025, Номер unknown, С. 162736 - 162736

Опубликована: Апрель 1, 2025

Язык: Английский

Процитировано

0